AtMetExpress Development LC-MS

Perk Nr:adn031884.

Polarity: [NEGATIVE]
Retention time: 4.52
m/z: 431
Annotation:
Annotation level: Unknown
compound: Vitexin
MS2Ts 39 MS2Ts
KNApSAcK C20H33O10(19):C20H32O9+O;
C24H33O5S1(18):(S)-Furanopetasitin; C24H32O5S;
C12H26N4O9P1S1(14):C11H23N4O8PS+CH3O;
C21H21O10(14):Apigenin 7-O-glucoside, Isovitexin;6-beta-D-Glucop
C27H29O5(14):C27H28O4+O; C27H28O6-O; C27H30O6-H2O;
C22H29N2O7(8):C22H28N2O6+O; C16H18N2O2+C6H10O5; C22H30N2O8-H2O;
C13H26N2O10P1S1(8):C12H23N2O9PS+CH3O;
C20H21N2O9(8):C14H10N2O4+C6H10O5;
C15H21N4O9S1(7):C15H20N4O8S+O;
C24H33O7(5):Grandisin;(-)-Grandisin, Magnosalicin, Inflexin, (
in-house MS/MS Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(28)
Rhamnosyl Kaempferol(27)
kaempferol 7-O-rhamnoside(27)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE60(27)
Luteolin_CE30(27)
Poncirin_CE50(27)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE40(27)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(27)
kaempferol(26)
Kaempferol 3-rhamnoglucoside(26)
Luteolin_CE10(26)
luteolin-7-O-rutinoside(26)
kaempferol 3-O-gentiobioside(26)
Kaempferol(26)
Poncirin_30V(26)
kaempferol-7-O-neohesperidoside_CE60(26)
Kaempferol(26)
kaempferol(26)
luteolin-4'-O-glucoside_CE30(26)
kaempferol-3-glucoside(26)
Maritimein_CE40(25)
Maritimein_CE30(25)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(25)
Luteolin_CE20(25)
luteolin-4'-O-glucoside_CE40(25)
kaempferol 3-O-sophoroside(24)
Poncirin_CE60(24)
kaempferol-7-O-neohesperidoside_CE40(24)
kaempferol-7-O-neohesperidoside(24)
kaempferol-7-O-neohesperidoside(24)
kaempferol-7-O-neohesperidoside_CE40(23)
kaempferol-7-O-neohesperidoside_CE60(22)
luteolin 7-O-allosylglucoside(22)
Kaempferol-3-Glucoside-2-p-coumaroyl_Ramp5-45 V(22)
isoscutellarein 7-O-allosylglucoside(21)
Datiscin_CE50(21)
Maritimein_Ramp5-45 V(21)
Kaempferol-3-Glucuronide_Ramp5-45 V(21)
luteolin-4'-O-glucoside_CE50(19)
kaempferol 3-O-rutinoside(19)
Luteolin(18)
kaempferol-7-O-neohesperidoside_CE50(18)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(16)
Luteolin_Ramp5-45 V(15)
Scutellarein(15)
kaempferol 3-O-Glucoside(14)
kaempferol 3-O-galactoside(14)
kaempferol-7-O-glucoside(14)
Scutellarin(14)
luteolin-7-O-rutinoside(14)
kaempferol 3-O-rutinoside(14)
Kaempferol hexoside(14)
Kaempferol 7-O-robinoside(14)
Glucosyl Rhamnosyl Kaempferol(14)
kaempferol-3-O-glucoside(14)
kaempferol 7-O-Glucoside(14)
Luteolin-4'-glucoside(14)
Kaempferol-3-Rhamnoside-4''-Rhamnoside-7-Rhamnoside_CE60(14)
Kaempferol 3-O-Glucoside(14)
Glucosyl Rhamnosyl Kaempferol(14)
Luteolin-7-glucoside(14)
kaempferol 3-O-glucoside(14)
kaempferol 3-O-robinoside(14)
Kaempferol-3-O-glucuronide(14)
Glucosyl Kaempferol(14)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(13)
Kaempferol-3-Glucoside-2-p-coumaroyl,-7-Glucoside_30V(13)
Kaempferol 3-Diglucoside (Isomer)(13)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(13)
kaempferol 3-Glucoside(12)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_30V(12)
luteolin-4'-O-glucoside_CE20(12)
kaempferol-3-O-rutinoside_30V(12)
Kaempferol-3-Rhamnoside_Ramp5-45 V(12)
kaempferol-3-sophoroside(12)
Kaempferol-3-Glucoside-6-p-coumaroyl_30V(12)
Datiscin_CE40(12)
taxifolin O-glucoside(9)
Kaempferol 3-Diglucoside(8)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(8)
7-O-Deoxyhexosyl(1,2)hexosylluteolin(7)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(7)
kaempferol-3-O-rutinoside(5)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(5)
kaempferol-3-O-glucoside(5)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n03720

ATH06n04262

ATH07n04084

ATH07n04663

ATH08n06590

ATH08n07263

ATH08n07750

ATH09n06738

ATH09n07376

ATH10n04385

ATH10n04386

ATH10n04870

ATH11n03566

ATH11n04003

ATH12n03088

ATH12n03299

ATH12n03502

ATH13n06913

ATH56n07868

ATH56n08628

ATH57n07618

ATH57n08364

ATH58n07984

ATH58n08239

ATH58n08497

ATH58n08754

ATH59n07555

ATH59n08309

ATH60n07474

ATH60n08207

ATH60n08456

ATH61n06761

ATH61n07479

ATH62n07063

ATH62n07797

ATH63n06951

ATH63n08212

ATH64n07696

ATH64n07915

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.1859 0.2745 0.3719 0.3884 0.3052
ATGE_7 0.0075 0.261 0.0231 0.0139 0.0764
ATGE_9 0.0063 0.0067 0.0084 0.0069 0.0071
ATGE_10 0.3209 0.4013 0.3075 0.2845 0.3286
ATGE_12 0.6684 0.681 0.7058 1 0.7638
ATGE_13 0.4989 0.3199 0.3854 0.0154 0.3049
ATGE_14 0.1607 0.0245 0.3437 0.013 0.1355
ATGE_15 0.0118 0.2272 0.1783 0.1905 0.152
ATGE_16 0.0061 0.0148 0.0145 0.1362 0.0429
ATGE_19 0.0077 0.0136 0.0076 0.0126 0.0104
ATGE_20 0.0109 0.1943 0.0128 0.0231 0.0603
ATGE_21 0.0174 0.38 0.2547 0.0098 0.1655
ATGE_25 2.5555 1.9292 2.881 2.9164 2.5705
ATGE_26 2.7878 2.2779 1.3212 2.8746 2.3154
ATGE_27 0.163 0.0526 0.1229 0.0106 0.0873
ATGE_28 0.0191 0.0231 0.0275 0.0771 0.0367
ATGE_29 0.0073 0.0063 0.0074 0.0065 0.0069
ATGE_32 0.0153 0.0064 0.2729 0.1722 0.1167
ATGE_33 0.4021 0.0194 0.0108 0.246 0.1696
ATGE_39 0.5 0.4267 0.0116 0.0123 0.2377
ATGE_41 0.6715 0.602 0.7196 0.7196 0.6782
ATGE_42 0.3995 0.3524 0.3585 0.2285 0.3347
ATGE_45 0.0126 0.0089 0.005 0.0066 0.0083
ATGE_76 0.0837 0.0149 0.1489 0.0066 0.0635
ATGE_77 0.0173 0.0129 0.0182 0.0202 0.0172
ATGE_78 0.1604 1.1829 0.3587 1.8576 0.8899
ATGE_84 0.0122 0.0078 0.0078 0.015 0.0107
ATGE_91 0.4015 0.4094 0.4518 0.553 0.4539
ATGE_92 0.3134 0.3082 0.3113 0.2009 0.2835
ATGE_93 0.0408 0.0058 0.0076 0.014 0.017
ATGE_95 0.0443 0.0076 0.0314 0.012 0.0238
ATGE_96 0.486 0.3018 0.2849 0.4986 0.3928
ATGE_97 0.2931 0.2276 0.0248 0.0204 0.1415
ATGE_98 0.0054 0.0103 0.0073 0.0054 0.0071
ATGE_99 0.0075 0.0216 0.0176 0.0305 0.0193
ATGE_101 0.8933 1.3379 0.8214 0.7308 0.9459
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch