AtMetExpress Development LC-MS

Perk Nr:adn045312. Kaempferol-3-Rha-7-Glu

Polarity: [NEGATIVE]
Retention time: 3.85
m/z: 593
Annotation: Kaempferol-3-Rha-7-Glu
Annotation level: Annotated
compound:
MS2Ts 45 MS2Ts
KNApSAcK C27H31O15(32):Paniculatin, Apigenin 7-allosyl-(1->2)-glucoside,
C34H27O10(28):Agathisflavone tetramethyl ether, Cupressuflavone
C31H31O12(5):C31H30O13-O; C25H20O7+C6H10O5;
in-house MS/MS Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(26)
Datiscin_30V(23)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_30V(23)
kaempferol-7-O-neohesperidoside_30V(23)
luteolin-4'-O-glucoside_Ramp5-45 V(23)
kaempferol 3-O-gentiobioside(22)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE60(22)
kaempferol-7-O-neohesperidoside_CE60(22)
Luteolin_CE30(22)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE40(22)
luteolin-4'-O-glucoside_CE30(22)
kaempferol(21)
Kaempferol 3-rhamnoglucoside(21)
Luteolin_CE10(21)
luteolin-7-O-rutinoside(21)
Kaempferol(21)
Poncirin_30V(21)
luteolin 7-O-allosylglucoside(21)
Kaempferol(21)
kaempferol(21)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(21)
kaempferol-3-glucoside(21)
kaempferol-7-O-neohesperidoside(21)
luteolin-4'-O-glucoside_CE20(19)
kaempferol 3-O-Glucoside(18)
kaempferol 3-O-galactoside(18)
kaempferol-7-O-glucoside(18)
Kaempferol hexoside(18)
Datiscin_CE50(18)
kaempferol-3-O-glucoside(18)
kaempferol 7-O-Glucoside(18)
Luteolin-4'-glucoside(18)
kaempferol-7-O-neohesperidoside_CE40(18)
Kaempferol 3-O-Glucoside(18)
Luteolin-7-glucoside(18)
kaempferol 3-O-glucoside(18)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE60(18)
Glucosyl Kaempferol(18)
isoscutellarein 7-O-allosylglucoside(17)
Luteolin_CE20(17)
kaempferol 3-O-sophoroside(16)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE60(16)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE50(16)
kaempferol 3-Glucoside(15)
Maritimein_CE40(15)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_30V(15)
Poncirin_CE60(14)
luteolin-4'-O-glucoside_CE40(14)
kaempferol-7-O-neohesperidoside_CE40(13)
kaempferol 3-O-rutinoside(12)
Kaempferol-3-Glucoside-2-p-coumaroyl_Ramp5-45 V(12)
Kaempferol 3-Diglucoside(9)
luteolin-7-O-rutinoside(9)
kaempferol 3-O-rutinoside(9)
Kaempferol 7-O-robinoside(9)
luteolin 7-O-(2-apiosyl)glucoside Luteolin 7-O-[2-(.beta.-D-apiofuranosyl)-.beta.-D-glucopyranoside(9)
Glucosyl Rhamnosyl Kaempferol(9)
Kaempferol 3-Diglucoside (Isomer)(9)
Glucosyl Rhamnosyl Kaempferol(9)
Scutellarein(9)
kaempferol 3-O-robinoside(9)
luteolin-4'-O-glucoside_CE50(8)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(8)
Rhamnosyl Kaempferol(7)
Scutellarin(7)
kaempferol-3-O-rutinoside(7)
7-O-Deoxyhexosyl(1,2)hexosylluteolin(7)
kaempferol-7-O-neohesperidoside_CE50(7)
kaempferol 7-O-rhamnoside(7)
Kaempferol-3-O-glucuronide(7)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(6)
kaempferol-3-sophoroside(6)
Luteolin_Ramp5-45 V(6)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(6)
Datiscin_CE40(5)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n06396

ATH06n06595

ATH06n06929

ATH07n07780

ATH08n09774

ATH08n10022

ATH08n10422

ATH08n10850

ATH09n10352

ATH09n10356

ATH10n07122

ATH10n07344

ATH11n05844

ATH11n06341

ATH12n05402

ATH12n05571

ATH12n05834

ATH12n06143

ATH13n09275

ATH13n09696

ATH13n10151

ATH14n08678

ATH14n09250

ATH14n09459

ATH56n11643

ATH57n11233

ATH57n11236

ATH57n12268

ATH58n11798

ATH58n12059

ATH58n12817

ATH59n11177

ATH60n12275

ATH61n10496

ATH61n10734

ATH61n11461

ATH62n10552

ATH62n10803

ATH62n11245

ATH62n11248

ATH63n11227

ATH63n11481

ATH64n10704

ATH64n11425

ATH64n11428

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.3417 0.3551 0.5 0.4865 0.4208
ATGE_7 0.7343 0.6625 0.892 0.6418 0.7326
ATGE_9 0.1557 0.413 0.2824 0.0696 0.2302
ATGE_10 0.4111 0.3469 0.4154 0.4085 0.3955
ATGE_12 0.0962 0.1135 0.0681 0.0815 0.0898
ATGE_13 0.1521 0.1207 0.0937 0.5567 0.2308
ATGE_14 0.2806 0.1939 0.1536 0.1256 0.1884
ATGE_15 0.8284 0.5075 0.3542 0.6064 0.5741
ATGE_16 1.3504 0.7475 1.0827 1.1316 1.078
ATGE_19 0.1108 0.1068 0.1374 0.1063 0.1153
ATGE_20 0.4219 0.6255 0.4652 0.5819 0.5236
ATGE_21 0.3673 0.6685 0.6082 0.3921 0.509
ATGE_25 0.0818 0.0681 0.0878 0.0634 0.0753
ATGE_26 0.256 0.3204 0.2309 0.2948 0.2755
ATGE_27 0.1021 0.1378 0.179 0.1893 0.1521
ATGE_28 0.0164 0.113 0.0491 0.1734 0.088
ATGE_29 1.697 2.0617 1.4888 1.5208 1.6921
ATGE_32 1.345 1.4375 1.1789 1.2328 1.2986
ATGE_33 1.6957 1.6295 1.6434 1.8481 1.7042
ATGE_39 2.4128 2.3813 2.2682 1.3316 2.0985
ATGE_41 0.138 0.1608 0.1238 0.1238 0.1366
ATGE_42 1.0107 0.5774 0.6522 0.7261 0.7416
ATGE_45 2.8632 2.0941 2.3558 2.2394 2.3881
ATGE_76 3.8229 1.1616 4.3693 4.4257 3.4449
ATGE_77 3.5519 3.9372 3.6266 3.4463 3.6405
ATGE_78 4.0373 0.5297 0.1449 0.382 1.2735
ATGE_84 0.0163 0.0626 0.0704 0.0877 0.0593
ATGE_91 0.3244 0.4055 0.1584 0.2617 0.2875
ATGE_92 1.6766 1.9585 1.7772 1.6617 1.7685
ATGE_93 3.7629 3.7397 3.7715 2.6401 3.4786
ATGE_95 1.6475 1.6045 1.3317 0.9735 1.3893
ATGE_96 0.1806 0.1207 0.1312 0.211 0.1609
ATGE_97 0.5985 0.8726 0.8618 0.845 0.7945
ATGE_98 1.1992 3.3896 1.3022 1.3001 1.7978
ATGE_99 2.8922 2.3966 2.2065 2.7633 2.5646
ATGE_101 0.218 0.0416 0.1 0.1556 0.1288
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch