AtMetExpress Development LC-MS

Perk Nr:adn045317.

Polarity: [NEGATIVE]
Retention time: 4.25
m/z: 593
Annotation:
Annotation level: Unknown
compound: "Quercetin-3,7-O-alpha-L-dirhamnopyranoside: Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside"
MS2Ts 74 MS2Ts
KNApSAcK C27H31O15(52):Paniculatin, Apigenin 7-allosyl-(1->2)-glucoside,
C34H27O10(47):Agathisflavone tetramethyl ether, Cupressuflavone
C30H27O13(11):Apigenin 7-(6''-E-Caffeoylglucoside);7-[[6-O-[3-(3
C31H31O12(9):C31H30O13-O; C25H20O7+C6H10O5;
in-house MS/MS Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_30V(33)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_30V(32)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(28)
Kaempferol-3,7-O-di-rhamnopyranoside_CE60(26)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(26)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE50(24)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(23)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE60(21)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_30V(19)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(16)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_30V(16)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(15)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE60(9)
Represetative peak adn044201::581: 0.091:1:0.924; adn045226::592: 0.38:0:0.923; adn055303::692: 0.274:1:0.745; adn055419::693: 0.336:2:0.833; adn131364::1214: 0.182:0:0.924; adn132397::1223: 0.07:1:0.882;

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n06402

ATH06n06403

ATH06n06600

ATH06n06936

ATH06n06939

ATH07n07291

ATH07n07294

ATH07n08006

ATH07n08009

ATH08n09779

ATH08n09780

ATH08n09783

ATH08n10434

ATH08n10675

ATH09n09900

ATH09n10156

ATH09n10553

ATH09n10993

ATH10n06881

ATH10n06884

ATH10n07535

ATH10n07985

ATH11n05853

ATH11n05856

ATH11n06520

ATH11n06523

ATH12n05407

ATH12n05410

ATH12n05840

ATH12n05843

ATH13n09042

ATH13n09045

ATH13n09703

ATH13n09706

ATH14n08685

ATH14n08688

ATH14n09462

ATH14n09465

ATH56n11400

ATH56n11403

ATH56n12113

ATH56n12116

ATH57n11242

ATH57n11755

ATH57n12017

ATH57n12278

ATH58n12062

ATH58n12065

ATH58n12316

ATH58n12319

ATH59n11181

ATH59n11440

ATH59n11927

ATH59n12428

ATH60n11066

ATH60n11069

ATH60n11813

ATH60n12282

ATH61n10250

ATH61n10503

ATH61n10975

ATH61n10978

ATH62n10556

ATH62n10559

ATH62n11251

ATH62n11254

ATH63n10713

ATH63n11237

ATH63n11488

ATH63n11491

ATH64n10711

ATH64n10968

ATH64n11431

ATH64n11688

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 7.7286 8.9319 17.1776 14.7865 12.1562
ATGE_7 36.7243 37.83 40.5912 29.4395 36.1462
ATGE_9 5.3073 5.9909 3.5254 0.5522 3.8439
ATGE_10 15.1538 10 22.4215 16.2398 15.9538
ATGE_12 8.1631 6.0972 7.3869 6.3347 6.9955
ATGE_13 9.8965 6.4909 6.5312 50.8608 18.4448
ATGE_14 12.6839 16.6939 9.2994 14.4319 13.2773
ATGE_15 53.3343 39.1414 15.3743 21.9455 32.4489
ATGE_16 61.0143 47.4777 59.8783 65.7159 58.5215
ATGE_19 3.6365 2.2712 5.1017 2.6177 3.4068
ATGE_20 13.4904 37.2145 26.6401 34.7436 28.0221
ATGE_21 33.86 56.0857 49.5917 36.0147 43.888
ATGE_25 8.3172 6.2777 8.9858 8.9106 8.1228
ATGE_26 23.3731 30.7074 15.2831 38.2309 26.8986
ATGE_27 9.579 9.7418 10.1247 37.2893 16.6837
ATGE_28 4.6904 7.713 3.0353 12.0361 6.8687
ATGE_29 102.9926 148.0425 102.9602 94.0241 112.0049
ATGE_32 101.7648 108.4741 81.161 76.4872 91.9718
ATGE_33 92.0529 105.454 96.55 101.0706 98.7819
ATGE_39 90.2538 109.7297 108.1195 78.8589 96.7405
ATGE_41 33.0167 36.4256 30.7172 30.7172 32.7192
ATGE_42 107.6738 67.2484 62.9243 89.0333 81.7199
ATGE_45 77.7367 68.8901 61.607 71.1352 69.8422
ATGE_76 38.8444 8.6094 43.7346 44.6407 33.9573
ATGE_77 40.7128 38.3722 37.3994 33.8231 37.5769
ATGE_78 50.4461 6.7914 4.6486 6.7378 17.156
ATGE_84 51.1492 52.953 54.7362 52.1453 52.7459
ATGE_91 3.8085 5.933 3.7173 6.1901 4.9122
ATGE_92 78.6791 75.5103 88.4835 67.1004 77.4433
ATGE_93 69.4822 66.6457 66.5583 54.007 64.1733
ATGE_95 100.8511 88.7729 81.8886 61.435 83.2369
ATGE_96 9.8789 9.3044 8.4608 8.9208 9.1412
ATGE_97 9.9532 15.4227 19.5303 19.2076 16.0284
ATGE_98 41.1032 93.1413 47.14 44.5334 56.4795
ATGE_99 59.9223 53.0288 39.9093 24.9287 44.4473
ATGE_101 4.1292 2.0277 2.8976 3.5118 3.1416
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch