AtMetExpress Development LC-MS

Perk Nr:adn060875.

Polarity: [NEGATIVE]
Retention time: 3.72
m/z: 739
Annotation:
Annotation level: Unknown
compound: Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside
MS2Ts 31 MS2Ts
KNApSAcK C33H41O19(24):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(18):C32H42N2O17S-H2O;
C44H37O11(13):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C35H37N2O16(13):C35H36N2O15+O;
C36H37O17(4):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
in-house MS/MS Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_30V(24)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_30V(24)
Keracyanin Chloride_Ramp5-45 V(22)
Robinin_30V(21)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE10(19)
kaempferol-7-O-neohesperidoside_CE10(19)
Poncirin_CE20(19)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE10(18)
Datiscin_CE20(17)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(15)
Poncirin_CE10(14)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE10(14)
6,8,-C-dihexosylapigenin(13)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(12)
Datiscin_CE10(12)
Tiliroside_Ramp5-45 V(12)
kaempferol-7-O-neohesperidoside_CE30(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(9)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(8)
kaempferol-3-O-rutinoside_CE40(8)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE10(7)
Kaempferol-3-Glucoside-6-p-coumaroyl_Ramp5-45 V(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(7)
kaempferol-7-O-neohesperidoside_CE20(7)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE10(7)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE20(6)
kaempferol-7-O-neohesperidoside_CE30(6)
kaempferol-3-O-rutinoside_CE10(6)
kaempferol-7-O-neohesperidoside_CE10(6)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE10(6)
kaempferol-7-O-neohesperidoside_CE20(5)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE10(5)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE20(5)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n09165

ATH07n10649

ATH08n12827

ATH08n12830

ATH09n12795

ATH09n13028

ATH10n10016

ATH11n07880

ATH11n08082

ATH12n07172

ATH12n07289

ATH13n12495

ATH14n11263

ATH14n11266

ATH56n14939

ATH56n14942

ATH57n15080

ATH57n15083

ATH58n15319

ATH58n15322

ATH59n14822

ATH59n15083

ATH60n14764

ATH60n14767

ATH61n13906

ATH61n14158

ATH62n14101

ATH62n14104

ATH63n15031

ATH64n14037

ATH64n14498

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 3.9145 6.5062 4.4318 4.65 4.8756
ATGE_7 38.015 42.1059 34.4087 29.1 35.9074
ATGE_9 2.1894 4.4988 2.8418 0.5522 2.5205
ATGE_10 35.4588 12.9659 35.7209 36.9776 30.2808
ATGE_12 5.9732 4.8054 4.8513 4.8819 5.128
ATGE_13 9.5192 6.9698 6.8437 61.5489 21.2204
ATGE_14 15.2261 18.0737 10.0807 14.3664 14.4367
ATGE_15 77.8609 52.2929 45.4974 69.6039 61.3138
ATGE_16 108.375 84.349 108.9294 107.4919 102.2863
ATGE_19 4.5463 7.578 6.8142 7.4455 6.596
ATGE_20 38.6657 56.1295 38.1825 48.1491 45.2817
ATGE_21 41.9271 83.0942 77.3232 46.4779 62.2056
ATGE_25 22.4035 7.4419 7.8611 7.4783 11.2962
ATGE_26 64.1829 61.2579 65.5261 69.2457 65.0531
ATGE_27 10.1849 9.0125 23.7739 31.2297 18.5502
ATGE_28 9.378 11.6753 4.0923 10.4409 8.8966
ATGE_29 154.1009 180 154.1637 134.5626 155.7068
ATGE_32 123.5824 142.7478 110.123 100.8356 119.3222
ATGE_33 147.3174 165.0724 153.1217 168.5654 158.5192
ATGE_39 155.2128 181.5959 189.1516 147.5915 168.3879
ATGE_41 22.4644 36.2837 13.1355 13.1355 21.2548
ATGE_42 213.6738 137 120.4558 186.1857 164.3288
ATGE_45 75.4253 54.8251 61.1922 70.0354 65.3695
ATGE_76 36.9617 8.3059 44.3979 48.5809 34.5616
ATGE_77 34.5618 33.7424 37.0234 36.7449 35.5181
ATGE_78 40.9296 40.068 7.1842 11.4007 24.8956
ATGE_84 0.3271 0.4046 0.4334 0.3358 0.3752
ATGE_91 6.5691 4.7559 3.8543 10.7333 6.4781
ATGE_92 140.3955 128.2487 140.7139 139.8161 137.2935
ATGE_93 44.6539 57.3581 55.6725 41.9672 49.9129
ATGE_95 32.9086 13.2576 24.6295 9.0889 19.9711
ATGE_96 1.9106 1.3044 0.9692 3.0633 1.8119
ATGE_97 5.1231 7.9457 14.6408 13.1871 10.2242
ATGE_98 25.4438 79.662 10.5405 26.9023 35.6372
ATGE_99 53.223 50.0576 42.0327 59.2239 51.1343
ATGE_101 7.4054 4.4513 5.1976 5.1424 5.5492
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch