AtMetExpress Development LC-MS

Perk Nr:adn060881.

Polarity: [NEGATIVE]
Retention time: 4.19
m/z: 739
Annotation:
Annotation level: Unknown
compound:
MS2Ts 30 MS2Ts
KNApSAcK C33H41O19(24):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(18):C32H42N2O17S-H2O;
C35H37N2O16(14):C35H36N2O15+O;
C44H37O11(12):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C37H41O16(4):C37H40O15+O;
in-house MS/MS Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(13)
apigenin-7-O-glucoside_CE20(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(9)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(9)
kaempferol-7-O-neohesperidoside_CE10(9)
kaempferol-3-O-rutinoside(8)
Robinin_30V(8)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_Ramp5-45 V(7)
Poncirin_CE20(7)
Keracyanin Chloride_Ramp5-45 V(7)
Kaempferol-3-Glucoside-6-p-coumaroyl_Ramp5-45 V(6)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(6)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE10(6)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE10(6)
Datiscin_Ramp5-45 V(6)
Datiscin_CE20(6)
Poncirin_Ramp5-45 V(6)
kaempferol-7-O-neohesperidoside_CE30(6)
Kaempferol-3-Rhamnoside-4''-Rhamnoside-7-Rhamnoside_CE60(6)
kaempferol-3-O-rutinoside_Ramp5-45 V(6)
Kaempferol O-rhamnosylhexoside(6)
Tiliroside_Ramp5-45 V(6)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(6)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(5)
Poncirin_CE10(5)
kaempferol-3-O-rutinoside_CE40(5)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE10(5)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(5)
6,8,-C-dihexosylapigenin(5)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(5)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(4)
Rhamnosyl Kaempferol(4)
kaempferol(4)
Maritimein_CE40(4)
kaempferol 3-O-sophoroside(4)
Kaempferol 3-rhamnoglucoside(4)
Luteolin_CE10(4)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(4)
luteolin-7-O-rutinoside(4)
kaempferol-7-O-neohesperidoside_CE30(4)
luteolin-7-O-rutinoside(4)
kaempferol 3-O-rutinoside(4)
7-O-Deoxyhexosyl(1,2)hexosylluteolin(4)
Kaempferol 7-O-robinoside(4)
Kaempferol-3-Glucoside-2-p-coumaroyl,-7-Glucoside_Ramp5-45 V(4)
Datiscin_30V(4)
kaempferol 3-O-gentiobioside(4)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(4)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_30V(4)
Datiscin_CE50(4)
Kaempferol(4)
Glucosyl Rhamnosyl Kaempferol(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(4)
kaempferol 7-O-rhamnoside(4)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(4)
Datiscin_CE10(4)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE60(4)
kaempferol-7-O-neohesperidoside_CE40(4)
Poncirin_30V(4)
kaempferol-7-O-neohesperidoside_CE60(4)
luteolin 7-O-allosylglucoside(4)
Luteolin_CE30(4)
kaempferol-7-O-neohesperidoside_30V(4)
Poncirin_CE50(4)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE40(4)
Maritimein_CE30(4)
kaempferol 3-O-rutinoside(4)
kaempferol-7-O-neohesperidoside_CE40(4)
Glucosyl Rhamnosyl Kaempferol(4)
kaempferol-7-O-neohesperidoside(4)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(4)
Kaempferol(4)
Vitexin_CE20(4)
kaempferol(4)
luteolin-4'-O-glucoside_CE30(4)
Datiscin_CE40(4)
Kaempferol-3-Glucoside-2-p-coumaroyl_Ramp5-45 V(4)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(4)
luteolin-4'-O-glucoside_Ramp5-45 V(4)
kaempferol 3-O-robinoside(4)
Luteolin_CE20(4)
kaempferol-3-glucoside(4)
kaempferol-7-O-neohesperidoside(4)
luteolin-4'-O-glucoside_CE40(4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n09174

ATH06n09177

ATH07n10659

ATH07n11099

ATH08n12836

ATH08n12839

ATH09n12807

ATH09n13034

ATH10n10026

ATH11n07890

ATH11n07997

ATH12n07182

ATH13n12736

ATH14n11272

ATH56n14948

ATH56n14951

ATH57n15343

ATH57n15605

ATH58n15328

ATH58n15331

ATH59n15338

ATH59n15341

ATH60n14775

ATH61n13918

ATH61n14164

ATH62n14110

ATH62n14113

ATH63n14790

ATH64n14047

ATH64n14292

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0125 0.0075 0.0061 0.0057 0.008
ATGE_7 0.0075 0.0073 0.0154 0.0093 0.0099
ATGE_9 0.28 0.7042 0.3954 0.0487 0.3571
ATGE_10 0.0079 0.0068 0.0794 0.0691 0.0408
ATGE_12 0.008 0.1783 0.0092 0.0064 0.0505
ATGE_13 0.006 0.006 0.0078 0.0077 0.0069
ATGE_14 0.0081 0.0109 0.0625 0.0549 0.0341
ATGE_15 0.0118 0.0075 0.0527 0.1089 0.0452
ATGE_16 0.1004 0.0074 0.0145 0.0069 0.0323
ATGE_19 0.0077 0.0164 0.0076 0.0075 0.0098
ATGE_20 0.0821 0.006 0.0796 0.0063 0.0435
ATGE_21 0.1137 0.0085 0.0986 0.0073 0.057
ATGE_25 0.0043 0.0075 0.0084 0.0086 0.0072
ATGE_26 0.0073 0.0039 0.006 0.0073 0.0061
ATGE_27 0.0072 0.0075 0.0054 0.0063 0.0066
ATGE_28 0.0082 0.0086 0.0058 0.0072 0.0075
ATGE_29 0.0073 0.0063 0.0074 0.0065 0.0069
ATGE_32 2.7648 0.0064 0.0067 0.0058 0.6959
ATGE_33 0.0079 3.2701 2.6913 0.0078 1.4943
ATGE_39 0.0076 0.0075 0.0174 0.0123 0.0112
ATGE_41 0.2447 0.6003 0.007 0.007 0.2147
ATGE_42 1.1727 0.0063 0.0054 0.0071 0.2979
ATGE_45 2.6151 0.0112 0.8279 0.0066 0.8652
ATGE_76 0.0071 0.0074 0.0061 0.0066 0.0068
ATGE_77 0.0123 0.0064 0.0182 0.0115 0.0121
ATGE_78 0.0065 0.3404 0.2137 0.4044 0.2413
ATGE_84 0.0102 0.0078 0.0078 1.7694 0.4488
ATGE_91 0.3218 0.374 0.1199 0.2765 0.273
ATGE_92 0.0074 0.0077 0.0075 0.0073 0.0075
ATGE_93 12.8746 9.9647 7.5837 7.4042 9.4568
ATGE_95 14.5979 7.5714 11.92 7.9519 10.5103
ATGE_96 0.3594 0.5433 0.5391 0.4722 0.4785
ATGE_97 0.5517 1.0054 0.011 0.0087 0.3942
ATGE_98 4.6811 16.662 7.167 6.8408 8.8377
ATGE_99 9.9323 10.4206 11.8413 8.1603 10.0886
ATGE_101 0.0113 0.1134 0.1333 0.0079 0.0664
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch