AtMetExpress Development LC-MS

Perk Nr:adn060882. Quercetin-triRha

Polarity: [NEGATIVE]
Retention time: 4.24
m/z: 739
Annotation: Quercetin-triRha
Annotation level: Characterized
compound:
MS2Ts 29 MS2Ts
KNApSAcK C33H41O19(24):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(16):C32H42N2O17S-H2O;
C44H37O11(12):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C35H37N2O16(12):C35H36N2O15+O;
C37H41O16(4):C37H40O15+O;
in-house MS/MS Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(13)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(11)
apigenin-7-O-glucoside_CE20(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(9)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_Ramp5-45 V(9)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(8)
Datiscin_Ramp5-45 V(8)
Poncirin_Ramp5-45 V(8)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(8)
Rhamnosyl Kaempferol(7)
luteolin-7-O-rutinoside(7)
kaempferol 3-O-rutinoside(7)
7-O-Deoxyhexosyl(1,2)hexosylluteolin(7)
Kaempferol 7-O-robinoside(7)
Kaempferol-3-Glucoside-2-p-coumaroyl,-7-Glucoside_Ramp5-45 V(7)
Datiscin_30V(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_30V(7)
Glucosyl Rhamnosyl Kaempferol(7)
kaempferol 7-O-rhamnoside(7)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(7)
kaempferol-7-O-neohesperidoside_CE40(7)
Poncirin_30V(7)
Luteolin_CE30(7)
kaempferol-7-O-neohesperidoside_30V(7)
Poncirin_CE50(7)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE40(7)
kaempferol 3-O-rutinoside(7)
kaempferol-7-O-neohesperidoside_CE40(7)
Glucosyl Rhamnosyl Kaempferol(7)
Kaempferol O-rhamnosylhexoside(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(7)
Datiscin_CE40(7)
Kaempferol-3-Glucoside-2-p-coumaroyl_Ramp5-45 V(7)
luteolin-4'-O-glucoside_Ramp5-45 V(7)
kaempferol 3-O-robinoside(7)
kaempferol-7-O-neohesperidoside(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(6)
kaempferol(6)
Kaempferol 3-rhamnoglucoside(6)
Luteolin_CE10(6)
luteolin-7-O-rutinoside(6)
kaempferol 3-O-gentiobioside(6)
Kaempferol(6)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE60(6)
Kaempferol(6)
kaempferol(6)
luteolin-4'-O-glucoside_CE30(6)
kaempferol-3-glucoside(6)
Maritimein_CE40(5)
kaempferol 3-O-sophoroside(5)
Datiscin_CE50(5)
kaempferol-7-O-neohesperidoside_CE60(5)
luteolin 7-O-allosylglucoside(5)
Maritimein_CE30(5)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_30V(5)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE20(5)
kaempferol-7-O-neohesperidoside(5)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_30V(5)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(5)
Luteolin_CE20(5)
luteolin-4'-O-glucoside_CE40(5)
isoscutellarein 7-O-allosylglucoside(4)
Kaempferol-3-Glucoside-6-p-coumaroyl_Ramp5-45 V(4)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(4)
kaempferol-3-O-rutinoside_CE40(4)
Poncirin_CE60(4)
Maritimein_Ramp5-45 V(4)
kaempferol-7-O-neohesperidoside_CE30(4)
kaempferol-3-O-rutinoside_Ramp5-45 V(4)
Kaempferol-3-Glucuronide_Ramp5-45 V(4)
kaempferol-7-O-neohesperidoside_CE10(4)
Tiliroside_Ramp5-45 V(4)
Vitexin_CE20(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(4)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(4)
Keracyanin Chloride_Ramp5-45 V(4)
Poncirin_CE10(3)
Luteolin(3)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(3)
kaempferol-7-O-neohesperidoside_CE30(3)
Robinin_30V(3)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE10(3)
kaempferol-7-O-neohesperidoside_CE60(3)
Poncirin_CE20(3)
kaempferol-7-O-neohesperidoside_CE50(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n09174

ATH06n09177

ATH07n10659

ATH07n10662

ATH08n12839

ATH08n12842

ATH09n12807

ATH09n13034

ATH10n10026

ATH10n10029

ATH11n07890

ATH12n07182

ATH12n07185

ATH13n12736

ATH14n11272

ATH56n14948

ATH56n14951

ATH57n15093

ATH57n15605

ATH58n15328

ATH58n15331

ATH59n15341

ATH60n14775

ATH61n13918

ATH61n14164

ATH62n14110

ATH62n14113

ATH63n14790

ATH64n14047

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.4648 0.3904 0.5247 0.4538 0.4584
ATGE_7 1.4711 1.0467 1.6323 1.1441 1.3236
ATGE_9 0.0063 0.0067 0.0084 0.0069 0.0071
ATGE_10 0.7771 0.5374 0.6659 0.75 0.6826
ATGE_12 0.3743 0.0081 0.2352 0.2918 0.2273
ATGE_13 0.501 0.2957 0.3151 1.9072 0.7547
ATGE_14 0.5204 0.8579 0.6041 0.7382 0.6801
ATGE_15 1.9911 0.9974 0.6482 0.74 1.0942
ATGE_16 0.7336 1.7722 2.0535 0.9168 1.369
ATGE_19 0.1185 0.115 0.145 0.1316 0.1275
ATGE_20 1.1917 0.5566 1.1902 1.3004 1.0597
ATGE_21 1.3965 0.8857 0.8383 1.4117 1.133
ATGE_25 0.3099 0.2398 0.3597 0.3919 0.3253
ATGE_26 0.7219 0.5465 0.4859 0.9778 0.683
ATGE_27 0.6009 0.5814 0.6202 1.4574 0.815
ATGE_28 0.2904 0.4753 0.0746 0.6795 0.3799
ATGE_29 1.5049 1.0595 1.4119 1.2835 1.3149
ATGE_32 0.0131 1.0344 1.2953 1.1272 0.8675
ATGE_33 1.5767 0.0111 0.0173 1.2774 0.7206
ATGE_39 1.5256 1.2853 3.3702 2.5024 2.1709
ATGE_41 0.5167 0.0051 0.8621 0.8621 0.5615
ATGE_42 0.0064 1.3545 1.1981 1.0976 0.9142
ATGE_45 0.0101 2.2466 0.005 0.9068 0.7921
ATGE_76 0.8851 0.5373 0.9367 0.7139 0.7682
ATGE_77 1.6386 1.4047 1.543 1.4898 1.519
ATGE_78 0.7934 0.0063 0.0073 0.0112 0.2045
ATGE_84 1.6564 0.8772 0.8381 0.015 0.8467
ATGE_91 0.0106 0.0059 0.0064 0.0074 0.0075
ATGE_92 1.4875 1.4533 1.5493 0.9509 1.3603
ATGE_93 0.0136 0.0058 0.0076 0.007 0.0085
ATGE_95 0.0156 0.0076 0.0121 0.0072 0.0106
ATGE_96 0.0055 0.0078 0.0083 0.0079 0.0074
ATGE_97 0.0073 0.0081 1.1629 1.0789 0.5643
ATGE_98 0.0054 0.0103 0.0073 0.0054 0.0071
ATGE_99 0.0075 0.0072 0.0151 0.0101 0.01
ATGE_101 0.2697 0.0069 0.0071 0.2189 0.1257
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch