AtMetExpress Development LC-MS

Perk Nr:adn060883. Kaempferol-Hex-diRha

Polarity: [NEGATIVE]
Retention time: 4.33
m/z: 739
Annotation: Kaempferol-Hex-diRha
Annotation level: Characterized
compound:
MS2Ts 29 MS2Ts
KNApSAcK C33H41O19(27):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(19):C32H42N2O17S-H2O;
C44H37O11(14):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C35H37N2O16(13):C35H36N2O15+O;
C37H41O16(5):C37H40O15+O;
in-house MS/MS Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(15)
Kaempferol-3-Rhamnoside-4''-Rhamnoside-7-Rhamnoside_CE60(14)
kaempferol-3-O-rutinoside(12)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_Ramp5-45 V(12)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(11)
Rhamnosyl Kaempferol(11)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(11)
luteolin-7-O-rutinoside(11)
kaempferol 3-O-rutinoside(11)
7-O-Deoxyhexosyl(1,2)hexosylluteolin(11)
Datiscin_Ramp5-45 V(11)
Kaempferol 7-O-robinoside(11)
Kaempferol-3-Glucoside-2-p-coumaroyl,-7-Glucoside_Ramp5-45 V(11)
Datiscin_30V(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_30V(11)
Poncirin_Ramp5-45 V(11)
Glucosyl Rhamnosyl Kaempferol(11)
kaempferol 7-O-rhamnoside(11)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_30V(11)
kaempferol-7-O-neohesperidoside_CE40(11)
Poncirin_30V(11)
kaempferol-7-O-neohesperidoside_30V(11)
Poncirin_CE50(11)
kaempferol 3-O-rutinoside(11)
kaempferol-7-O-neohesperidoside_CE40(11)
Glucosyl Rhamnosyl Kaempferol(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(11)
Datiscin_CE40(11)
Kaempferol-3-Glucoside-2-p-coumaroyl_Ramp5-45 V(11)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(11)
luteolin-4'-O-glucoside_Ramp5-45 V(11)
kaempferol 3-O-robinoside(11)
kaempferol-7-O-neohesperidoside(11)
kaempferol(10)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(9)
apigenin-7-O-glucoside_CE20(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(9)
Kaempferol O-rhamnosylhexoside(9)
luteolin-4'-O-glucoside_CE30(9)
Maritimein_CE40(8)
kaempferol 3-O-sophoroside(8)
Datiscin_CE50(8)
kaempferol-7-O-neohesperidoside_CE60(8)
luteolin 7-O-allosylglucoside(8)
Maritimein_CE30(8)
kaempferol-7-O-neohesperidoside(8)
Kaempferol-3,7-O-di-rhamnopyranoside_CE50(8)
Luteolin_CE20(8)
luteolin-4'-O-glucoside_CE40(8)
isoscutellarein 7-O-allosylglucoside(7)
Maritimein_Ramp5-45 V(7)
Kaempferol-3-Glucuronide_Ramp5-45 V(7)
Poncirin_CE60(6)
Luteolin(5)
kaempferol-7-O-neohesperidoside_CE60(5)
kaempferol-7-O-neohesperidoside_CE50(5)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_30V(4)
Poncirin_CE40(4)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_30V(4)
Vitexin_CE20(4)
luteolin-4'-O-glucoside_CE50(3)
Robinin_30V(3)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE20(3)
kaempferol-7-O-neohesperidoside_CE10(3)
Scutellarein(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n09177

ATH07n10659

ATH07n10662

ATH08n12839

ATH08n12842

ATH09n12807

ATH10n10026

ATH10n10029

ATH11n07890

ATH11n07893

ATH12n07182

ATH12n07185

ATH13n12736

ATH14n11505

ATH56n14951

ATH57n15093

ATH57n15605

ATH58n15331

ATH58n15334

ATH59n14836

ATH59n15341

ATH60n14775

ATH60n14778

ATH61n13918

ATH61n13921

ATH62n14113

ATH62n14116

ATH63n14790

ATH64n14047

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0125 0.0075 0.0061 0.0057 0.008
ATGE_7 0.0075 0.0073 0.0154 0.0093 0.0099
ATGE_9 0.0252 0.0067 0.0084 0.0069 0.0118
ATGE_10 0.2466 0.1859 0.167 0.1585 0.1895
ATGE_12 0.3155 0.3945 0.3684 0.2596 0.3345
ATGE_13 0.3387 0.2515 0.3723 0.536 0.3746
ATGE_14 0.2915 0.2349 0.2994 0.1989 0.2562
ATGE_15 0.0118 0.3232 0.3291 0.3044 0.2421
ATGE_16 0.3934 0.2599 0.0145 0.3764 0.261
ATGE_19 0.0489 0.0164 0.0687 0.0075 0.0354
ATGE_20 0.0082 0.2429 0.1773 0.0063 0.1087
ATGE_21 0.3644 0.6257 0.5013 0.4117 0.4758
ATGE_25 1.5643 1.2525 1.3767 1.0172 1.3027
ATGE_26 1.1317 1.492 0.9397 0.7911 1.0886
ATGE_27 0.1435 0.1253 0.1916 0.2361 0.1741
ATGE_28 0.1589 0.1391 0.2003 0.2481 0.1866
ATGE_29 1.128 1.2127 1.2456 1.0901 1.1691
ATGE_32 0.0131 0.8383 0.5906 0.6125 0.5136
ATGE_33 0.7037 0.0111 0.0173 0.8507 0.3957
ATGE_39 0.8435 0.7702 0.0204 0.0148 0.4122
ATGE_41 0.5502 0.448 0.6214 0.6214 0.5603
ATGE_42 0.6544 0.6496 0.6198 0.7309 0.6637
ATGE_45 0.0101 0.0112 0.005 0.0066 0.0082
ATGE_76 0.0071 0.0074 0.0061 0.0066 0.0068
ATGE_77 0.0123 0.0064 0.0182 0.0086 0.0114
ATGE_78 0.0065 0.3531 0.1056 0.1872 0.1631
ATGE_84 0.0081 0.0078 0.0078 0.015 0.0097
ATGE_91 0.1117 0.2519 0.137 0.1975 0.1745
ATGE_92 0.8606 0.8031 0.9088 0.5 0.7681
ATGE_93 0.0136 0.0058 0.0076 0.007 0.0085
ATGE_95 0.0156 0.0076 0.0121 0.0072 0.0106
ATGE_96 0.0055 0.0078 0.0083 0.0079 0.0074
ATGE_97 0.0073 0.1544 0.011 0.0087 0.0454
ATGE_98 0.0054 0.0103 0.0073 0.0054 0.0071
ATGE_99 0.0075 0.0072 0.0151 0.0101 0.01
ATGE_101 0.3134 0.1643 0.169 0.2189 0.2164
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch