AtMetExpress Development LC-MS

Perk Nr:adn062743. Kaempferol-diHex-Rha

Polarity: [NEGATIVE]
Retention time: 3.17
m/z: 755
Annotation: Kaempferol-diHex-Rha
Annotation level: Characterized
compound:
MS2Ts 15 MS2Ts
KNApSAcK C40H37O15(8):C40H36O16-O; C39H34O14+CH3O; C34H26O10+C6H10O5; C4
C33H41O20(7):Luteolin 7-rutinoside-3'-glucoside, Luteolin 7-rut
C44H37O12(4):Guibourtinidol-(4alpha->2)-3,5,3',4'-tetrahydroxys
C35H37N2O17(4):C34H34N2O16+CH3O;
C34H45O19(2):Myricoside, 7,4'-Dihydroxy-5-methoxyflavanone 7-ne
C33H45N2O16S1(2):C33H44N2O17S-O;
in-house MS/MS Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE20(9)
Poncirin_CE10(9)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE10(9)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE10(9)
Datiscin_CE20(9)
Robinin_30V(9)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE10(9)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(9)
Datiscin_CE10(9)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_30V(9)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE20(9)
kaempferol-7-O-neohesperidoside_CE10(9)
Poncirin_CE20(9)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_30V(9)
6,8,-C-dihexosylapigenin(9)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(7)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE20(7)
Keracyanin Chloride_Ramp5-45 V(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(6)
kaempferol-7-O-neohesperidoside_CE20(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE10(6)
Kaempferol 3-O-robinoside-7-O-rhamnoside(5)
O-hexosyl-2''-O-rhamnosyl-C-hexosylluteolin(5)
2-Glucosyl?Rhamnosyl Kaempferol(5)
2-Glucosyl?Rhamnosyl Kaempferol(5)
2-Rhamnosyl?Glucosyl Kaempferol(5)
O-hexosyl-2''-O-rhamnosyl-6-C-hexosyluteolin(5)
2-Rhamnosyl?Glucosyl Kaempferol(5)
Coumaroyl?Glucosyl?Rhamnosyl Kaempferol(5)
2-Rhamnosyl?Glucosyl Kaempferol(5)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE10(4)
kaempferol-7-O-neohesperidoside_CE20(4)
kaempferol-7-O-neohesperidoside_CE30(4)
kaempferol-3-O-rutinoside_CE10(4)
kaempferol-7-O-neohesperidoside_CE10(4)
kaempferol-7-O-neohesperidoside_CE30(4)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE10(4)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE30(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(3)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE10(3)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE10(3)
Datiscin_CE30(3)
Tiliroside_Ramp5-45 V(3)
Kaempferol-3-Glucoside-6-p-coumaroyl_Ramp5-45 V(2)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(2)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE30(2)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(2)
kaempferol-3-O-rutinoside_CE40(2)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(2)
Poncirin_CE30(2)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE20(2)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE20(2)
kaempferol-3-O-rutinoside_CE20(2)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE20(2)
Robinin_CE50(2)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(2)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06n09154

ATH08n12817

ATH08n12821

ATH10n10414

ATH12n07280

ATH14n11480

ATH56n14928

ATH57n15069

ATH58n15308

ATH59n15318

ATH60n15259

ATH61n14390

ATH62n14343

ATH62n14578

ATH64n14273

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0075 0.0075 0.0082 0.0057 0.0072
ATGE_7 0.035 0.0147 0.0411 0.0139 0.0262
ATGE_9 0.0063 0.0067 0.0084 0.0069 0.0071
ATGE_10 0.0159 0.0181 0.0224 0.006 0.0156
ATGE_12 0.0187 0.0297 0.0092 0.0257 0.0208
ATGE_13 0.0223 0.006 0.0312 0.067 0.0316
ATGE_14 0.0354 0.0081 0.0104 0.0445 0.0246
ATGE_15 0.0828 0.0505 0.0326 0.0346 0.0501
ATGE_16 0.1065 0.0915 0.1192 0.0877 0.1012
ATGE_19 0.0128 0.0246 0.0229 0.0075 0.017
ATGE_20 0.0438 0.0425 0.0488 0.0546 0.0474
ATGE_21 0.0495 0.0885 0.063 0.0563 0.0643
ATGE_25 0.0614 0.0303 0.0481 0.0547 0.0486
ATGE_26 0.0731 0.1103 0.0823 0.0786 0.0861
ATGE_27 0.0243 0.01 0.0235 0.0404 0.0245
ATGE_28 0.0082 0.0086 0.0196 0.0265 0.0157
ATGE_29 0.1502 0.1808 0.1339 0.1252 0.1475
ATGE_32 0.1296 0.1939 0.1722 0.1135 0.1523
ATGE_33 0.4126 0.3676 0.4065 0.4424 0.4073
ATGE_39 0.5487 0.553 0.481 0.3465 0.4823
ATGE_41 0.0188 0.0224 0.0186 0.0186 0.0196
ATGE_42 1.2613 0.7494 0.7675 0.9309 0.9273
ATGE_45 0.0531 0.0112 0.0101 0.0133 0.0219
ATGE_76 0.0478 0.0074 0.0163 0.031 0.0256
ATGE_77 0.0123 0.0086 0.0182 0.0608 0.025
ATGE_78 0.0329 0.0702 0.0073 0.0112 0.0304
ATGE_84 0.0081 0.0078 0.0078 0.0075 0.0078
ATGE_91 0.0079 0.0236 0.0085 0.0123 0.0131
ATGE_92 0.3184 0.2746 0.3215 0.3137 0.307
ATGE_93 0.1226 0.1115 0.1142 0.0864 0.1087
ATGE_95 0.0704 0.0535 0.0096 0.0072 0.0352
ATGE_96 0.0111 0.0104 0.0083 0.0079 0.0094
ATGE_97 0.0073 0.0271 0.0414 0.0087 0.0211
ATGE_98 0.0307 0.162 0.0073 0.0452 0.0613
ATGE_99 0.1177 0.0865 0.0125 0.1221 0.0847
ATGE_101 0.0371 0.0069 0.0142 0.0343 0.0231
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch