AtMetExpress Development LC-MS

Perk Nr:adn128021.

Polarity: [NEGATIVE]
Retention time: 4.26
m/z: 1187
Annotation:
Annotation level: Unknown
compound: "Quercetin-3,7-O-alpha-L-dirhamnopyranoside: Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside"
MS2Ts 11 MS2Ts
KNApSAcK
in-house MS/MS Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE10(11)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE20(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(11)
kaempferol-7-O-neohesperidoside_CE20(11)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE30(11)
Poncirin_CE10(11)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(11)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE10(11)
kaempferol-7-O-neohesperidoside_CE20(11)
kaempferol-7-O-neohesperidoside_CE30(11)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE10(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE10(11)
Datiscin_CE20(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(11)
kaempferol-3-O-rutinoside_CE10(11)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(11)
Robinin_30V(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE10(11)
Poncirin_CE30(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(11)
kaempferol-7-O-neohesperidoside_CE10(11)
kaempferol-7-O-neohesperidoside_CE30(11)
Datiscin_CE10(11)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE20(11)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE20(11)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE10(11)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE10(11)
kaempferol-3-O-rutinoside_CE20(11)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_30V(11)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE20(11)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE10(11)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE20(11)
Robinin_CE50(11)
Kaempferol-3-Glucoside-2''-p-coumaroyl_CE20(11)
kaempferol-7-O-neohesperidoside_CE10(11)
Poncirin_CE20(11)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_30V(11)
6,8,-C-dihexosylapigenin(11)
Kaempferol-3-Glucoside-6''-p-coumaroyl_CE30(11)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(11)
Kaempferol 3-O-robinoside-7-O-rhamnoside(9)
O-hexosyl-2''-O-rhamnosyl-C-hexosylluteolin(9)
2-Glucosyl?Rhamnosyl Kaempferol(9)
2-Glucosyl?Rhamnosyl Kaempferol(9)
2-Rhamnosyl?Glucosyl Kaempferol(9)
O-hexosyl-2''-O-rhamnosyl-6-C-hexosyluteolin(9)
2-Rhamnosyl?Glucosyl Kaempferol(9)
Coumaroyl?Glucosyl?Rhamnosyl Kaempferol(9)
2-Rhamnosyl?Glucosyl Kaempferol(9)
kaempferol-3-O-rutinoside_CE30(7)
Datiscin_CE30(4)
Represetative peak adn095730::996: 0.202:2:0.844; adn156914::1484: 0.204:2:0.829; adn157011::1485: 0.536:2:0.828;

eFP visualizaion


Raw chromatograms


MS2Ts

ATH56n19126

ATH56n19129

ATH57n19508

ATH58n19691

ATH58n19694

ATH59n19078

ATH60n18977

ATH61n18014

ATH62n17958

ATH63n18781

ATH64n17488

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.1959 0.4408 1.188 0.9884 0.7033
ATGE_7 2.3157 4.0911 2.748 1.5209 2.6689
ATGE_9 0.0968 0.1128 0.0254 0.0069 0.0605
ATGE_10 2.3023 1.2879 2.2545 3.4227 2.3169
ATGE_12 0.4331 0.0918 0.1083 0.3004 0.2334
ATGE_13 1.2555 0.3802 0.2864 3.4871 1.3523
ATGE_14 0.9073 0.3606 1 0.4162 0.671
ATGE_15 3.639 4.5555 1.3517 3.0668 3.1532
ATGE_16 5.5 3.7945 6.5036 2.9284 4.6816
ATGE_19 0.0154 0.0082 0.0687 0.0177 0.0275
ATGE_20 1.2986 1.7246 1.1645 2.0525 1.56
ATGE_21 1.8542 3.7628 2.8904 2.1519 2.6648
ATGE_25 1.1067 0.2398 0.4872 0.4956 0.5823
ATGE_26 2.2512 3.2034 0.4899 4.4471 2.5979
ATGE_27 0.9513 1.0325 1.8806 2.6553 1.6299
ATGE_28 0.0547 0.1681 0.0235 1.4506 0.4242
ATGE_29 58.6354 34.4 61.2059 54.8571 52.2746
ATGE_32 43.0021 54.9568 36.7651 40.8747 43.8997
ATGE_33 39.4021 35.3119 40.0869 33.8664 37.1668
ATGE_39 37.1871 31.7702 24.8688 11.2871 26.2783
ATGE_41 2.6945 2.0882 3.1051 3.1051 2.7482
ATGE_42 16.7149 22.4798 25.2018 8.2238 18.155
ATGE_45 14.3797 10.5156 22.1062 8.4345 13.859
ATGE_76 4.0095 0.3034 5.5571 2.5033 3.0933
ATGE_77 2.3985 2.6601 2.2428 1.6405 2.2355
ATGE_78 3.5186 0.351 0.1351 0.1722 1.0442
ATGE_84 19.3026 7.4412 8.2976 10.9423 11.4959
ATGE_91 0.0452 0.1476 0.0471 0.0938 0.0834
ATGE_92 32.4452 19.8989 38.3113 4.5588 23.8036
ATGE_93 6.7356 4.36 5.5355 5.4696 5.5252
ATGE_95 6.0026 6.6811 5.2469 7.7283 6.4147
ATGE_96 0.4953 0.3805 0.2877 0.3957 0.3898
ATGE_97 0.995 0.9403 0.8453 0.8187 0.8998
ATGE_98 4.9257 6.0551 6.5773 5.3833 5.7354
ATGE_99 3.9373 6.024 2.5088 2.9567 3.8567
ATGE_101 0.1066 0.0231 0.0238 0.0316 0.0463
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch