AtMetExpress Development LC-MS

Perk Nr:adp006530.

Polarity:	[POSITIVE]
Retention time:	1.01
m/z:	277
Annotation:
Annotation level:	Unknown
compound:
MS2Ts	8 MS2Ts
KNApSAcK	C13H9O7(5):C13H8O6+O; C13H10O8-H2O; C6H14O10P1(5):2-Carboxyarabinitol 1-phosphate, 6-Phospho-D-gluco C6H15O8P2(4):C5H12O7P2+CH3O; C15H17O5(2):Vernolepin, Dihydromethysticin, Lactucin, Vernomen C12H21O5S1(2):C6H10S+C6H10O5; C7H18O3P1S3(2):C6H15O2PS3+CH3O; C10H17N2O7(1):C10H16N2O8-O; C4H6N2O2+C6H10O5; C14H17N2O4(1):C14H16N2O3+O; C14H18N2O5-H2O; C19H17O2(1):C19H16O3-O; C19H18O3-H2O; ,
in-house MS/MS	L-Glutamic acid_Ramp5-45 V(4) L-(+)-Lysine_Ramp5-45 V(4) L-saccharopine_Ramp5-45 V(3) L-Pyroglutamic acid_Ramp5-45 V(3) DL-Pipecolinic acid_Ramp5-45 V(3) L-Lysine monohydrochloride_Ramp5-45 V(3) DL-Pipecolinic acid_CE20(3) 1-Amino-1-cyclopentanecarboxylic acid_30V(3) L-lysine, HCl(3) L-Glutamine_Ramp5-45 V(3) L-saccharopine_CE30(3) gamma-Glu-Cys_Ramp5-45 V(2) L-(+)-Lysine_CE20(2) L-glutamic acid(2) L-Lysine monohydrochloride_CE20(2) L-Glutamine_CE20(2) N-Acetyl-DL-glutamic acid_Ramp5-45 V(2) L-saccharopine_CE40(1) L-Glutamic acid_CE30(1) (S)-(+)-2-(anilinomethyl)pyrrolidine_CE30(1) L-Glutamine_CE30(1) (S)-(+)-2-(anilinomethyl)pyrrolidine_30V(1) (S)-(+)-2-(anilinomethyl)pyrrolidine_CE40(1) L-saccharopine_CE50(1) L-beta-homolysine-2HCl_Ramp5-45 V(1) L-glutamine(1) DL-Pipecolinic acid_CE30(1) L-saccharopine(1) DL-Pipecolinic acid_30V(1) L-(+)-Lysine_CE40(1) (S)-(+)-2-(anilinomethyl)pyrrolidine_CE20(1) 1-Amino-1-cyclopentanecarboxylic acid_CE30(1) L-Glutamic acid_CE20(1) L-beta-homolysine-2HCl_CE30(1) L-beta-homolysine-2HCl_CE20(1) L-Lysine monohydrochloride_CE30(1) L-Glutamine_30V(1) L-(+)-Lysine_CE30(1) L-pipecolic acid(1) Ne-acetyl-L-lysine(1) pyro-glutamic acid(1) 1-Amino-1-cyclopentanecarboxylic acid_CE20(1) (S)-(+)-2-(anilinomethyl)pyrrolidine_Ramp5-45 V(1)
Represetative peak	This peak

eFP visualizaion

Raw chromatograms

MS2Ts

ATH06p04087

ATH08p03444

ATH14p03678

ATH56p04104

ATH57p03207

ATH57p04069

ATH59p03201

ATH64p04270

Peak intensity data

Sample	1	2	3	4	Average
ATGE_1	0.0026	0.019	0.0015	0.0588	0.0205
ATGE_7	0.0019	0.0714	0.0248	0.1396	0.0594
ATGE_9	0.0021	0.002	0.0357	0.002	0.0105
ATGE_10	0.0015	0.0015	0.0014	0.0014	0.0015
ATGE_12	0.0014	0.0401	0.002	0.0014	0.0112
ATGE_13	0.0015	0.0847	0.0022	0.1155	0.051
ATGE_14	0.002	0.0019	0.0015	0.0019	0.0018
ATGE_15	0.1202	0.0802	0.0678	0.0744	0.0856
ATGE_16	0.1482	0.0327	0.0292	0.1464	0.0891
ATGE_19	0.0802	0.0037	0.0019	0.0018	0.0219
ATGE_20	0.0019	0.1477	0.0017	0.1268	0.0695
ATGE_21	0.0019	0.0021	0.1164	0.0019	0.0306
ATGE_25	0.0014	0.0018	0.0013	0.0015	0.0015
ATGE_26	0.0516	0.0496	0.002	0.0016	0.0262
ATGE_27	0.022	0.0242	0.0015	0.002	0.0125
ATGE_28	0.002	0.0961	0.0801	0.0015	0.0449
ATGE_29	0.0016	0.0022	0.0017	0.0358	0.0103
ATGE_32	0.13	0.1552	0.1087	0.0485	0.1106
ATGE_33	0.05	0.0358	0.0371	0.0386	0.0404
ATGE_39	0.0016	0.002	0.002	0.0576	0.0158
ATGE_41	0.0016	0.0163	0.0012	0.0012	0.0051
ATGE_42	0.0018	0.0175	0.0265	0.0019	0.0119
ATGE_45	0.0562	0.0514	0.0557	0.0018	0.0413
ATGE_76	0.0022	0.0153	0.0016	0.002	0.0053
ATGE_77	0.037	0.0321	0.0213	0.0346	0.0312
ATGE_78	0.0307	0.0033	0.0208	0.0757	0.0326
ATGE_84	0.0172	0.0019	0.0016	0.0121	0.0082
ATGE_91	0.0469	0.002	0.0664	0.0973	0.0531
ATGE_92	0.0375	0.0447	0.049	0.0016	0.0332
ATGE_93	0.0266	0.0342	0.0243	0.0015	0.0216
ATGE_95	0.0262	0.0335	0.0018	0.0015	0.0157
ATGE_96	0.0014	0.0017	0.0017	0.0015	0.0016
ATGE_97	0.0016	0.047	0.002	0.0019	0.0131
ATGE_98	0.0227	0.0359	0.0188	0.0222	0.0249
ATGE_99	0.0514	0.0323	0.0019	0.0299	0.0289
ATGE_101	0.0409	0.0092	0.0021	0.0483	0.0251