AtMetExpress Development LC-MS

Perk Nr:adp021117. Procyanidin B2

Polarity: [POSITIVE]
Retention time: 3.69
m/z: 579
Annotation: Procyanidin B2
Annotation level: Identified
compound: Procyanidin B2
MS2Ts 35 MS2Ts
KNApSAcK C30H27O12(13):Epicatechin-(4beta->8)-ent-epicatechin, Procyanidi
C34H27O9(11):C34H26O8+O; C34H26O10-O;
C27H31O14(8):Chrysin 7-gentiobioside, 7,3',4'-Trihydroxyflavone
C26H27O15(8):C25H24O14+CH3O; C26H28O16-H2O;
C21H31N4O13S1(8):C15H20N4O8S+C6H10O5;
C33H23O10(5):C33H24O11-H2O;
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(9)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(9)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(9)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(9)
cyanidin 3-O-rhamnoside(9)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(9)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(9)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(9)
cyanidin-3-O-rhamnoside chloride_CE20(9)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(9)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(9)
Robinin_Ramp5-45 V(9)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(9)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(9)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(9)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(9)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(9)
kaempferol 3-O-a-rhamnopyranoside(9)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(9)
Poncirin_CE20(8)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(8)
delta-Tocotrienol_Ramp5-45 V(8)
Robinin_CE40(8)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(8)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(8)
kaempferol-3-O-rutinoside_Ramp5-45 V(7)
Kaempferol-3-Glucoside_CE20(7)
Ideain chloride_CE30(7)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(7)
cyanidin 3-diglucoside(7)
Kaempferol-3-Rhamnoside_Ramp5-45 V(7)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(7)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(7)
Luteolin_CE20(7)
Kaempferol-3-Glucuronide_CE30(7)
kaempferol-7-O-neohesperidoside_CE30(7)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(7)
luteolin-4'-O-glucoside_Ramp5-45 V(7)
cyanidin-3-glucoside chloride_Ramp5-45 V(7)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(7)
luteolin-4'-O-glucoside_CE40(7)
cyanidin 3-(6''-acetyl)galactoside(7)
cyanidin 3-sambubinoside(7)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(7)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(7)
Poncirin_CE30(7)
Isosakuranetin_CE10(7)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(7)
Datiscin_CE30(7)
Luteolin_CE10(7)
kaempferol-3-O-glucoside_Ramp5-45 V(7)
Luteolin_Ramp5-45 V(7)
Kaempferol-3-Glucoside_Ramp5-45 V(7)
Keracyanin Chloride_CE40(7)
Keracyanin Chloride_CE50(7)
kaempferol-7-O-neohesperidoside_CE40(7)
Maritimein_Ramp5-45 V(7)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(7)
kaempferol-3-O-glucoside_CE40(7)
Keracyanin Chloride_Ramp5-45 V(7)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(7)
cyanidin 3-(6''-maronoyl)-laminaribiose(7)
cyanidin 3-galactoside(7)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(7)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(7)
kaempferol-7-O-neohesperidoside_CE40(7)
Kaempferol-3-O-alpha-L-arabinoside_CE20(7)
Datiscin_CE20(7)
cyanidin 3-glucoside(7)
cyanidin 3-malonylglucoside(7)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(7)
luteolin-7-O-glucoside_CE30(7)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(7)
Sakuranetin_CE10(7)
Ideain chloride_Ramp5-45 V(7)
cyanidin 3-(6''-coumaroyl)glucoside(7)
Datiscin_Ramp5-45 V(7)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(7)
cyanidin 3-sophoroside(7)
luteolin-7-O-glucoside_Ramp5-45 V(7)
Kaempferol_CE10(7)
Kaempferol-3-Glucuronide_Ramp5-45 V(7)
cyanidin 3-laminaribiose(7)
cyanidin 3-arabinoside(7)
kaempferol-7-O-neohesperidoside_CE50(7)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(7)
kaempferol-3-O-glucoside_CE30(7)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(7)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(7)
kaempferol-3-O-glucoside_CE20(7)
cyanidin-3-glucoside chloride_CE40(7)
Sakuranetin_CE20(7)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(7)
cyanidin 3-dioxaloylglucoside(7)
cyanidin 7-arabinoside(7)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(7)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(7)
Maritimein_CE20(7)
cyanidin-3-O-rhamnoside chloride_CE30(7)
cyanidin 3-(glucosyl)rhamnoside(7)
Calciferol_Ramp5-45 V(7)
cyanidin 3-sophoroside(7)
cyanidin 3-xyloside(7)
luteolin-4'-O-glucoside_CE30(7)
cyanidin 3-(6''-acetoyl)glucoside(7)
Kaempferol_CE20(7)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(7)
Poncirin_CE40(6)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(6)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(6)
Robinin_CE60(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(6)
N1-Acetylspermine Trihydrochloride_CE30(6)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(6)
Cyanidin 3-(Glucosyl)Rhamnoside(6)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(6)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(6)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(6)
Robinin_CE50(6)
Kaempferol-3-Glucuronide_CE20(6)
Kaempferol-3-Glucoside_CE40(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(6)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(6)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(6)
kaempferol-3-O-rutinoside_CE50(6)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(6)
cyanidin-3,5-di-O-glucoside chloride_CE40(6)
Datiscin_CE60(6)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(6)
Datiscin_CE50(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(6)
Datiscin_CE40(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(6)
kaempferol-3-O-rutinoside_CE40(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(6)
cyanidin-3,5-di-O-glucoside chloride_CE60(5)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(5)
Keracyanin Chloride_CE60(5)
kaempferol-7-O-neohesperidoside_CE30(5)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(5)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(5)
Cyanidin-3-O-Glucoside(5)
alpha-Tocotrienol_Ramp5-45 V(5)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(5)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(5)
cyanidin-3-glucoside chloride_CE50(5)
cyanidin-3-O-rhamnoside chloride_CE60(5)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(5)
luteolin-3',7-di-O-glucoside _CE50(5)
Kaempferol-3,7-O-di-rhamnopyranoside_CE30(5)
4-Hydroxybenzoate_Ramp5-45 V(5)
kaempferol-3-O-rutinoside_CE30(5)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(5)
Luteolin_CE40(5)
cyanidin 3-glucoside(4)
cyanidin-3-O-rhamnoside chloride_CE40(4)
Cyanidin 3-Diglucoside(4)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(4)
Hinokitiol_Ramp5-45 V(4)
Cyanidin 3-(3''-Malonyl)Glucoside(4)
Solasodine_Ramp5-45 V(4)
cyanidin-3-O-rhamnoside chloride_CE50(4)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(4)
Cyanidin 3-Glucoside(4)
kaempferol-7-O-neohesperidoside_CE50(4)
Cyanidin 3-(6''-Malonyl Glucoside)(4)
kaempferol-3-O-rutinoside_CE20(4)
luteolin-7-O-glucoside_CE40(4)
Cyanidin 3-Laminaribioside(4)
Kaempferol 3-Glucoside(4)
Cyanidin 3-(3''-Malonyl)Glucoside(4)
Cyanidin 3-O-glucuronide(4)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(4)
cyanidin 3-rutinoside(4)
luteolin-4'-O-glucoside_CE50(4)
cyanidin-3,5-di-O-glucoside chloride_CE50(4)
Cyanidin 3-(6''-Acetyl) Glucoside(4)
Dehydroevodiamine(4)
Maritimein_CE40(4)
divaricataester C(4)
Cyanidin-3-O-Glucoside(4)
cyanidin 3-glucoside(4)
cyanidin-3-glucoside chloride_CE30(4)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(4)
kaempferol-7-O-neohesperidoside_CE60(4)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(4)
Cyanidin-3-O-Rutinoside(4)
Ideain chloride_CE50(4)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(4)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(4)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(4)
luteolin-3',7-di-O-glucoside _CE60(4)
cyanidin-3-sophoroside(4)
cyanidin-3-glucoside p-coumaric(4)
Isosakuranetin_CE20(4)
Cyanidin 3-Glucoside(4)
Cyanidin 3-Glucoside(4)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(4)
cyanidin-3-glucoside chloride_CE60(4)
Ideain chloride_CE60(4)
cyanidin-3-glucoside(4)
luteolin-7-O-glucoside_CE60(4)
Ideain chloride_CE40(4)
Cyanidin 3-Galactoside(4)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(4)
Cyanidin 3-(3''-Acetyl)Glucoside(4)
kaempferol-7-O-neohesperidoside_CE20(4)
luteolin-7-O-glucoside_CE20(4)
Cyanidin 3-Glucoside(4)
Kaempferol-3-Glucoside_CE30(4)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(4)
luteolin-7-O-glucoside_CE50(4)
cyanidin-3-xyloside-glucoside(4)
kaempferol-7-O-neohesperidoside_CE60(4)
cyanidin 3-sophoroside(4)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p08386

ATH06p08850

ATH07p07718

ATH07p08092

ATH08p08734

ATH08p08986

ATH08p09457

ATH08p09458

ATH10p07829

ATH11p08296

ATH11p08299

ATH11p08734

ATH11p08960

ATH12p08121

ATH13p10404

ATH14p09316

ATH14p09792

ATH56p08535

ATH56p09036

ATH56p09504

ATH57p07891

ATH58p10190

ATH58p11118

ATH59p08416

ATH59p09083

ATH61p10098

ATH61p10101

ATH61p10800

ATH61p10803

ATH62p08912

ATH63p09148

ATH63p11336

ATH63p11833

ATH64p10832

ATH64p11738

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0019 0.0013 0.0019 0.0014 0.0016
ATGE_9 0.0021 0.003 0.0184 0.002 0.0064
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0014 0.0014 0.002 0.0021 0.0017
ATGE_16 0.0018 0.0018 0.0041 0.0017 0.0024
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0115 0.0021 0.0017 0.0019 0.0043
ATGE_25 0.0022 0.0028 0.0146 0.0015 0.0053
ATGE_26 0.0019 0.0016 0.002 0.0016 0.0018
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0016 0.0022 0.0017 0.0016 0.0017
ATGE_32 0.0018 0.0017 0.0015 0.0016 0.0017
ATGE_33 0.0016 0.0018 0.002 0.0021 0.0019
ATGE_39 0.0016 0.002 0.002 0.0017 0.0018
ATGE_41 0.0032 0.0015 0.0012 0.0012 0.0018
ATGE_42 0.0018 0.0014 0.0551 0.0019 0.015
ATGE_45 0.0016 0.0015 0.0017 0.0018 0.0017
ATGE_76 0.8038 0.3079 1.3261 0.1788 0.6542
ATGE_77 2.484 0.7658 0.6844 1.2278 1.2905
ATGE_78 0.1466 0.0033 0.0014 0.0028 0.0385
ATGE_84 0.0464 0.0019 0.0419 0.0273 0.0294
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0017 0.0017 0.0017 0.0016 0.0017
ATGE_93 0.0194 0.0228 0.0021 0.0015 0.0114
ATGE_95 0.0021 0.0019 0.0018 0.0078 0.0034
ATGE_96 0.0014 0.0017 0.0017 0.0015 0.0016
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0313 0.0376 0.0212 0.0207 0.0277
ATGE_99 0.0361 0.0384 0.0329 0.0331 0.0351
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch