AtMetExpress Development LC-MS

Perk Nr:adp021123. "Kaempferol 3,7-O-dirhamnopyranoside_1"

Polarity: [POSITIVE]
Retention time: 4.61
m/z: 579
Annotation: "Kaempferol 3,7-O-dirhamnopyranoside_1"
Annotation level: Identified
compound: "Kaempferol-3,7-O-di-rhamnopyranoside: Kaempferol-3,7-O-bis-alpha-L-rhamnoside: Kaempferol-3-Rhamnoside-7-Rhamnoside"
MS2Ts 61 MS2Ts
KNApSAcK C27H31O14(39):Chrysin 7-gentiobioside, 7,3',4'-Trihydroxyflavone
C34H27O9(36):C34H26O8+O; C34H26O10-O;
C21H31N4O13S1(29):C15H20N4O8S+C6H10O5;
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(54)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(54)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(54)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(54)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(54)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(54)
cyanidin-3-O-rhamnoside chloride_CE20(54)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(54)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(54)
kaempferol 3-O-a-rhamnopyranoside(54)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(54)
kaempferol-3-O-rutinoside_Ramp5-45 V(53)
Kaempferol-3-Glucoside_CE20(53)
Ideain chloride_CE30(53)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(53)
cyanidin 3-diglucoside(53)
Kaempferol-3-Rhamnoside_Ramp5-45 V(53)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(53)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(53)
Luteolin_CE20(53)
Kaempferol-3-Glucuronide_CE30(53)
kaempferol-7-O-neohesperidoside_CE30(53)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(53)
luteolin-4'-O-glucoside_Ramp5-45 V(53)
cyanidin-3-glucoside chloride_Ramp5-45 V(53)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(53)
luteolin-4'-O-glucoside_CE40(53)
cyanidin 3-(6''-acetyl)galactoside(53)
cyanidin 3-sambubinoside(53)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(53)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(53)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(53)
Poncirin_CE30(53)
Isosakuranetin_CE10(53)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(53)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(53)
Datiscin_CE30(53)
Luteolin_CE10(53)
kaempferol-3-O-glucoside_Ramp5-45 V(53)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(53)
Poncirin_CE20(53)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(53)
Luteolin_Ramp5-45 V(53)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(53)
Kaempferol-3-Glucoside_Ramp5-45 V(53)
Robinin_CE50(53)
Keracyanin Chloride_CE40(53)
cyanidin 3-O-rhamnoside(53)
kaempferol-7-O-neohesperidoside_CE40(53)
Maritimein_Ramp5-45 V(53)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(53)
kaempferol-3-O-glucoside_CE40(53)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(53)
cyanidin 3-(6''-maronoyl)-laminaribiose(53)
cyanidin 3-galactoside(53)
Robinin_CE40(53)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(53)
kaempferol-7-O-neohesperidoside_CE40(53)
Kaempferol-3-O-alpha-L-arabinoside_CE20(53)
Datiscin_CE20(53)
cyanidin 3-glucoside(53)
cyanidin 3-malonylglucoside(53)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(53)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(53)
luteolin-7-O-glucoside_CE30(53)
Sakuranetin_CE10(53)
Ideain chloride_Ramp5-45 V(53)
cyanidin 3-(6''-coumaroyl)glucoside(53)
Datiscin_Ramp5-45 V(53)
cyanidin 3-sophoroside(53)
luteolin-7-O-glucoside_Ramp5-45 V(53)
Kaempferol_CE10(53)
Kaempferol-3-Glucuronide_Ramp5-45 V(53)
cyanidin 3-laminaribiose(53)
cyanidin 3-arabinoside(53)
kaempferol-7-O-neohesperidoside_CE50(53)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(53)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(53)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(53)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(53)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(53)
Sakuranetin_CE20(53)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(53)
cyanidin 3-dioxaloylglucoside(53)
Robinin_Ramp5-45 V(53)
cyanidin 7-arabinoside(53)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(53)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(53)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(53)
Maritimein_CE20(53)
cyanidin-3-O-rhamnoside chloride_CE30(53)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(53)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(53)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(53)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(53)
cyanidin 3-sophoroside(53)
cyanidin 3-xyloside(53)
cyanidin 3-(6''-acetoyl)glucoside(53)
Kaempferol_CE20(53)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(53)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(52)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(52)
Keracyanin Chloride_CE50(52)
Keracyanin Chloride_Ramp5-45 V(52)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(52)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(52)
kaempferol-3-O-glucoside_CE30(52)
kaempferol-3-O-glucoside_CE20(52)
cyanidin-3-glucoside chloride_CE40(52)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(52)
Datiscin_CE40(52)
luteolin-4'-O-glucoside_CE30(52)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(51)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(51)
Kaempferol-3-Glucoside_CE40(51)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(51)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(51)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(51)
Datiscin_CE50(51)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(51)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(51)
kaempferol-3-O-rutinoside_CE40(51)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(49)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(49)
Kaempferol-3-Glucuronide_CE20(49)
cyanidin-3,5-di-O-glucoside chloride_CE40(49)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(49)
cyanidin-3,5-di-O-glucoside chloride_CE60(48)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(48)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(48)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(47)
Keracyanin Chloride_CE60(47)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(47)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(46)
luteolin-3',7-di-O-glucoside _CE50(46)
Datiscin_CE60(46)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(45)
cyanidin-3-glucoside chloride_CE50(45)
cyanidin-3,5-di-O-glucoside chloride_CE50(44)
Ideain chloride_CE60(44)
kaempferol-3-O-rutinoside_CE30(44)
Luteolin_CE40(44)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(43)
cyanidin-3-glucoside chloride_CE30(42)
Isosakuranetin_CE20(42)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(42)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(42)
kaempferol-3-O-rutinoside_CE50(42)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(41)
kaempferol-7-O-neohesperidoside_CE30(41)
Cyanidin 3-(Glucosyl)Rhamnoside(41)
cyanidin-3-glucoside chloride_CE60(41)
cyanidin-3-O-rhamnoside chloride_CE60(39)
luteolin-7-O-glucoside_CE20(38)
Cyanidin-3-O-Glucoside(36)
Robinin_CE60(34)
Ideain chloride_CE40(32)
Kaempferol-3,7-O-di-rhamnopyranoside_CE30(32)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(31)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(29)
Maritimein_CE40(29)
luteolin-7-O-glucoside_CE60(29)
kaempferol-7-O-neohesperidoside_CE60(29)
cyanidin-3-O-rhamnoside chloride_CE40(28)
kaempferol-7-O-neohesperidoside_CE50(27)
luteolin-3',7-di-O-glucoside _CE60(27)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(26)
Kaempferol-3-Glucoside_CE30(26)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(26)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(26)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(24)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(24)
kaempferol-7-O-neohesperidoside_CE20(23)
Ideain chloride_CE50(22)
cyanidin 3-glucoside(21)
Cyanidin 3-Diglucoside(21)
Cyanidin 3-(3''-Malonyl)Glucoside(21)
cyanidin-3-O-rhamnoside chloride_CE50(21)
Cyanidin 3-Glucoside(21)
Cyanidin 3-(6''-Malonyl Glucoside)(21)
luteolin-7-O-glucoside_CE40(21)
Cyanidin 3-Laminaribioside(21)
Kaempferol 3-Glucoside(21)
Cyanidin 3-(3''-Malonyl)Glucoside(21)
Cyanidin 3-O-glucuronide(21)
cyanidin 3-rutinoside(21)
Cyanidin 3-(6''-Acetyl) Glucoside(21)
Dehydroevodiamine(21)
divaricataester C(21)
Cyanidin-3-O-Glucoside(21)
cyanidin 3-glucoside(21)
Cyanidin-3-O-Rutinoside(21)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(21)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(21)
cyanidin-3-sophoroside(21)
cyanidin-3-glucoside p-coumaric(21)
Cyanidin 3-Glucoside(21)
Cyanidin 3-Glucoside(21)
cyanidin-3-glucoside(21)
Cyanidin 3-Galactoside(21)
Cyanidin 3-(3''-Acetyl)Glucoside(21)
Cyanidin 3-Glucoside(21)
cyanidin-3-xyloside-glucoside(21)
cyanidin 3-sophoroside(21)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(19)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(19)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(19)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(17)
kaempferol-3-O-rutinoside_CE20(17)
kaempferol-7-O-neohesperidoside_CE60(17)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(17)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(16)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(15)
kaempferol-7-O-neohesperidoside(14)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(14)
cyanidin 3-O-galactosyl-rhamnoside(14)
cyanidin 3-rutinoside(14)
Kaempferol_CE30(13)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE50(13)
Poncirin_Ramp5-45 V(11)
Maritimein_CE30(11)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE50(7)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE60(7)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p08402

ATH06p08757

ATH06p08866

ATH06p08869

ATH07p07734

ATH07p07737

ATH07p08111

ATH07p08114

ATH07p08390

ATH08p08753

ATH08p09005

ATH08p09230

ATH08p09600

ATH09p08167

ATH09p08624

ATH10p07513

ATH10p07847

ATH11p08314

ATH11p08317

ATH11p08751

ATH11p08754

ATH12p07856

ATH12p07859

ATH12p08240

ATH12p08243

ATH13p09816

ATH13p10422

ATH14p09136

ATH14p09610

ATH56p08551

ATH56p08843

ATH56p09252

ATH56p09788

ATH57p07913

ATH57p07916

ATH57p08570

ATH57p08573

ATH58p10206

ATH58p10209

ATH58p10867

ATH58p10870

ATH59p08184

ATH59p08187

ATH59p08837

ATH59p08840

ATH61p10117

ATH61p10624

ATH61p10817

ATH61p11089

ATH62p07740

ATH62p07743

ATH62p08394

ATH62p08397

ATH63p08959

ATH63p08961

ATH63p09372

ATH63p09643

ATH63p11101

ATH63p11850

ATH64p11092

ATH64p11509

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.5612 1.1646 2.194 1.7453 1.4163
ATGE_7 6.0889 3.1285 6.4666 7.1939 5.7195
ATGE_9 0.0845 0.1346 0.046 0.0377 0.0757
ATGE_10 5.2529 4.0621 4.3217 4.5689 4.5514
ATGE_12 2.1669 1.7471 1.9598 1.5897 1.8659
ATGE_13 3.5867 3.0483 2.2784 12.4755 5.3472
ATGE_14 4.4994 4.1936 4.052 3.7895 4.1336
ATGE_15 13.1838 9.0634 6.9126 8.7276 9.4719
ATGE_16 15.4343 11.9158 11.2531 15.2385 13.4604
ATGE_19 1.4904 0.4715 2.1713 1.5234 1.4142
ATGE_20 7.5947 8.7261 7.4795 9.7672 8.3919
ATGE_21 8.1551 10.9771 10.844 10.5273 10.1259
ATGE_25 2.4514 3.1541 3.2614 2.4035 2.8176
ATGE_26 8.99 13.4489 8.9724 8.708 10.0298
ATGE_27 3.2184 2.9821 5.3702 8.6382 5.0522
ATGE_28 2.4322 2.1478 1.2752 5.4154 2.8177
ATGE_29 26.2173 30.6315 28.7866 26.6927 28.082
ATGE_32 18.4654 20.0754 16.9413 18.3355 18.4544
ATGE_33 19.2767 18.5278 19.4912 17.6229 18.7296
ATGE_39 17.9767 19.1539 17.7085 15.3179 17.5392
ATGE_41 4.9796 4.7529 5.3165 5.3165 5.0913
ATGE_42 19.2476 16.2138 16.0802 16.5767 17.0296
ATGE_45 14.526 13.47 10.3168 11.3218 12.4086
ATGE_76 5.5622 3.1787 7.9134 8.1736 6.207
ATGE_77 9.1877 5.1132 3.9527 6.2788 6.1331
ATGE_78 7.3353 2.9208 1.8479 1.9314 3.5089
ATGE_84 0.7716 0.6891 0.8353 0.9021 0.7995
ATGE_91 1.1591 1.9088 1.1806 1.6124 1.4652
ATGE_92 16.8353 13.5676 19.9143 8.7172 14.7586
ATGE_93 0.4595 0.4657 0.474 0.3833 0.4456
ATGE_95 0.3277 0.279 0.304 0.1965 0.2768
ATGE_96 0.3407 0.1962 0.2553 0.5437 0.334
ATGE_97 2.4719 3.672 3.8225 3.9561 3.4806
ATGE_98 0.3557 0.6267 0.3289 0.3657 0.4193
ATGE_99 0.438 0.565 0.4271 0.3739 0.451
ATGE_101 1.6038 0.9419 1.1944 1.5136 1.3134
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch