AtMetExpress Development LC-MS

Perk Nr:adp021948. Kaempferol-3-Rha-7-Glu

Polarity: [POSITIVE]
Retention time: 3.88
m/z: 595
Annotation: Kaempferol-3-Rha-7-Glu
Annotation level: Characterized
compound:
MS2Ts 36 MS2Ts
KNApSAcK C34H27O10(15):Agathisflavone tetramethyl ether, Cupressuflavone
C31H31O12(9):C31H30O13-O; C25H20O7+C6H10O5;
C24H35O17(8):C18H24O12+C6H10O5;
in-house MS/MS kaempferol-3-O-rutinoside_Ramp5-45 V(28)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(28)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(28)
luteolin-4'-O-glucoside_Ramp5-45 V(28)
cyanidin-3-glucoside chloride_Ramp5-45 V(28)
Datiscin_CE20(28)
Ideain chloride_Ramp5-45 V(28)
luteolin-7-O-glucoside_Ramp5-45 V(28)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(28)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(28)
Kaempferol-3-Glucoside_CE20(27)
Ideain chloride_CE30(27)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(27)
cyanidin 3-diglucoside(27)
Kaempferol-3-Rhamnoside_Ramp5-45 V(27)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(27)
Luteolin_CE20(27)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(27)
luteolin-4'-O-glucoside_CE40(27)
cyanidin 3-(6''-acetyl)galactoside(27)
cyanidin 3-sambubinoside(27)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(27)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(27)
Poncirin_CE30(27)
Isosakuranetin_CE10(27)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(27)
Luteolin_CE10(27)
kaempferol-3-O-glucoside_Ramp5-45 V(27)
Poncirin_CE20(27)
Luteolin_Ramp5-45 V(27)
Kaempferol-3-Glucoside_Ramp5-45 V(27)
Keracyanin Chloride_CE40(27)
Maritimein_Ramp5-45 V(27)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(27)
cyanidin 3-(6''-maronoyl)-laminaribiose(27)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(27)
cyanidin 3-galactoside(27)
Kaempferol-3-O-alpha-L-arabinoside_CE20(27)
cyanidin 3-glucoside(27)
cyanidin 3-malonylglucoside(27)
luteolin-7-O-glucoside_CE30(27)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(27)
Sakuranetin_CE10(27)
cyanidin 3-(6''-coumaroyl)glucoside(27)
Datiscin_Ramp5-45 V(27)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(27)
cyanidin 3-sophoroside(27)
Kaempferol_CE10(27)
cyanidin 3-laminaribiose(27)
Kaempferol-3-Glucuronide_Ramp5-45 V(27)
cyanidin 3-arabinoside(27)
luteolin-3',7-di-O-glucoside _CE50(27)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(27)
Sakuranetin_CE20(27)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(27)
cyanidin 3-dioxaloylglucoside(27)
cyanidin 7-arabinoside(27)
Maritimein_CE20(27)
luteolin-7-O-glucoside_CE20(27)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(27)
cyanidin 3-sophoroside(27)
kaempferol 3-O-a-rhamnopyranoside(27)
cyanidin 3-xyloside(27)
cyanidin 3-(6''-acetoyl)glucoside(27)
Kaempferol_CE20(27)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(27)
cyanidin 3-glucoside(26)
cyanidin-3,5-di-O-glucoside chloride_CE60(26)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(26)
Cyanidin 3-Glucoside(26)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(26)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(26)
Kaempferol-3-Glucuronide_CE30(26)
kaempferol-7-O-neohesperidoside_CE30(26)
Kaempferol 3-Glucoside(26)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(26)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(26)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(26)
Cyanidin-3-O-Glucoside(26)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(26)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(26)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(26)
Datiscin_CE30(26)
divaricataester C(26)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(26)
Cyanidin-3-O-Glucoside(26)
cyanidin 3-glucoside(26)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(26)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(26)
Keracyanin Chloride_CE50(26)
kaempferol-7-O-neohesperidoside_CE40(26)
Kaempferol-3-Glucoside_CE40(26)
kaempferol-3-O-glucoside_CE40(26)
Keracyanin Chloride_Ramp5-45 V(26)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(26)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(26)
kaempferol-7-O-neohesperidoside_CE40(26)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(26)
Cyanidin 3-Glucoside(26)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(26)
Cyanidin 3-Glucoside(26)
cyanidin-3-O-rhamnoside chloride_CE60(26)
cyanidin-3-O-rhamnoside chloride_CE20(26)
cyanidin-3-glucoside(26)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(26)
kaempferol-7-O-neohesperidoside_CE50(26)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(26)
cyanidin-3,5-di-O-glucoside chloride_CE40(26)
Cyanidin 3-Galactoside(26)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(26)
Robinin_Ramp5-45 V(26)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(26)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(26)
cyanidin-3-O-rhamnoside chloride_CE30(26)
Cyanidin 3-Glucoside(26)
Datiscin_CE50(26)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(26)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(26)
Datiscin_CE40(26)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(26)
luteolin-4'-O-glucoside_CE30(26)
kaempferol-3-O-rutinoside_CE40(26)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(26)
Poncirin_CE40(25)
Keracyanin Chloride_CE60(25)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(25)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(25)
Robinin_CE50(25)
Kaempferol-3-Glucuronide_CE20(25)
cyanidin 3-O-rhamnoside(25)
luteolin-3',7-di-O-glucoside _CE60(25)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(25)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(25)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(25)
kaempferol-3-O-glucoside_CE30(25)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(25)
kaempferol-3-O-glucoside_CE20(25)
cyanidin-3-glucoside chloride_CE40(25)
kaempferol-7-O-neohesperidoside_CE20(25)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(25)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(25)
kaempferol-3-O-rutinoside_CE30(25)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(25)
cyanidin-3-glucoside chloride_CE20(24)
kaempferol-7-O-neohesperidoside(24)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(24)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(24)
kaempferol-3-O-rutinoside_CE20(24)
kaempferol-7-O-neohesperidoside_CE30(24)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(24)
luteolin-4'-O-glucoside_CE50(24)
cyanidin-3,5-di-O-glucoside chloride_CE50(24)
cyanidin-3-glucoside chloride_CE30(24)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(24)
cyanidin-3-glucoside chloride_CE50(24)
Isosakuranetin_CE20(24)
cyanidin-3-glucoside chloride_CE60(24)
Ideain chloride_CE60(24)
Datiscin_CE60(24)
Ideain chloride_CE40(24)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(24)
Luteolin_CE40(24)
cyanidin-3-O-rhamnoside chloride_CE40(23)
Maritimein_CE40(23)
cyanidin 3-O-galactosyl-rhamnoside(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(23)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(23)
luteolin-7-O-glucoside_CE60(23)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(23)
cyanidin 3-rutinoside(23)
Cyanidin 3-Diglucoside(22)
Cyanidin 3-(3''-Malonyl)Glucoside(22)
kaempferol-7-O-neohesperidoside_CE50(22)
Cyanidin 3-(6''-Malonyl Glucoside)(22)
Cyanidin 3-Laminaribioside(22)
Cyanidin 3-(3''-Malonyl)Glucoside(22)
Cyanidin 3-O-glucuronide(22)
cyanidin 3-rutinoside(22)
Cyanidin 3-(6''-Acetyl) Glucoside(22)
Dehydroevodiamine(22)
Cyanidin-3-O-Rutinoside(22)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(22)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(22)
cyanidin-3-sophoroside(22)
cyanidin-3-glucoside p-coumaric(22)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(22)
kaempferol-3-O-rutinoside_CE50(22)
Cyanidin 3-(3''-Acetyl)Glucoside(22)
cyanidin-3-xyloside-glucoside(22)
cyanidin 3-sophoroside(22)
cyanidin-3-O-rhamnoside chloride_CE50(21)
luteolin-7-O-glucoside_CE40(21)
Robinin_CE60(21)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(21)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(21)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(21)
Ideain chloride_CE50(21)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(21)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(21)
Kaempferol-3-Glucoside_CE30(21)
luteolin-7-O-glucoside_CE50(21)
kaempferol-7-O-neohesperidoside_CE60(21)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(21)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(21)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(19)
Robinin_CE40(19)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(19)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(18)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(18)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(18)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(17)
Kaempferol_CE30(17)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(17)
Poncirin_Ramp5-45 V(16)
Maritimein_CE30(16)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(14)
luteolin-4'-O-glucoside_CE60(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE40(12)
Kaempferol 3-O-rutinoside(12)
luteolin-4'-O-glucoside_CE20(12)
cyanidin 3-(glucosyl)rhamnoside(12)
cyanidin 3-glucoside(11)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(11)
Probable kaempferol triglycosidese of m/z 741 or757(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-(3''-malonyl)glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-rutinoside(11)
cyanidin 3-galactoside(11)
cyanidin 3,5-diglucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
Probable kaempferol triglycosidese of m/z 741 or757(11)
cyanidin 3-glucoside(11)
cyanidin 3-glucoside(11)
cyanidin-3,5-di-O-glucoside chloride_CE30(11)
cyanidin 3-glucoside(11)
cyanidin 3-(caffeoyl)diglucoside-5-glucoside(11)
cyanidin 3-galactoside(11)
cyanidin 3-galactoside(11)
cyanidin 3,5-diglucoside(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(7)
Ideain chloride_CE20(6)
Kaempferol-3-Glucoside_CE10(6)
Luteolin_CE30(5)
Cyanidin 3-(Glucosyl)Rhamnoside(4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p08852

ATH06p08855

ATH06p09499

ATH06p09601

ATH07p08484

ATH08p09214

ATH08p09462

ATH08p09721

ATH09p09252

ATH12p08226

ATH12p08228

ATH12p08611

ATH14p09597

ATH14p09800

ATH14p10354

ATH56p09237

ATH56p09506

ATH56p09774

ATH56p10034

ATH57p09335

ATH57p09868

ATH58p10853

ATH58p10856

ATH58p11551

ATH58p12035

ATH59p09299

ATH61p12136

ATH62p08380

ATH62p08918

ATH62p09174

ATH62p09706

ATH63p09891

ATH63p10420

ATH64p11495

ATH64p11745

ATH64p12596

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0296 0.0562 0.0693 0.0725 0.0569
ATGE_7 0.1295 0.1231 0.1482 0.1629 0.1409
ATGE_9 0.0175 0.0637 0.0391 0.002 0.0306
ATGE_10 0.0574 0.0483 0.0578 0.0577 0.0553
ATGE_12 0.0156 0.0122 0.013 0.0103 0.0128
ATGE_13 0.0195 0.0127 0.0022 0.1342 0.0421
ATGE_14 0.0326 0.0327 0.0244 0.0256 0.0288
ATGE_15 0.2425 0.078 0.0431 0.0882 0.113
ATGE_16 0.2143 0.1412 0.1029 0.214 0.1681
ATGE_19 0.0109 0.0037 0.0193 0.0156 0.0124
ATGE_20 0.0693 0.1054 0.0943 0.1096 0.0946
ATGE_21 0.0539 0.0946 0.0779 0.0797 0.0765
ATGE_25 0.0022 0.0028 0.0013 0.0015 0.0019
ATGE_26 0.041 0.0885 0.0357 0.0376 0.0507
ATGE_27 0.0015 0.0186 0.0268 0.0328 0.0199
ATGE_28 0.002 0.0018 0.0018 0.033 0.0096
ATGE_29 0.3502 0.3795 0.3208 0.3365 0.3468
ATGE_32 0.289 0.2962 0.2646 0.21 0.265
ATGE_33 0.3073 0.3327 0.3281 0.2878 0.314
ATGE_39 0.4144 0.4464 0.4274 0.2925 0.3952
ATGE_41 0.0326 0.0225 0.0224 0.0224 0.025
ATGE_42 0.2597 0.1591 0.1482 0.1515 0.1796
ATGE_45 0.5662 0.4946 0.3646 0.3054 0.4327
ATGE_76 0.6375 0.2147 0.6963 0.6182 0.5417
ATGE_77 0.8303 0.5704 0.4298 0.5471 0.5944
ATGE_78 0.6 0.0774 0.0245 0.0742 0.194
ATGE_84 0.0018 0.0019 0.0016 0.0015 0.0017
ATGE_91 0.0577 0.0541 0.0274 0.0376 0.0442
ATGE_92 0.3063 0.3626 0.3291 0.4337 0.3579
ATGE_93 0.653 0.612 0.5417 0.4409 0.5619
ATGE_95 0.3214 0.2665 0.2877 0.1581 0.2584
ATGE_96 0.0265 0.015 0.0197 0.0246 0.0215
ATGE_97 0.0713 0.1079 0.1186 0.1106 0.1021
ATGE_98 0.2014 0.7568 0.2291 0.2292 0.3541
ATGE_99 0.4352 0.4848 0.3932 0.3739 0.4218
ATGE_101 0.0218 0.0015 0.0149 0.0228 0.0152
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch