AtMetExpress Development LC-MS

Perk Nr:adp021951.

Polarity: [POSITIVE]
Retention time: 4.14
m/z: 595
Annotation:
Annotation level: Unknown
compound: Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside
MS2Ts 61 MS2Ts
KNApSAcK C27H31O15(39):Paniculatin, Apigenin 7-allosyl-(1->2)-glucoside,
C31H31O12(13):C31H30O13-O; C25H20O7+C6H10O5;
C30H27O13(9):Apigenin 7-(6''-E-Caffeoylglucoside);7-[[6-O-[3-(3
C24H35O17(7):C18H24O12+C6H10O5;
in-house MS/MS Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(48)
Cyanidin-3-O-Glucoside(46)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(44)
luteolin-4'-O-glucoside_Ramp5-45 V(44)
cyanidin-3-glucoside chloride_Ramp5-45 V(44)
Datiscin_CE20(44)
Ideain chloride_Ramp5-45 V(44)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(44)
Robinin_Ramp5-45 V(44)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(43)
cyanidin 3-O-rhamnoside(43)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(43)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(43)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(43)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(43)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(43)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(43)
luteolin-7-O-glucoside_CE20(43)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(43)
kaempferol 3-O-a-rhamnopyranoside(43)
cyanidin 3-glucoside(42)
kaempferol-3-O-rutinoside_Ramp5-45 V(42)
Kaempferol-3-Glucoside_CE20(42)
Ideain chloride_CE30(42)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(42)
cyanidin 3-diglucoside(42)
Kaempferol-3-Rhamnoside_Ramp5-45 V(42)
Cyanidin 3-Glucoside(42)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(42)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(42)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(42)
Luteolin_CE20(42)
Kaempferol-3-Glucuronide_CE30(42)
kaempferol-7-O-neohesperidoside_CE30(42)
Kaempferol 3-Glucoside(42)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(42)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(42)
luteolin-4'-O-glucoside_CE40(42)
cyanidin 3-(6''-acetyl)galactoside(42)
cyanidin 3-sambubinoside(42)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(42)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(42)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(42)
Poncirin_CE30(42)
Isosakuranetin_CE10(42)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(42)
Datiscin_CE30(42)
Luteolin_CE10(42)
kaempferol-3-O-glucoside_Ramp5-45 V(42)
divaricataester C(42)
Poncirin_CE20(42)
Cyanidin-3-O-Glucoside(42)
cyanidin 3-glucoside(42)
Luteolin_Ramp5-45 V(42)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(42)
Kaempferol-3-Glucoside_Ramp5-45 V(42)
Robinin_CE50(42)
Keracyanin Chloride_CE40(42)
kaempferol-7-O-neohesperidoside_CE40(42)
Maritimein_Ramp5-45 V(42)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(42)
kaempferol-3-O-glucoside_CE40(42)
Keracyanin Chloride_Ramp5-45 V(42)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(42)
cyanidin 3-(6''-maronoyl)-laminaribiose(42)
cyanidin 3-galactoside(42)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(42)
kaempferol-7-O-neohesperidoside_CE40(42)
Kaempferol-3-O-alpha-L-arabinoside_CE20(42)
cyanidin 3-glucoside(42)
cyanidin 3-malonylglucoside(42)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(42)
Cyanidin 3-Glucoside(42)
luteolin-7-O-glucoside_CE30(42)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(42)
Cyanidin 3-Glucoside(42)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(42)
Sakuranetin_CE10(42)
cyanidin-3-O-rhamnoside chloride_CE20(42)
cyanidin-3-glucoside(42)
cyanidin 3-(6''-coumaroyl)glucoside(42)
Datiscin_Ramp5-45 V(42)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(42)
cyanidin 3-sophoroside(42)
luteolin-7-O-glucoside_Ramp5-45 V(42)
Kaempferol_CE10(42)
cyanidin 3-laminaribiose(42)
Kaempferol-3-Glucuronide_Ramp5-45 V(42)
cyanidin 3-arabinoside(42)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(42)
kaempferol-7-O-neohesperidoside_CE50(42)
luteolin-3',7-di-O-glucoside _CE50(42)
kaempferol-3-O-glucoside_CE30(42)
cyanidin-3,5-di-O-glucoside chloride_CE40(42)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(42)
kaempferol-3-O-glucoside_CE20(42)
cyanidin-3-glucoside chloride_CE40(42)
Cyanidin 3-Galactoside(42)
Sakuranetin_CE20(42)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(42)
cyanidin 3-dioxaloylglucoside(42)
cyanidin 7-arabinoside(42)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(42)
Maritimein_CE20(42)
cyanidin-3-O-rhamnoside chloride_CE30(42)
Cyanidin 3-Glucoside(42)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(42)
cyanidin 3-sophoroside(42)
cyanidin 3-xyloside(42)
luteolin-4'-O-glucoside_CE30(42)
cyanidin 3-(6''-acetoyl)glucoside(42)
Kaempferol_CE20(42)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(42)
cyanidin-3,5-di-O-glucoside chloride_CE60(41)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(41)
Keracyanin Chloride_CE60(41)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(41)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(41)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(41)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(41)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(41)
cyanidin-3,5-di-O-glucoside chloride_CE50(41)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(41)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(41)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(41)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(41)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(41)
Keracyanin Chloride_CE50(41)
Kaempferol-3-Glucuronide_CE20(41)
Kaempferol-3-Glucoside_CE40(41)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(41)
cyanidin-3-glucoside chloride_CE50(41)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(41)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(41)
cyanidin-3-O-rhamnoside chloride_CE60(41)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(41)
Ideain chloride_CE60(41)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(41)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(41)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(41)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(41)
Datiscin_CE50(41)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(41)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(41)
Datiscin_CE40(41)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(41)
kaempferol-3-O-rutinoside_CE40(41)
Luteolin_CE40(41)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(41)
Poncirin_CE40(39)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(39)
kaempferol-7-O-neohesperidoside_CE30(39)
luteolin-4'-O-glucoside_CE50(39)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(39)
cyanidin-3-glucoside chloride_CE30(39)
Isosakuranetin_CE20(39)
cyanidin-3-glucoside chloride_CE60(39)
cyanidin-3-O-rhamnoside chloride_CE40(38)
kaempferol-7-O-neohesperidoside_CE50(38)
Maritimein_CE40(38)
Robinin_CE40(38)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(38)
luteolin-7-O-glucoside_CE60(38)
kaempferol-3-O-rutinoside_CE50(38)
Datiscin_CE60(38)
kaempferol-7-O-neohesperidoside_CE60(38)
kaempferol-3-O-rutinoside_CE20(37)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(37)
Ideain chloride_CE40(37)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(37)
kaempferol-7-O-neohesperidoside_CE20(37)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(36)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(36)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(36)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(36)
Cyanidin 3-Diglucoside(35)
Cyanidin 3-(3''-Malonyl)Glucoside(35)
cyanidin-3-O-rhamnoside chloride_CE50(35)
Cyanidin 3-(6''-Malonyl Glucoside)(35)
luteolin-7-O-glucoside_CE40(35)
Cyanidin 3-Laminaribioside(35)
Cyanidin 3-(3''-Malonyl)Glucoside(35)
Cyanidin 3-O-glucuronide(35)
cyanidin 3-rutinoside(35)
Cyanidin 3-(6''-Acetyl) Glucoside(35)
Dehydroevodiamine(35)
Cyanidin-3-O-Rutinoside(35)
Ideain chloride_CE50(35)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(35)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(35)
cyanidin-3-sophoroside(35)
cyanidin-3-glucoside p-coumaric(35)
Cyanidin 3-(3''-Acetyl)Glucoside(35)
Kaempferol-3-Glucoside_CE30(35)
luteolin-7-O-glucoside_CE50(35)
cyanidin-3-xyloside-glucoside(35)
cyanidin 3-sophoroside(35)
Robinin_CE60(34)
cyanidin 3-O-galactosyl-rhamnoside(34)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(34)
cyanidin 3-rutinoside(34)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(32)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(32)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(31)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(31)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(31)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(29)
Maritimein_CE30(29)
Kaempferol_CE30(29)
cyanidin 3-(glucosyl)rhamnoside(29)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(26)
luteolin-4'-O-glucoside_CE60(25)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(25)
Poncirin_Ramp5-45 V(24)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(16)
Cyanidin 3-(Glucosyl)Rhamnoside(13)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(12)
Luteolin_CE30(12)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(9)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(8)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(7)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p08858

ATH06p08861

ATH06p09272

ATH06p09508

ATH07p08103

ATH07p08491

ATH07p08703

ATH08p09220

ATH08p09223

ATH08p09729

ATH08p09960

ATH09p08617

ATH09p09036

ATH09p09252

ATH10p07840

ATH10p08154

ATH11p08747

ATH11p09022

ATH11p09345

ATH11p09432

ATH12p08231

ATH12p08234

ATH12p08617

ATH12p08895

ATH13p10415

ATH13p10819

ATH13p11013

ATH14p09603

ATH14p09800

ATH14p10062

ATH14p10242

ATH56p09244

ATH56p09774

ATH56p10043

ATH56p10309

ATH57p08563

ATH57p09344

ATH57p09871

ATH58p10859

ATH58p10862

ATH58p11557

ATH59p08832

ATH59p09981

ATH61p10810

ATH61p10813

ATH61p11079

ATH61p11608

ATH61p12136

ATH62p08387

ATH62p08918

ATH62p09180

ATH62p09452

ATH63p09365

ATH63p10156

ATH63p11844

ATH63p12333

ATH63p12588

ATH64p11748

ATH64p11962

ATH64p12162

ATH64p12165

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.002 0.0019
ATGE_7 0.0019 0.0013 0.0149 0.0162 0.0086
ATGE_9 0.0021 0.003 0.0023 0.002 0.0024
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0391 0.0111
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0558 0.0014 0.002 0.0106 0.0175
ATGE_16 0.0339 0.0364 0.0027 0.0026 0.0189
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0268 0.0081
ATGE_25 0.0022 0.0028 0.0013 0.0015 0.0019
ATGE_26 0.0019 0.0152 0.002 0.0016 0.0052
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0507 0.0954 0.0597 0.0513 0.0643
ATGE_32 0.0027 0.0565 0.027 0.0267 0.0282
ATGE_33 0.0314 0.0028 0.035 0.0429 0.028
ATGE_39 0.0024 0.0387 0.002 0.0017 0.0112
ATGE_41 0.0024 0.0015 0.0012 0.0012 0.0016
ATGE_42 0.0677 0.0294 0.0272 0.0381 0.0406
ATGE_45 0.0016 0.0015 0.0141 0.0018 0.0047
ATGE_76 0.0022 0.0017 0.0096 0.002 0.0039
ATGE_77 0.0025 0.0022 0.003 0.0028 0.0026
ATGE_78 0.0041 0.0067 0.0014 0.0028 0.0037
ATGE_84 0.0018 0.0019 0.0016 0.0015 0.0017
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0017 0.0206 0.0258 0.0421 0.0226
ATGE_93 0.002 0.0031 0.0031 0.0031 0.0028
ATGE_95 0.0189 0.0028 0.0018 0.018 0.0104
ATGE_96 0.0021 0.0017 0.0017 0.0015 0.0018
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0015 0.0068 0.0016 0.0023 0.003
ATGE_99 0.0038 0.0013 0.0019 0.0032 0.0025
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch