AtMetExpress Development LC-MS

Perk Nr:adp021958.

Polarity: [POSITIVE]
Retention time: 4.85
m/z: 595
Annotation:
Annotation level: Unknown
compound: kaempferol-3-O-rutinoside: Kaempferol-3-Glucoside-3''-Rhamnoside
MS2Ts 31 MS2Ts
KNApSAcK C27H31O15(12):Paniculatin, Apigenin 7-allosyl-(1->2)-glucoside,
C34H27O10(12):Agathisflavone tetramethyl ether, Cupressuflavone
C30H27O13(8):Apigenin 7-(6''-E-Caffeoylglucoside);7-[[6-O-[3-(3
C35H31O9(5):C34H28O8+CH3O;
C28H35O14(5):Poncirin;Isosakuranetin-7-O-beta-D-neohesperidosid
C31H31O12(4):C31H30O13-O; C25H20O7+C6H10O5;
C34H31N2O8(4):C34H30N2O9-O;
in-house MS/MS Cyanidin-3-O-Glucoside(24)
cyanidin 3-glucoside(23)
cyanidin-3,5-di-O-glucoside chloride_CE60(23)
cyanidin-3-glucoside chloride_CE20(23)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(23)
kaempferol-3-O-rutinoside_Ramp5-45 V(23)
Kaempferol-3-Glucoside_CE20(23)
Ideain chloride_CE30(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(23)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(23)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(23)
cyanidin 3-diglucoside(23)
Kaempferol-3-Rhamnoside_Ramp5-45 V(23)
Cyanidin 3-Glucoside(23)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(23)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(23)
kaempferol-3-O-rutinoside_CE20(23)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(23)
Luteolin_CE20(23)
Kaempferol-3-Glucuronide_CE30(23)
Keracyanin Chloride_CE60(23)
kaempferol-7-O-neohesperidoside_CE30(23)
Kaempferol 3-Glucoside(23)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(23)
luteolin-4'-O-glucoside_Ramp5-45 V(23)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(23)
cyanidin-3-glucoside chloride_Ramp5-45 V(23)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(23)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(23)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(23)
luteolin-4'-O-glucoside_CE40(23)
cyanidin 3-(6''-acetyl)galactoside(23)
cyanidin 3-sambubinoside(23)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(23)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(23)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(23)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(23)
cyanidin-3,5-di-O-glucoside chloride_CE50(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(23)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(23)
Poncirin_CE30(23)
Isosakuranetin_CE10(23)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(23)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(23)
Datiscin_CE30(23)
Luteolin_CE10(23)
kaempferol-3-O-glucoside_Ramp5-45 V(23)
divaricataester C(23)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(23)
Poncirin_CE20(23)
Cyanidin-3-O-Glucoside(23)
cyanidin 3-glucoside(23)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(23)
Luteolin_Ramp5-45 V(23)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(23)
Kaempferol-3-Glucoside_Ramp5-45 V(23)
Robinin_CE50(23)
Keracyanin Chloride_CE40(23)
Keracyanin Chloride_CE50(23)
Kaempferol-3-Glucuronide_CE20(23)
cyanidin 3-O-rhamnoside(23)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(23)
kaempferol-7-O-neohesperidoside_CE40(23)
Maritimein_Ramp5-45 V(23)
Kaempferol-3-Glucoside_CE40(23)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(23)
kaempferol-3-O-glucoside_CE40(23)
Keracyanin Chloride_Ramp5-45 V(23)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(23)
cyanidin 3-(6''-maronoyl)-laminaribiose(23)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(23)
cyanidin 3-galactoside(23)
luteolin-3',7-di-O-glucoside _CE60(23)
Robinin_CE40(23)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(23)
kaempferol-7-O-neohesperidoside_CE40(23)
Kaempferol-3-O-alpha-L-arabinoside_CE20(23)
Datiscin_CE20(23)
cyanidin-3-glucoside chloride_CE50(23)
cyanidin 3-glucoside(23)
cyanidin 3-malonylglucoside(23)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(23)
Cyanidin 3-Glucoside(23)
luteolin-7-O-glucoside_CE30(23)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(23)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(23)
Cyanidin 3-Glucoside(23)
cyanidin-3-O-rhamnoside chloride_CE60(23)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(23)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(23)
Sakuranetin_CE10(23)
Ideain chloride_Ramp5-45 V(23)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(23)
Ideain chloride_CE60(23)
cyanidin-3-O-rhamnoside chloride_CE20(23)
cyanidin-3-glucoside(23)
cyanidin 3-(6''-coumaroyl)glucoside(23)
Datiscin_Ramp5-45 V(23)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(23)
cyanidin 3-sophoroside(23)
luteolin-7-O-glucoside_Ramp5-45 V(23)
Kaempferol_CE10(23)
cyanidin 3-laminaribiose(23)
Kaempferol-3-Glucuronide_Ramp5-45 V(23)
cyanidin 3-arabinoside(23)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(23)
kaempferol-7-O-neohesperidoside_CE50(23)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(23)
luteolin-3',7-di-O-glucoside _CE50(23)
kaempferol-3-O-glucoside_CE30(23)
cyanidin-3,5-di-O-glucoside chloride_CE40(23)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(23)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(23)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(23)
kaempferol-3-O-glucoside_CE20(23)
cyanidin-3-glucoside chloride_CE40(23)
Cyanidin 3-Galactoside(23)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(23)
Sakuranetin_CE20(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(23)
cyanidin 3-dioxaloylglucoside(23)
Robinin_Ramp5-45 V(23)
cyanidin 7-arabinoside(23)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(23)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(23)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(23)
Maritimein_CE20(23)
cyanidin-3-O-rhamnoside chloride_CE30(23)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(23)
kaempferol-3-O-rutinoside_CE30(23)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(23)
luteolin-7-O-glucoside_CE20(23)
Cyanidin 3-Glucoside(23)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(23)
Datiscin_CE50(23)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(23)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(23)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(23)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(23)
Datiscin_CE40(23)
cyanidin 3-sophoroside(23)
kaempferol 3-O-a-rhamnopyranoside(23)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(23)
cyanidin 3-xyloside(23)
luteolin-4'-O-glucoside_CE30(23)
kaempferol-3-O-rutinoside_CE40(23)
cyanidin 3-(6''-acetoyl)glucoside(23)
Kaempferol_CE20(23)
Luteolin_CE40(23)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(23)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(23)
kaempferol-7-O-neohesperidoside(22)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(22)
kaempferol-7-O-neohesperidoside_CE30(22)
Maritimein_CE40(22)
cyanidin-3-glucoside chloride_CE30(22)
Isosakuranetin_CE20(22)
cyanidin-3-glucoside chloride_CE60(22)
Datiscin_CE60(22)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(22)
cyanidin-3-O-rhamnoside chloride_CE40(21)
Cyanidin 3-Diglucoside(21)
Cyanidin 3-(3''-Malonyl)Glucoside(21)
cyanidin-3-O-rhamnoside chloride_CE50(21)
Poncirin_CE40(21)
kaempferol-7-O-neohesperidoside_CE50(21)
Cyanidin 3-(6''-Malonyl Glucoside)(21)
luteolin-7-O-glucoside_CE40(21)
Cyanidin 3-Laminaribioside(21)
Cyanidin 3-(3''-Malonyl)Glucoside(21)
Cyanidin 3-O-glucuronide(21)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(21)
cyanidin 3-rutinoside(21)
luteolin-4'-O-glucoside_CE50(21)
Cyanidin 3-(6''-Acetyl) Glucoside(21)
Dehydroevodiamine(21)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(21)
Cyanidin-3-O-Rutinoside(21)
Ideain chloride_CE50(21)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(21)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(21)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(21)
cyanidin-3-sophoroside(21)
cyanidin-3-glucoside p-coumaric(21)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(21)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(21)
luteolin-7-O-glucoside_CE60(21)
kaempferol-3-O-rutinoside_CE50(21)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(21)
Ideain chloride_CE40(21)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(21)
Cyanidin 3-(3''-Acetyl)Glucoside(21)
kaempferol-7-O-neohesperidoside_CE20(21)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(21)
Kaempferol-3-Glucoside_CE30(21)
luteolin-7-O-glucoside_CE50(21)
cyanidin-3-xyloside-glucoside(21)
kaempferol-7-O-neohesperidoside_CE60(21)
cyanidin 3-sophoroside(21)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(19)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(19)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(19)
kaempferol-7-O-neohesperidoside_CE60(19)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(19)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(19)
Maritimein_CE30(18)
Kaempferol_CE30(18)
luteolin-4'-O-glucoside_CE60(16)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(16)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(15)
Poncirin_Ramp5-45 V(14)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(14)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_Ramp5-45 V(7)
cyanidin 3-(glucosyl)rhamnoside(7)
Cyanidin-3-O-alpha-arabinopyranoside_CE20(5)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p09095

ATH06p09285

ATH07p08716

ATH08p09480

ATH08p09601

ATH08p10079

ATH08p10081

ATH11p09441

ATH11p09444

ATH12p08523

ATH12p08524

ATH12p08902

ATH13p10835

ATH13p11250

ATH14p09938

ATH14p10255

ATH14p10259

ATH56p09527

ATH56p09787

ATH56p10058

ATH56p10584

ATH57p09358

ATH58p10874

ATH58p11352

ATH58p11572

ATH58p12050

ATH63p12345

ATH64p11513

ATH64p11764

ATH64p12422

ATH64p12612

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0071 0.0015 0.0013 0.0031
ATGE_7 0.0019 0.0013 0.0019 0.0014 0.0016
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0014 0.0014 0.002 0.0138 0.0046
ATGE_16 0.0321 0.0018 0.0027 0.0307 0.0168
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0019 0.0019
ATGE_25 0.0022 0.0018 0.0013 0.0015 0.0017
ATGE_26 0.0013 0.0011 0.002 0.0016 0.0015
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0458 0.1365 0.0025 0.0423 0.0568
ATGE_32 0.0036 0.0062 0.0331 0.0242 0.0168
ATGE_33 0.0016 0.0047 0.0041 0.0032 0.0034
ATGE_39 0.004 0.004 0.003 0.0026 0.0034
ATGE_41 0.0024 0.0163 0.0018 0.0018 0.0056
ATGE_42 0.0686 0.0189 0.0014 0.0361 0.0312
ATGE_45 0.0025 0.0023 0.0026 0.0036 0.0027
ATGE_76 0.0022 0.0017 0.0192 0.0188 0.0105
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.003 0.005 0.0014 0.0028 0.0031
ATGE_84 0.0018 0.0019 0.0177 0.0022 0.0059
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0017 0.0017 0.0258 0.005 0.0085
ATGE_93 0.2558 0.3132 0.2465 0.2122 0.257
ATGE_95 0.2237 0.2243 0.1809 0.0978 0.1817
ATGE_96 0.0021 0.0017 0.0017 0.0015 0.0018
ATGE_97 0.0016 0.0213 0.0162 0.0019 0.0103
ATGE_98 0.1128 0.2448 0.1268 0.1464 0.1577
ATGE_99 0.2866 0.3425 0.2125 0.2126 0.2635
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch