AtMetExpress Development LC-MS

Perk Nr:adp022794.

Polarity: [POSITIVE]
Retention time: 3.83
m/z: 611
Annotation:
Annotation level: Unknown
compound:
MS2Ts 50 MS2Ts
KNApSAcK C27H31O16(32):Isoscutellarein 7-allosyl-(1->2)-glucoside, Luteol
C31H31O13(8):4'-O-Methylcarthamidin 7-(2-p-coumaroylglucoside);
in-house MS/MS Hyperoside_Ramp5-45 V(45)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(45)
delphinidin 3-malonylglucoside(45)
delphinidin 3-arabinoside(45)
delphinidin 3-galactoside(45)
delphinidin 3-glucoside(45)
Peltatoside_Ramp5-45 V(45)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(45)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(45)
Quercetin-3-O-beta-D-galactoside_CE20(45)
delphinidin 3-(6''-coumaroyl)glucoside(45)
Quercetin-7-O-rhamnoside_Ramp5-45 V(45)
quercetin 3-O-a-rhamnopyranoside(45)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(45)
delphinidin 3-(6''-acetyl)glucoside(45)
Quercetin-3-Glucuronide_Ramp5-45 V(45)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(45)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(44)
Quercetin-3-Arabinoside_Ramp5-45 V(44)
Quercetin_CE10(44)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(44)
Quercetin-3-D-xyloside_Ramp5-45 V(44)
Spiraeoside_Ramp5-45 V(44)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(43)
Quercetin-3-Arabinoside_CE20(43)
Quercitrin_Ramp5-45 V(43)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(43)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(43)
Quercetin-3-D-xyloside_CE20(43)
PIPES_CE20(43)
Quercetin-3-Rhamnoside_Ramp5-45 V(43)
Quercetin_CE20(43)
Delphinidin-3-O-beta-glucopyranoside_CE50(43)
Quercetin-3-O-beta-D-galactoside_CE30(43)
Hesperetin_CE20(43)
(NC-OMe)-Hex ? isomer #1(43)
Quercetin-3-O-glucose-6''-acetate_CE20(43)
Hesperetin_CE10(43)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(43)
Hyperoside_CE20(43)
PIPES_CE10(43)
Quercetin_Ramp5-45 V(43)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(43)
Spiraeoside_CE30(42)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(42)
delphinidin 3-O-Glucoside(42)
quercetin-3-O-beta-glucopyranoside_CE20(42)
Rutin _CE40(42)
Delphinidin 3-Galactoside(42)
Peltatoside_CE40(42)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(42)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(42)
Delphinidin 3-Glucoside(42)
delphinidin 3-glucoside(42)
Peltatoside_CE20(42)
Peltatoside_CE30(42)
Rutin _CE50(42)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(42)
Quercetin-3-Glucuronide_CE20(42)
Quercetin-3-O-beta-D-galactoside_CE50(42)
Spiraeoside_CE50(42)
delphinidin 3-O-Glucoside(42)
Hyperoside_CE40(42)
delphinidin 3-glucoside(42)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(42)
Quercetin-3-Glucuronide_CE30(42)
Delphinidin 3-Glucoside(42)
quercetin 3-glucoside(42)
delphinidin 3-O-Glucoside(42)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(42)
quercetin-3-O-beta-glucopyranoside_CE30(42)
quercetin-3-O-beta-glucopyranoside_CE40(42)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(42)
Rutin _CE30(42)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(42)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(41)
Delphinidin-3-O-beta-glucopyranoside_CE60(41)
Spiraeoside_CE60(41)
Delphinidin-3-O-beta-glucopyranoside_CE40(41)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(41)
Quercetin-3-D-xyloside_CE30(41)
Ellagic Acid(39)
Quercetin-3-Glucuronide_CE40(39)
dihexosyl quercetin (39)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE60(39)
Quercetin-3-Arabinoside_CE30(39)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(39)
delphinidin 3-xyloside-glucoside(39)
delphinidin 3-glucoside p-coumaric(39)
Peltatoside_CE50(38)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(38)
Quercetin-3-O-beta-D-galactoside_CE40(38)
Quercitrin_CE20(38)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(37)
Quercetin-3-Rhamnoside_CE10(37)
rutin(37)
Spiraeoside_CE40(37)
herbacetin-7-O-rha(35)
quercetin-3'/4'-rha(35)
Quercitrin_CE10(35)
Quercetin-3-O-glucose-6''-acetate_CE40(34)
Peltatoside_CE60(33)
quercetin-3-O-beta-glucopyranoside_CE50(32)
Quercetin-3-Rhamnoside_CE20(32)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(29)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(28)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE60(18)
Quercetin-3-D-xyloside_CE50(18)
Quercetin 3'/4'-rhamnose(16)
rhodionin:7-O-? -L-rhamnopyranosylherbacetin(16)
Quercetin 3'/4'-rhamnose(16)
Herbacetin 7-O-rhamnose(16)
Hyperoside_CE30(14)
herbacetin-7-O-rha-8-O-glu(6)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p09267

ATH06p09722

ATH06p09725

ATH07p08485

ATH07p08925

ATH08p09720

ATH08p09723

ATH08p10188

ATH08p10415

ATH09p09031

ATH09p09488

ATH10p08148

ATH10p08483

ATH11p09113

ATH11p09425

ATH11p09539

ATH11p09760

ATH12p08833

ATH12p08999

ATH13p11231

ATH13p11581

ATH14p10055

ATH14p10489

ATH14p10783

ATH56p10037

ATH56p10565

ATH56p10830

ATH56p11095

ATH57p09338

ATH57p09604

ATH57p10128

ATH58p11553

ATH58p11817

ATH58p12253

ATH58p12511

ATH59p10170

ATH61p11603

ATH61p12130

ATH61p12391

ATH61p12395

ATH62p09444

ATH62p09963

ATH63p10151

ATH63p10937

ATH63p13059

ATH63p13773

ATH64p12160

ATH64p12401

ATH64p12803

ATH64p13040

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0019 0.0013 0.0019 0.0472 0.0131
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0077 0.0015 0.0014 0.0014 0.003
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0213 0.0067
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0728 0.0014 0.002 0.0021 0.0196
ATGE_16 0.0368 0.0149 0.0027 0.0105 0.0162
ATGE_19 0.0018 0.0037 0.0058 0.0018 0.0033
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0019 0.0019
ATGE_25 0.0022 0.0018 0.0013 0.0015 0.0017
ATGE_26 0.0013 0.0022 0.002 0.0016 0.0018
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0378 0.0022 0.0307 0.0399 0.0276
ATGE_32 0.0963 0.0834 0.0648 0.0569 0.0753
ATGE_33 0.0016 0.1036 0.0722 0.0601 0.0594
ATGE_39 0.0016 0.002 0.002 0.0017 0.0018
ATGE_41 0.0032 0.0015 0.0012 0.0012 0.0018
ATGE_42 0.0176 0.0014 0.015 0.0019 0.009
ATGE_45 0.0125 0.0015 0.0017 0.0081 0.006
ATGE_76 0.0022 0.0017 0.0016 0.183 0.0471
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.4307 0.0942 0.0216 0.21 0.1891
ATGE_84 0.0609 0.0019 0.0476 0.0523 0.0407
ATGE_91 0.1666 0.0811 0.0938 0.1147 0.1141
ATGE_92 0.0017 0.0017 0.0017 0.0025 0.0019
ATGE_93 0.0214 0.0186 0.0021 0.0023 0.0111
ATGE_95 0.0021 0.0019 0.0027 0.0125 0.0048
ATGE_96 0.1061 0.0763 0.1169 0.1319 0.1078
ATGE_97 0.0543 0.1271 0.143 0.1485 0.1182
ATGE_98 0.018 0.0034 0.0171 0.0015 0.01
ATGE_99 0.0019 0.0357 0.0019 0.0299 0.0173
ATGE_101 0.0865 0.0108 0.0021 0.0666 0.0415
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch