AtMetExpress Development LC-MS

Perk Nr:adp022795. Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside

Polarity: [POSITIVE]
Retention time: 3.99
m/z: 611
Annotation: Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside
Annotation level: Identified
compound: Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside
MS2Ts 59 MS2Ts
KNApSAcK C34H27O11(37):C34H26O10+O; C33H24O10+CH3O;
C27H31O16(36):Isoscutellarein 7-allosyl-(1->2)-glucoside, Luteol
C30H27O14(11):Prodelphinidin B4;Gallocatechin-(4alpha->8)-epigal
C31H31O13(8):4'-O-Methylcarthamidin 7-(2-p-coumaroylglucoside);
in-house MS/MS Hyperoside_Ramp5-45 V(54)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(54)
delphinidin 3-malonylglucoside(54)
delphinidin 3-arabinoside(54)
delphinidin 3-galactoside(54)
delphinidin 3-glucoside(54)
Peltatoside_Ramp5-45 V(54)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(54)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(54)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(54)
Quercetin-3-Arabinoside_Ramp5-45 V(54)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(54)
Quercetin-3-O-beta-D-galactoside_CE20(54)
delphinidin 3-(6''-coumaroyl)glucoside(54)
Quercetin-7-O-rhamnoside_Ramp5-45 V(54)
Quercetin_CE10(54)
quercetin 3-O-a-rhamnopyranoside(54)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(54)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(54)
Quercetin-3-D-xyloside_Ramp5-45 V(54)
delphinidin 3-(6''-acetyl)glucoside(54)
Quercetin-3-Glucuronide_Ramp5-45 V(54)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(54)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(54)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(53)
Quercetin-3-Arabinoside_CE20(53)
Quercitrin_Ramp5-45 V(53)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(53)
Quercetin-3-D-xyloside_CE20(53)
PIPES_CE20(53)
Quercetin-3-Rhamnoside_Ramp5-45 V(53)
Quercetin_CE20(53)
Delphinidin-3-O-beta-glucopyranoside_CE50(53)
Quercetin-3-O-beta-D-galactoside_CE30(53)
Hesperetin_CE20(53)
Quercetin-3-O-glucose-6''-acetate_CE20(53)
Hesperetin_CE10(53)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(53)
Hyperoside_CE20(53)
Spiraeoside_Ramp5-45 V(53)
PIPES_CE10(53)
Quercetin_Ramp5-45 V(53)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(53)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(52)
quercetin-3-O-beta-glucopyranoside_CE20(52)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(52)
Peltatoside_CE20(52)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(52)
(NC-OMe)-Hex ? isomer #1(52)
Hyperoside_CE40(52)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(52)
Quercetin-3-Glucuronide_CE30(52)
Hesperidin_Ramp5-45 V(51)
Spiraeoside_CE30(51)
delphinidin 3-O-Glucoside(51)
Quercetin-3-O-glucose-6''-acetate_CE50(51)
Ellagic Acid(51)
Quercetin-3-O-glucose-6''-acetate_CE30(51)
Rutin _CE40(51)
Delphinidin 3-Galactoside(51)
Peltatoside_CE40(51)
Quercetin-3-Glucuronide_CE40(51)
dihexosyl quercetin (51)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE60(51)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(51)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(51)
Delphinidin 3-Glucoside(51)
Quercetin-3-Arabinoside_CE30(51)
delphinidin 3-glucoside(51)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(51)
Peltatoside_CE30(51)
Delphinidin-3-O-beta-glucopyranoside_CE60(51)
Rutin _CE50(51)
Quercetin-3-Arabinoside_CE40(51)
Quercetin-3-Glucuronide_CE20(51)
Quercetin-3-O-beta-D-galactoside_CE50(51)
Spiraeoside_CE60(51)
Spiraeoside_CE50(51)
delphinidin 3-O-Glucoside(51)
delphinidin 3-glucoside(51)
Delphinidin-3-O-beta-glucopyranoside_CE40(51)
PIPES_CE30(51)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(51)
Quercetin-3-D-xyloside_CE40(51)
delphinidin 3-xyloside-glucoside(51)
Delphinidin 3-Glucoside(51)
quercetin 3-glucoside(51)
delphinidin 3-O-Glucoside(51)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(51)
delphinidin 3-glucoside p-coumaric(51)
quercetin-3-O-beta-glucopyranoside_CE30(51)
Quercetin-3-D-xyloside_CE30(51)
quercetin-3-O-beta-glucopyranoside_CE40(51)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(51)
Rutin _CE30(51)
Delphinidin-3-O-beta-glucopyranoside_CE30(51)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(51)
Quercetin-3-Rhamnoside_CE10(49)
Quercetin-3-O-glucose-6''-acetate_CE40(49)
Quercetin-3-Rhamnoside_CE20(48)
rutin(48)
Peltatoside_CE60(47)
quercetin-3-O-beta-glucopyranoside_CE50(45)
herbacetin-7-O-rha(44)
quercetin-3'/4'-rha(44)
Quercitrin_CE10(44)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(43)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE60(27)
Quercetin 3'/4'-rhamnose(22)
rhodionin:7-O-? -L-rhamnopyranosylherbacetin(22)
Quercetin 3'/4'-rhamnose(22)
Herbacetin 7-O-rhamnose(22)
Quercetin-3-D-xyloside_CE50(21)
herbacetin-7-O-rha-8-O-glu(11)
Quercetin-3-Rhamnoside_CE30(6)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p09267

ATH06p09602

ATH06p09725

ATH06p09957

ATH07p08485

ATH07p08925

ATH08p09723

ATH08p09726

ATH08p10188

ATH08p10191

ATH09p09031

ATH09p09488

ATH10p08148

ATH10p08483

ATH11p09113

ATH11p09341

ATH11p09539

ATH11p09832

ATH12p08615

ATH12p08833

ATH12p08999

ATH12p09262

ATH13p11231

ATH13p11234

ATH13p11581

ATH13p11584

ATH14p10055

ATH14p10058

ATH14p10489

ATH14p10492

ATH56p10037

ATH56p10040

ATH56p10830

ATH56p11101

ATH57p09338

ATH57p10128

ATH57p10131

ATH58p11553

ATH58p11556

ATH58p12253

ATH58p12256

ATH59p10170

ATH61p11603

ATH61p12137

ATH61p12395

ATH61p12923

ATH62p09178

ATH62p09444

ATH62p09963

ATH63p10151

ATH63p10937

ATH63p12584

ATH63p13059

ATH63p13306

ATH63p13773

ATH64p12160

ATH64p12407

ATH64p12803

ATH64p12806

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.5975 0.7339 0.8308 0.7193 0.7204
ATGE_7 0.8278 0.9469 1.0208 1.3406 1.034
ATGE_9 0.5148 1.2682 0.4827 0.1103 0.594
ATGE_10 0.145 0.1297 0.1186 0.1934 0.1466
ATGE_12 0.0491 0.0357 0.0311 0.0348 0.0377
ATGE_13 0.0991 0.0902 0.0585 0.3342 0.1455
ATGE_14 0.1651 0.136 0.1136 0.1205 0.1338
ATGE_15 0.5721 0.2676 0.1901 0.1978 0.3069
ATGE_16 0.3267 0.1842 0.146 0.3175 0.2436
ATGE_19 0.0683 0.0511 0.0919 0.0864 0.0744
ATGE_20 0.1503 0.1819 0.1628 0.2463 0.1853
ATGE_21 0.1512 0.3166 0.2643 0.1959 0.232
ATGE_25 0.047 0.0281 0.0632 0.0354 0.0434
ATGE_26 0.1178 0.1167 0.145 0.0793 0.1147
ATGE_27 0.2066 0.0631 0.193 0.3761 0.2097
ATGE_28 0.1484 0.1081 0.1121 0.3099 0.1696
ATGE_29 4.5861 2.8601 3.7883 6.8125 4.5118
ATGE_32 16.2118 14.0323 13.8341 13.2033 14.3203
ATGE_33 14.2852 15.0659 16.0949 14.5048 14.9877
ATGE_39 13.5887 13.6014 14.4795 11.5545 13.306
ATGE_41 2.6557 1.8461 3.7302 3.7302 2.9905
ATGE_42 13.6363 10.1704 11.1339 9.7595 11.175
ATGE_45 8.1065 7.2158 5.7946 6.1754 6.8231
ATGE_76 1.5026 0.4268 1.3381 1.4173 1.1712
ATGE_77 1.7734 1 0.9176 1.3038 1.2487
ATGE_78 2.5169 0.0538 0.0633 0.2757 0.7274
ATGE_84 5.2975 2.398 5.4899 5.9423 4.7819
ATGE_91 0.2872 0.3527 0.1009 0.258 0.2497
ATGE_92 7.0836 7.8062 9.9393 7.6995 8.1321
ATGE_93 13.3285 11.4024 11.3153 11.664 11.9276
ATGE_95 18.418 16.0345 18.5411 15.1511 17.0362
ATGE_96 1.5911 1.8605 1.8956 1.55 1.7243
ATGE_97 0.7682 1.5245 1.3103 1.314 1.2293
ATGE_98 13.6277 28.7962 14.6211 12.8274 17.4681
ATGE_99 15.6885 17.2677 14.1327 13.5929 15.1704
ATGE_101 0.0956 0.0627 0.1623 0.2399 0.1401
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch