AtMetExpress Development LC-MS

Perk Nr:adp022799.

Polarity: [POSITIVE]
Retention time: 4.5
m/z: 611
Annotation:
Annotation level: Unknown
compound: Rutin
MS2Ts 27 MS2Ts
KNApSAcK C27H31O16(13):Isoscutellarein 7-allosyl-(1->2)-glucoside, Luteol
C31H31O13(9):4'-O-Methylcarthamidin 7-(2-p-coumaroylglucoside);
C35H31O10(7):C35H30O11-O; C34H28O9+CH3O; C35H32O11-H2O;
C24H35O18(7):C18H24O13+C6H10O5;
C28H35O15(6):Hesperidin, Neohesperidin, 4,2',4'-Trihydroxy-6'-m
in-house MS/MS delphinidin 3-O-Glucoside(15)
Delphinidin 3-Galactoside(15)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(15)
Delphinidin 3-Glucoside(15)
delphinidin 3-glucoside(15)
(NC-OMe)-Hex ? isomer #1(15)
delphinidin 3-O-Glucoside(15)
delphinidin 3-glucoside(15)
Delphinidin 3-Glucoside(15)
quercetin 3-glucoside(15)
delphinidin 3-O-Glucoside(15)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(14)
Spiraeoside_CE30(14)
Hyperoside_Ramp5-45 V(14)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(14)
delphinidin 3-malonylglucoside(14)
Quercetin-3-Arabinoside_CE20(14)
Quercitrin_Ramp5-45 V(14)
delphinidin 3-arabinoside(14)
delphinidin 3-galactoside(14)
delphinidin 3-glucoside(14)
Peltatoside_Ramp5-45 V(14)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(14)
Quercetin-3-D-xyloside_CE20(14)
Quercetin_CE20(14)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(14)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(14)
Quercetin-3-Arabinoside_Ramp5-45 V(14)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(14)
Peltatoside_CE20(14)
Quercetin-3-O-beta-D-galactoside_CE20(14)
Delphinidin-3-O-beta-glucopyranoside_CE50(14)
delphinidin 3-(6''-coumaroyl)glucoside(14)
Quercetin-3-O-beta-D-galactoside_CE30(14)
Quercetin-7-O-rhamnoside_Ramp5-45 V(14)
Quercetin_CE10(14)
Hesperetin_CE20(14)
Quercetin-3-O-glucose-6''-acetate_CE20(14)
Hesperetin_CE10(14)
quercetin 3-O-a-rhamnopyranoside(14)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(14)
Quercetin-3-D-xyloside_Ramp5-45 V(14)
Hyperoside_CE20(14)
delphinidin 3-(6''-acetyl)glucoside(14)
Spiraeoside_Ramp5-45 V(14)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(14)
PIPES_CE10(14)
rutin(14)
Quercetin-3-Glucuronide_Ramp5-45 V(14)
Quercetin_Ramp5-45 V(14)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(14)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(14)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(13)
Quercetin-3-Rhamnoside_Ramp5-45 V(13)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(13)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(13)
Quercetin-3-Glucuronide_CE30(13)
quercetin-3-O-beta-glucopyranoside_CE30(13)
quercetin-3-O-beta-glucopyranoside_CE40(13)
quercetin-3-O-beta-glucopyranoside_CE20(12)
Rutin _CE40(12)
PIPES_CE20(12)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(12)
Peltatoside_CE30(12)
Hyperoside_CE40(12)
Rutin _CE30(12)
Quercetin-3-O-glucose-6''-acetate_CE50(11)
Peltatoside_CE40(11)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(11)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(11)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(11)
Quercetin-3-O-beta-D-galactoside_CE40(11)
Delphinidin-3-O-beta-glucopyranoside_CE60(11)
Rutin _CE50(11)
Quercetin-3-Arabinoside_CE40(11)
Quercetin-3-Glucuronide_CE20(11)
Quercetin-3-O-beta-D-galactoside_CE50(11)
Spiraeoside_CE60(11)
Spiraeoside_CE50(11)
Delphinidin-3-O-beta-glucopyranoside_CE40(11)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(11)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(11)
Quercetin-3-D-xyloside_CE30(11)
Delphinidin-3-O-beta-glucopyranoside_CE30(11)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(11)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(11)
quercetin-3-O-beta-glucopyranoside_CE50(9)
Quercetin-3-Rhamnoside_CE20(9)
Peltatoside_CE60(9)
Quercetin-3-O-glucose-6''-acetate_CE40(9)
herbacetin-7-O-rha(8)
quercetin-3'/4'-rha(8)
Rutin _CE20(7)
Q-Hex (T4). (7)
Quercitrin_CE10(6)
Hyperoside_CE30(6)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE60(6)
Quercetin-3-D-xyloside_CE50(6)
delphinidin 3-glucoside(5)
Ellagic acid hexose(5)
Delphinidin-3-O-beta-glucopyranoside_CE20(5)
delphinidin 3,5-diglucoside(5)
delphinidin 3-glucoside(5)
delphinidin 3-rutinoside(5)
delphinidin 3-galactoside(5)
delphinidin 3-glucoside(5)
delphinidin 3-glucoside(5)
Delphinidin 3,5-Diglucoside(4)
delphinidin 3-glucoside-5-rhamnoside(4)
Cyanidin-3-O-Glucoside(4)
Quercetin-3-O-beta-D-galactoside_CE10(4)
similar to peak 7(4)
Spiraeoside_CE20(4)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(4)
(NC-OMe)-Hex ? isomer #2(4)
quercetin-3-O-beta-glucopyranoside_CE10(4)
quercetin 3-rutinoside(4)
quercetin 3-neo hesperidoside(4)
delphinidin 3-O-Rutinoside(4)
Quercetin hexose(4)
rhamnosyl hexosyl quercetin (4)
Delphinidin 3-Rutinoside(4)
delphinidin 3-O-Rutinoside(4)
delphinidin 3-glucoside-5-acetylrhamnoside(4)
N1-Acetylspermine Trihydrochloride_CE30(3)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE30(3)
delta-Tocotrienol_Ramp5-45 V(3)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(3)
4-Hydroxybenzoate_Ramp5-45 V(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p09512

ATH06p09734

ATH08p10199

ATH11p09123

ATH11p09126

ATH11p09548

ATH11p09770

ATH12p08843

ATH13p11242

ATH13p11815

ATH14p10067

ATH14p10070

ATH14p10501

ATH14p10504

ATH56p11366

ATH57p10137

ATH58p11831

ATH58p12525

ATH61p11613

ATH61p12406

ATH62p09187

ATH63p13071

ATH63p13785

ATH64p12170

ATH64p12173

ATH64p12812

ATH64p12816

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0019 0.0013 0.0019 0.0021 0.0018
ATGE_9 0.0021 0.003 0.0195 0.002 0.0067
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0014 0.0014 0.002 0.0021 0.0017
ATGE_16 0.0018 0.0018 0.0027 0.0017 0.002
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0019 0.0019
ATGE_25 0.0022 0.0018 0.0106 0.0015 0.004
ATGE_26 0.0013 0.0022 0.002 0.0016 0.0018
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0112 0.0022 0.0017 0.0016 0.0042
ATGE_32 0.0036 0.0044 0.0015 0.0016 0.0028
ATGE_33 0.0016 0.0037 0.0051 0.0053 0.0039
ATGE_39 0.0032 0.003 0.003 0.0017 0.0027
ATGE_41 0.004 0.0031 0.0012 0.0012 0.0024
ATGE_42 0.0037 0.0014 0.0014 0.0019 0.0021
ATGE_45 0.0025 0.0015 0.0026 0.0018 0.0021
ATGE_76 0.0469 0.0119 0.0689 0.0868 0.0536
ATGE_77 0.1679 0.0554 0.064 0.1096 0.0992
ATGE_78 0.161 0.0033 0.0014 0.0142 0.045
ATGE_84 0.0145 0.0227 0.0322 0.0166 0.0215
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0017 0.0017 0.0017 0.0025 0.0019
ATGE_93 0.0624 0.086 0.0793 0.0606 0.0721
ATGE_95 0.1733 0.1447 0.1067 0.1143 0.1348
ATGE_96 0.0014 0.0124 0.0152 0.0015 0.0076
ATGE_97 0.0016 0.017 0.0121 0.0019 0.0082
ATGE_98 0.1786 0.2277 0.1939 0.1625 0.1907
ATGE_99 0.1961 0.2204 0.1157 0.1121 0.1611
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch