AtMetExpress Development LC-MS

Perk Nr:adp023750. Quercetin-3-Glu-7-Hex

Polarity: [POSITIVE]
Retention time: 4.1
m/z: 627
Annotation: Quercetin-3-Glu-7-Hex
Annotation level: Characterized
compound:
MS2Ts 30 MS2Ts
KNApSAcK C34H27O12(17):C33H24O11+CH3O;
C27H31O17(16):6-Hydroxyluteolin 7-sophoroside, 6-Hydroxyluteolin
C24H35O17S1(13):C18H24O12S+C6H10O5;
C30H27O15(4):6-Hydroxykaempferol 7-(6''-(E)-caffeylglucoside) ,
in-house MS/MS Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(19)
Spiraeoside_CE30(19)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(19)
Hyperoside_Ramp5-45 V(19)
quercetin-3-O-beta-glucopyranoside_CE20(19)
delphinidin 3-malonylglucoside(19)
Quercetin-3-Arabinoside_CE20(19)
Quercitrin_Ramp5-45 V(19)
delphinidin 3-arabinoside(19)
delphinidin 3-galactoside(19)
Rutin _CE40(19)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(19)
Peltatoside_CE40(19)
delphinidin 3-glucoside(19)
Peltatoside_Ramp5-45 V(19)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(19)
Quercetin-3-D-xyloside_CE20(19)
PIPES_CE20(19)
Quercetin-3-Rhamnoside_Ramp5-45 V(19)
Quercetin_CE20(19)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(19)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(19)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(19)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(19)
Quercetin-3-Arabinoside_Ramp5-45 V(19)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(19)
Peltatoside_CE20(19)
Quercetin-3-O-beta-D-galactoside_CE20(19)
Peltatoside_CE30(19)
Delphinidin-3-O-beta-glucopyranoside_CE60(19)
Delphinidin-3-O-beta-glucopyranoside_CE50(19)
Rutin _CE50(19)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(19)
delphinidin 3-(6''-coumaroyl)glucoside(19)
Quercetin-3-O-beta-D-galactoside_CE30(19)
Quercetin-7-O-rhamnoside_Ramp5-45 V(19)
Quercetin_CE10(19)
Hesperetin_CE20(19)
Quercetin-3-Glucuronide_CE20(19)
(NC-OMe)-Hex ? isomer #1(19)
Quercetin-3-O-glucose-6''-acetate_CE20(19)
Quercetin-3-O-beta-D-galactoside_CE50(19)
Spiraeoside_CE60(19)
Hesperetin_CE10(19)
Spiraeoside_CE50(19)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(19)
quercetin 3-O-a-rhamnopyranoside(19)
Hyperoside_CE40(19)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(19)
Delphinidin-3-O-beta-glucopyranoside_CE40(19)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(19)
Quercetin-3-D-xyloside_Ramp5-45 V(19)
Quercetin-3-Glucuronide_CE30(19)
Hyperoside_CE20(19)
delphinidin 3-(6''-acetyl)glucoside(19)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(19)
Spiraeoside_Ramp5-45 V(19)
quercetin-3-O-beta-glucopyranoside_CE30(19)
Quercetin-3-D-xyloside_CE30(19)
quercetin-3-O-beta-glucopyranoside_CE40(19)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(19)
PIPES_CE10(19)
Rutin _CE30(19)
Quercetin-3-Glucuronide_Ramp5-45 V(19)
Quercetin_Ramp5-45 V(19)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(19)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(19)
Delphinidin-3-O-beta-glucopyranoside_CE30(19)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(19)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(19)
Peltatoside_CE50(18)
Hesperidin_Ramp5-45 V(18)
delphinidin 3-O-Glucoside(18)
Quercetin-3-O-glucose-6''-acetate_CE50(18)
Ellagic Acid(18)
Quercetin-3-O-glucose-6''-acetate_CE30(18)
Delphinidin 3-Galactoside(18)
Quercetin-3-Glucuronide_CE40(18)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(18)
quercetin-3-O-beta-glucopyranoside_CE50(18)
dihexosyl quercetin (18)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(18)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE60(18)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(18)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(18)
Quercetin-3-O-beta-D-galactoside_CE40(18)
Delphinidin 3-Glucoside(18)
Quercetin-3-Arabinoside_CE30(18)
delphinidin 3-glucoside(18)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(18)
Quercetin-3-Arabinoside_CE40(18)
Quercetin-3-Rhamnoside_CE20(18)
Quercitrin_CE20(18)
Peltatoside_CE60(18)
delphinidin 3-O-Glucoside(18)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(18)
delphinidin 3-glucoside(18)
PIPES_CE30(18)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(18)
Quercetin-3-D-xyloside_CE40(18)
delphinidin 3-xyloside-glucoside(18)
Delphinidin 3-Glucoside(18)
quercetin 3-glucoside(18)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE40(18)
delphinidin 3-O-Glucoside(18)
delphinidin 3-glucoside p-coumaric(18)
Quercetin-3-O-glucose-6''-acetate_CE40(18)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE60(18)
Spiraeoside_CE40(18)
Hyperoside_CE30(17)
rutin(17)
Quercetin-3-D-xyloside_CE50(17)
Quercetin-3-Rhamnoside_CE10(14)
Quercetin-3-Rhamnoside_CE30(9)
Rutin _CE60(6)
Q-Hex (T4). (4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p09269

ATH06p09505

ATH06p09726

ATH07p08487

ATH07p08927

ATH07p09136

ATH08p09961

ATH08p10066

ATH08p10190

ATH09p09037

ATH09p09706

ATH10p08344

ATH10p08489

ATH11p09340

ATH11p09541

ATH12p08835

ATH12p09002

ATH14p10792

ATH56p10039

ATH56p10573

ATH56p10831

ATH57p09340

ATH58p11821

ATH58p11824

ATH58p12255

ATH61p11605

ATH61p12666

ATH62p10488

ATH63p10426

ATH64p12598

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0039 0.0015 0.002 0.0025
ATGE_7 0.0019 0.0013 0.0019 0.0014 0.0016
ATGE_9 0.0021 0.0113 0.0023 0.0163 0.008
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0014 0.0014 0.002 0.0021 0.0017
ATGE_16 0.0018 0.0018 0.0027 0.0017 0.002
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0019 0.0019
ATGE_25 0.0014 0.0018 0.0053 0.0015 0.0025
ATGE_26 0.0211 0.0321 0.0214 0.0122 0.0217
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.1344 0.1231 0.3208 0.3406 0.2297
ATGE_32 6.1172 4.8761 4.1057 4.4535 4.8881
ATGE_33 3.084 3.6786 2.9236 3.4511 3.2843
ATGE_39 1.6281 1.7502 1.4529 1.5065 1.5844
ATGE_41 0.1696 0.2261 0.2024 0.2024 0.2001
ATGE_42 0.641 0.5035 0.5716 0.561 0.5693
ATGE_45 1.2818 1.4877 0.9973 0.9763 1.1858
ATGE_76 0.0357 0.0017 0.0256 0.0303 0.0233
ATGE_77 0.0594 0.0255 0.0167 0.0211 0.0307
ATGE_78 0.041 0.0033 0.0014 0.0028 0.0121
ATGE_84 0.0018 0.0099 0.0016 0.0136 0.0067
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 2.0887 2.3471 2.115 2.0329 2.1459
ATGE_93 0.002 0.0031 0.0021 0.0015 0.0022
ATGE_95 0.0031 0.0028 0.0018 0.0015 0.0023
ATGE_96 0.0021 0.0017 0.0017 0.0015 0.0018
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0015 0.0068 0.0016 0.0023 0.003
ATGE_99 0.0028 0.0013 0.0019 0.0021 0.002
ATGE_101 0.0018 0.0015 0.0512 0.0255 0.02
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch