AtMetExpress Development LC-MS

Perk Nr:adp026744.

Polarity: [POSITIVE]
Retention time: 4.49
m/z: 681
Annotation:
Annotation level: Unknown
compound:
MS2Ts 21 MS2Ts
KNApSAcK C34H33O13S1(8):C34H34O14S-H2O;
C30H33O18(7):Luteolin 7-(6''-malonylneohesperidoside), Kaempfer
C33H29O16(4):C33H30O17-H2O;
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(8)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(8)
cyanidin 3-O-rhamnoside(8)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(8)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(8)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(8)
cyanidin-3-O-rhamnoside chloride_CE20(8)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(8)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(8)
Robinin_Ramp5-45 V(8)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(8)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(8)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(8)
cyanidin 3-(glucosyl)rhamnoside(8)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(8)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(8)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(8)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(8)
kaempferol 3-O-a-rhamnopyranoside(8)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(8)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(7)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(7)
Robinin_CE40(7)
cyanidin-3,5-di-O-glucoside chloride_CE60(6)
kaempferol-3-O-rutinoside_Ramp5-45 V(6)
Kaempferol-3-Glucoside_CE20(6)
Ideain chloride_CE30(6)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(6)
cyanidin 3-diglucoside(6)
Poncirin_CE40(6)
Kaempferol-3-Rhamnoside_Ramp5-45 V(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(6)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(6)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(6)
Luteolin_CE20(6)
Kaempferol-3-Glucuronide_CE30(6)
Keracyanin Chloride_CE60(6)
kaempferol-7-O-neohesperidoside_CE30(6)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(6)
luteolin-4'-O-glucoside_Ramp5-45 V(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(6)
cyanidin-3-glucoside chloride_Ramp5-45 V(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(6)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(6)
luteolin-4'-O-glucoside_CE40(6)
cyanidin 3-(6''-acetyl)galactoside(6)
cyanidin 3-sambubinoside(6)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(6)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(6)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(6)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(6)
Poncirin_CE30(6)
Isosakuranetin_CE10(6)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(6)
Cyanidin 3-(Glucosyl)Rhamnoside(6)
Datiscin_CE30(6)
Luteolin_CE10(6)
kaempferol-3-O-glucoside_Ramp5-45 V(6)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(6)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(6)
Poncirin_CE20(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(6)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(6)
Luteolin_Ramp5-45 V(6)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(6)
Kaempferol-3-Glucoside_Ramp5-45 V(6)
Robinin_CE50(6)
Keracyanin Chloride_CE40(6)
Keracyanin Chloride_CE50(6)
Kaempferol-3-Glucuronide_CE20(6)
kaempferol-7-O-neohesperidoside_CE40(6)
Maritimein_Ramp5-45 V(6)
Kaempferol-3-Glucoside_CE40(6)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(6)
kaempferol-3-O-glucoside_CE40(6)
Keracyanin Chloride_Ramp5-45 V(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(6)
cyanidin 3-(6''-maronoyl)-laminaribiose(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(6)
cyanidin 3-galactoside(6)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(6)
kaempferol-7-O-neohesperidoside_CE40(6)
Kaempferol-3-O-alpha-L-arabinoside_CE20(6)
Datiscin_CE20(6)
cyanidin 3-glucoside(6)
cyanidin 3-malonylglucoside(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(6)
luteolin-7-O-glucoside_CE30(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(6)
cyanidin-3-O-rhamnoside chloride_CE60(6)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(6)
Sakuranetin_CE10(6)
Ideain chloride_Ramp5-45 V(6)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(6)
cyanidin 3-(6''-coumaroyl)glucoside(6)
Datiscin_Ramp5-45 V(6)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(6)
cyanidin 3-sophoroside(6)
luteolin-7-O-glucoside_Ramp5-45 V(6)
Kaempferol_CE10(6)
cyanidin 3-laminaribiose(6)
Kaempferol-3-Glucuronide_Ramp5-45 V(6)
cyanidin 3-arabinoside(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(6)
kaempferol-7-O-neohesperidoside_CE50(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(6)
luteolin-3',7-di-O-glucoside _CE50(6)
kaempferol-3-O-glucoside_CE30(6)
cyanidin-3,5-di-O-glucoside chloride_CE40(6)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(6)
kaempferol-3-O-glucoside_CE20(6)
cyanidin-3-glucoside chloride_CE40(6)
Sakuranetin_CE20(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(6)
cyanidin 3-dioxaloylglucoside(6)
cyanidin 7-arabinoside(6)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(6)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(6)
Maritimein_CE20(6)
cyanidin-3-O-rhamnoside chloride_CE30(6)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(6)
Datiscin_CE50(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(6)
Datiscin_CE40(6)
cyanidin 3-sophoroside(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(6)
cyanidin 3-xyloside(6)
luteolin-4'-O-glucoside_CE30(6)
kaempferol-3-O-rutinoside_CE40(6)
cyanidin 3-(6''-acetoyl)glucoside(6)
Kaempferol_CE20(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(5)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(5)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(5)
Cyanidin-3-O-Glucoside(5)
luteolin-4'-O-glucoside_CE50(5)
cyanidin-3,5-di-O-glucoside chloride_CE50(5)
cyanidin-3-glucoside chloride_CE30(5)
cyanidin-3-glucoside chloride_CE50(5)
Isosakuranetin_CE20(5)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(5)
cyanidin-3-glucoside chloride_CE60(5)
Ideain chloride_CE60(5)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(5)
Datiscin_CE60(5)
kaempferol-3-O-rutinoside_CE30(5)
luteolin-7-O-glucoside_CE20(5)
Luteolin_CE40(5)
cyanidin-3-O-rhamnoside chloride_CE40(4)
kaempferol-7-O-neohesperidoside_CE50(4)
kaempferol-7-O-neohesperidoside_CE30(4)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(4)
Maritimein_CE40(4)
luteolin-3',7-di-O-glucoside _CE60(4)
luteolin-7-O-glucoside_CE60(4)
kaempferol-3-O-rutinoside_CE50(4)
Ideain chloride_CE40(4)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(4)
kaempferol-7-O-neohesperidoside_CE60(4)
cyanidin-3-O-rhamnoside chloride_CE50(3)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(3)
luteolin-7-O-glucoside_CE40(3)
Ideain chloride_CE50(3)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(3)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(3)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(3)
kaempferol-7-O-neohesperidoside_CE20(3)
Kaempferol-3-Glucoside_CE30(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p10177

ATH06p10605

ATH08p10611

ATH08p11001

ATH12p09610

ATH14p11203

ATH14p11614

ATH56p11624

ATH56p11627

ATH56p12391

ATH57p11195

ATH58p12885

ATH58p13498

ATH59p11641

ATH61p13697

ATH61p14440

ATH62p11268

ATH62p11779

ATH63p12205

ATH64p13423

ATH64p14097

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0023 0.0015 0.0013 0.0019
ATGE_7 0.0135 0.0136 0.0159 0.0014 0.0111
ATGE_9 0.0021 0.002 0.038 0.002 0.011
ATGE_10 0.0069 0.0023 0.0014 0.0014 0.003
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0088 0.0036
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.019 0.0014 0.002 0.0021 0.0061
ATGE_16 0.0018 0.0074 0.0027 0.0017 0.0034
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0018 0.0018
ATGE_21 0.0019 0.0021 0.0017 0.0096 0.0038
ATGE_25 0.0014 0.0018 0.0066 0.0015 0.0028
ATGE_26 0.0013 0.0011 0.002 0.0114 0.0039
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0354 0.0388 0.0358 0.048 0.0395
ATGE_32 0.1081 0.0969 0.0864 0.0828 0.0935
ATGE_33 0.0585 0.0414 0.0454 0.0461 0.0479
ATGE_39 0.0337 0.0397 0.0316 0.0139 0.0297
ATGE_41 0.0024 0.0015 0.0012 0.0012 0.0016
ATGE_42 0.0018 0.0014 0.0114 0.0019 0.0041
ATGE_45 0.0226 0.0176 0.0115 0.0136 0.0163
ATGE_76 0.0119 0.0017 0.0176 0.002 0.0083
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.002 0.0033 0.0014 0.0028 0.0024
ATGE_84 0.0018 0.0019 0.0016 0.0015 0.0017
ATGE_91 0.0159 0.002 0.0017 0.0119 0.0079
ATGE_92 0.0605 0.0508 0.0633 0.0632 0.0595
ATGE_93 0.0419 0.0238 0.0275 0.0295 0.0307
ATGE_95 0.084 0.0632 0.0579 0.0665 0.0679
ATGE_96 0.0014 0.0017 0.0116 0.0119 0.0067
ATGE_97 0.0016 0.016 0.002 0.0019 0.0054
ATGE_98 0.0219 0.0034 0.0278 0.0214 0.0186
ATGE_99 0.0209 0.0195 0.0149 0.0202 0.0189
ATGE_101 0.0018 0.0015 0.0128 0.0164 0.0081
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch