AtMetExpress Development LC-MS

Perk Nr:adp030263. "Kaempferol-3-O-a-L-rhamnopyranosyl(1,2)-b-D-glucopyranoside-7-O-a-L-rhamnopyranoside_1"

Polarity: [POSITIVE]
Retention time: 3.74
m/z: 741
Annotation: "Kaempferol-3-O-a-L-rhamnopyranosyl(1,2)-b-D-glucopyranoside-7-O-a-L-rhamnopyranoside_1"
Annotation level: Identified
compound: Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside: Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside
MS2Ts 27 MS2Ts
KNApSAcK C33H41O19(19):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(15):C32H42N2O17S-H2O;
C44H37O11(12):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C35H37N2O16(12):C35H36N2O15+O;
C37H41O16(6):C37H40O15+O;
C36H37O17(4):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(24)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(24)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(24)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(24)
Poncirin_CE20(24)
cyanidin 3-O-rhamnoside(24)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(24)
Robinin_CE40(24)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(24)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(24)
cyanidin-3-O-rhamnoside chloride_CE20(24)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(24)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(24)
Robinin_Ramp5-45 V(24)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(24)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(24)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(24)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(24)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(24)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(24)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(24)
kaempferol 3-O-a-rhamnopyranoside(24)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(24)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(23)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(23)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(23)
Keracyanin Chloride_Ramp5-45 V(23)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(22)
kaempferol-3-O-rutinoside_Ramp5-45 V(21)
cyanidin 3-diglucoside(21)
cyanidin 3-(6''-acetyl)galactoside(21)
cyanidin 3-sambubinoside(21)
cyanidin 3-rutinoside(21)
Isosakuranetin_CE10(21)
kaempferol-3-O-glucoside_Ramp5-45 V(21)
Cyanidin-3-O-Rutinoside(21)
cyanidin 3-(6''-maronoyl)-laminaribiose(21)
cyanidin 3-galactoside(21)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(21)
cyanidin-3-glucoside p-coumaric(21)
cyanidin 3-glucoside(21)
cyanidin 3-malonylglucoside(21)
cyanidin 3-(6''-coumaroyl)glucoside(21)
cyanidin 3-sophoroside(21)
cyanidin 3-laminaribiose(21)
cyanidin 3-arabinoside(21)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(21)
cyanidin 3-dioxaloylglucoside(21)
cyanidin 7-arabinoside(21)
cyanidin 3-(glucosyl)rhamnoside(21)
cyanidin 3-sophoroside(21)
cyanidin 3-xyloside(21)
cyanidin 3-(6''-acetoyl)glucoside(21)
cyanidin-3-glucoside chloride_Ramp5-45 V(19)
luteolin-4'-O-glucoside_CE40(19)
Poncirin_CE30(19)
Keracyanin Chloride_CE40(19)
luteolin-7-O-glucoside_CE30(19)
Ideain chloride_Ramp5-45 V(19)
luteolin-7-O-glucoside_Ramp5-45 V(19)
Kaempferol_CE10(19)
Kaempferol-3-Glucoside_CE20(18)
Datiscin_CE20(18)
Ideain chloride_CE30(17)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(17)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(17)
luteolin-4'-O-glucoside_Ramp5-45 V(17)
cyanidin 3-O-galactosyl-rhamnoside(17)
Luteolin_Ramp5-45 V(17)
Robinin_CE50(17)
kaempferol-7-O-neohesperidoside_CE40(17)
kaempferol 3-O-b-glucopyranoside-7-O-a-rhamnopyranoside(17)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(17)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(17)
cyanidin 3-rutinoside(17)
Maritimein_CE20(17)
kaempferol-7-O-neohesperidoside_CE40(16)
kaempferol-7-O-neohesperidoside_CE50(16)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(16)
kaempferol-7-O-neohesperidoside_CE30(15)
Cyanidin-3-O-Glucoside(15)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(15)
Datiscin_CE30(15)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(15)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(14)
Luteolin_CE20(14)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(14)
Maritimein_Ramp5-45 V(14)
kaempferol-3-O-glucoside_CE40(14)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(14)
Kaempferol-3-O-alpha-L-arabinoside_CE20(14)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(14)
Sakuranetin_CE20(14)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(14)
cyanidin-3-O-rhamnoside chloride_CE30(14)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(14)
luteolin-4'-O-glucoside_CE30(14)
Kaempferol_CE20(14)
Kaempferol-3-Glucuronide_CE30(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(13)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(13)
kaempferol-3-O-glucoside_CE30(13)
cyanidin-3-glucoside chloride_CE40(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(13)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(12)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(12)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(12)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(12)
Keracyanin Chloride_CE50(12)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(12)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(12)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(12)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(12)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(11)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(11)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(11)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(11)
Kaempferol-3-Glucoside_CE40(11)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(11)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(11)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(11)
cyanidin-3,5-di-O-glucoside chloride_CE40(11)
kaempferol-3-O-glucoside_CE20(11)
kaempferol-7-O-neohesperidoside_CE20(11)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(11)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(11)
Datiscin_CE40(11)
kaempferol-3-O-rutinoside_CE40(11)
Poncirin_CE40(9)
cyanidin-3-O-rhamnoside chloride_CE60(9)
Datiscin_CE60(9)
kaempferol-7-O-neohesperidoside_CE30(8)
cyanidin-3-glucoside chloride_CE30(8)
kaempferol-3-O-rutinoside_CE30(8)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(7)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(7)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(6)
luteolin-4'-O-glucoside_CE50(6)
Isosakuranetin_CE20(6)
cyanidin-3-glucoside chloride_CE60(6)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(6)
kaempferol-3-O-rutinoside_CE50(6)
luteolin-7-O-glucoside_CE20(6)
cyanidin 3-glucoside(5)
cyanidin-3-glucoside chloride_CE20(5)
cyanidin-3-O-rhamnoside chloride_CE40(5)
Cyanidin 3-Diglucoside(5)
Cyanidin 3-(3''-Malonyl)Glucoside(5)
cyanidin-3-O-rhamnoside chloride_CE50(5)
Cyanidin 3-Glucoside(5)
kaempferol-7-O-neohesperidoside_CE50(5)
Cyanidin 3-(6''-Malonyl Glucoside)(5)
kaempferol-3-O-rutinoside_CE20(5)
luteolin-7-O-glucoside_CE40(5)
Cyanidin 3-Laminaribioside(5)
Kaempferol 3-Glucoside(5)
Cyanidin 3-(3''-Malonyl)Glucoside(5)
Cyanidin 3-O-glucuronide(5)
Cyanidin 3-(6''-Acetyl) Glucoside(5)
Dehydroevodiamine(5)
Maritimein_CE40(5)
divaricataester C(5)
Cyanidin-3-O-Glucoside(5)
cyanidin 3-glucoside(5)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(5)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(5)
Ideain chloride_CE50(5)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(5)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(5)
luteolin-3',7-di-O-glucoside _CE60(5)
cyanidin-3-sophoroside(5)
Cyanidin 3-Glucoside(5)
Cyanidin 3-Glucoside(5)
cyanidin-3-glucoside(5)
luteolin-7-O-glucoside_CE60(5)
Ideain chloride_CE40(5)
Cyanidin 3-Galactoside(5)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(5)
Cyanidin 3-(3''-Acetyl)Glucoside(5)
Cyanidin 3-Glucoside(5)
Kaempferol-3-Glucoside_CE30(5)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(5)
luteolin-7-O-glucoside_CE50(5)
cyanidin-3-xyloside-glucoside(5)
kaempferol-7-O-neohesperidoside_CE60(5)
cyanidin 3-sophoroside(5)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(4)
Robinin_CE60(4)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(4)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(4)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(4)
kaempferol-7-O-neohesperidoside_CE60(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(4)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(4)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(4)
kaempferol-7-O-neohesperidoside(3)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(3)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE50(3)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(3)
luteolin-4'-O-glucoside_CE60(3)
Poncirin_Ramp5-45 V(3)
Keracyanin Chloride_CE30(3)
Maritimein_CE30(3)
Kaempferol_CE30(3)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(3)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE50(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11023

ATH06p11026

ATH07p10022

ATH07p10025

ATH07p10026

ATH08p11462

ATH09p10909

ATH10p09328

ATH11p10919

ATH11p10984

ATH12p10027

ATH12p10030

ATH13p12918

ATH14p11717

ATH56p13121

ATH57p12419

ATH57p12422

ATH58p14121

ATH58p14124

ATH59p11959

ATH61p14649

ATH61p15123

ATH62p12216

ATH62p12219

ATH63p13123

ATH63p15460

ATH64p14411

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.4333 0.8764 0.9423 1.2046 0.8642
ATGE_7 4.5077 5.2965 4.8238 5.0528 4.9202
ATGE_9 0.2546 0.6084 0.3064 0.0827 0.313
ATGE_10 2.4685 1.9094 3.4418 2.0502 2.4675
ATGE_12 1.3323 1.1054 1.2238 1.0897 1.1878
ATGE_13 1.8016 1.6627 1.3845 8.1084 3.2393
ATGE_14 1.5351 2.0486 1.9455 2.0187 1.887
ATGE_15 11.9306 5.9241 1.8735 5.8968 6.4063
ATGE_16 13.0066 12.2329 12.3407 12.978 12.6395
ATGE_19 1.102 0.6571 1.5779 1.2373 1.1436
ATGE_20 4.9707 3.199 5.3576 5.9483 4.8689
ATGE_21 5.1926 3.7127 6.0833 6.0518 5.2601
ATGE_25 1.5679 1.8533 1.8855 1.564 1.7177
ATGE_26 7.343 11.243 3.0531 7.3246 7.2409
ATGE_27 2.3123 2.0995 2.9327 3.0986 2.6108
ATGE_28 1.3841 1.5101 0.8491 2.2627 1.5015
ATGE_29 26.351 27.5582 26.2517 26.0366 26.5494
ATGE_32 16.5545 18.3438 16.9938 15.6753 16.8918
ATGE_33 20.8268 21.2356 21.9742 19.494 20.8826
ATGE_39 23.7285 23.5698 21.3098 18.0925 21.6751
ATGE_41 4.5318 2.1118 1.6454 1.6454 2.4836
ATGE_42 28.9165 24.4726 22.6561 24.2932 25.0846
ATGE_45 7.9119 8.6804 5.9008 5.9336 7.1067
ATGE_76 4.4653 1.2745 4.1394 2.0826 2.9904
ATGE_77 5.0447 3.0554 3.3521 3.9153 3.8419
ATGE_78 4.1958 5.0656 0.8308 3.2642 3.3391
ATGE_84 0.0409 0.0415 0.0476 0.0599 0.0475
ATGE_91 1.0812 1.0651 1.0186 1.1643 1.0823
ATGE_92 21.5895 19.3798 21.727 19.9957 20.673
ATGE_93 6.0409 2.8112 2.8888 4.3297 4.0176
ATGE_95 4.1376 3.0268 3.6144 2.4432 3.3055
ATGE_96 0.2424 0.1882 0.1555 0.3553 0.2354
ATGE_97 1.0534 1.7051 2.0466 1.7537 1.6397
ATGE_98 3.13 10.5753 3.3518 3.2162 5.0683
ATGE_99 5.2704 6.0809 4.8293 2.3301 4.6277
ATGE_101 0.7677 0.5499 0.6335 0.8649 0.704
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch