AtMetExpress Development LC-MS

Perk Nr:adp030264.

Polarity: [POSITIVE]
Retention time: 3.95
m/z: 741
Annotation:
Annotation level: Unknown
compound:
MS2Ts 20 MS2Ts
KNApSAcK C33H41O19(9):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(9):C32H42N2O17S-H2O;
C35H37N2O16(7):C35H36N2O15+O;
C44H37O11(5):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C36H37O17(5):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
in-house MS/MS cyanidin 3-O-rhamnoside(15)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(15)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(15)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(15)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(15)
Robinin_Ramp5-45 V(15)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(15)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(14)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(14)
Robinin_CE40(14)
cyanidin-3-O-rhamnoside chloride_CE20(14)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(14)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(14)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(14)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(14)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(14)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(14)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(14)
kaempferol 3-O-a-rhamnopyranoside(14)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(14)
cyanidin 3-(glucosyl)rhamnoside(13)
kaempferol-3-O-rutinoside_Ramp5-45 V(12)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(12)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(12)
cyanidin 3-diglucoside(12)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(12)
cyanidin 3-(6''-acetyl)galactoside(12)
cyanidin 3-sambubinoside(12)
cyanidin 3-rutinoside(12)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(12)
Isosakuranetin_CE10(12)
Cyanidin 3-(Glucosyl)Rhamnoside(12)
kaempferol-3-O-glucoside_Ramp5-45 V(12)
Poncirin_CE20(12)
Cyanidin-3-O-Rutinoside(12)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(12)
Keracyanin Chloride_Ramp5-45 V(12)
cyanidin 3-(6''-maronoyl)-laminaribiose(12)
cyanidin 3-galactoside(12)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(12)
cyanidin-3-glucoside p-coumaric(12)
cyanidin 3-glucoside(12)
cyanidin 3-malonylglucoside(12)
cyanidin 3-(6''-coumaroyl)glucoside(12)
cyanidin 3-sophoroside(12)
cyanidin 3-laminaribiose(12)
cyanidin 3-arabinoside(12)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(12)
cyanidin 3-dioxaloylglucoside(12)
cyanidin 7-arabinoside(12)
cyanidin 3-sophoroside(12)
cyanidin 3-xyloside(12)
cyanidin 3-(6''-acetoyl)glucoside(12)
Kaempferol-3-Glucoside_CE20(11)
Ideain chloride_CE30(11)
Kaempferol-3-Rhamnoside_Ramp5-45 V(11)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(11)
Luteolin_CE20(11)
kaempferol-7-O-neohesperidoside_CE30(11)
luteolin-4'-O-glucoside_Ramp5-45 V(11)
cyanidin-3-glucoside chloride_Ramp5-45 V(11)
luteolin-4'-O-glucoside_CE40(11)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(11)
Cyanidin-3-O-Glucoside(11)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(11)
Poncirin_CE30(11)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(11)
Datiscin_CE30(11)
Luteolin_CE10(11)
Luteolin_Ramp5-45 V(11)
Kaempferol-3-Glucoside_Ramp5-45 V(11)
Keracyanin Chloride_CE40(11)
kaempferol-7-O-neohesperidoside_CE40(11)
Maritimein_Ramp5-45 V(11)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(11)
kaempferol-7-O-neohesperidoside_CE40(11)
Kaempferol-3-O-alpha-L-arabinoside_CE20(11)
Datiscin_CE20(11)
luteolin-7-O-glucoside_CE30(11)
Sakuranetin_CE10(11)
Ideain chloride_Ramp5-45 V(11)
Datiscin_Ramp5-45 V(11)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(11)
luteolin-7-O-glucoside_Ramp5-45 V(11)
Kaempferol_CE10(11)
Kaempferol-3-Glucuronide_Ramp5-45 V(11)
kaempferol-3-O-glucoside_CE30(11)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(11)
cyanidin-3-glucoside chloride_CE40(11)
Sakuranetin_CE20(11)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(11)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(11)
Maritimein_CE20(11)
cyanidin-3-O-rhamnoside chloride_CE30(11)
luteolin-4'-O-glucoside_CE30(11)
Kaempferol_CE20(11)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(9)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(9)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(9)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(9)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(9)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(9)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(9)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(9)
kaempferol 3-O-b-glucopyranoside-7-O-a-rhamnopyranoside(9)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(9)
cyanidin-3,5-di-O-glucoside chloride_CE40(9)
kaempferol-3-O-glucoside_CE20(9)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(9)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(9)
Keracyanin Chloride_CE60(8)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(8)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(8)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(8)
Keracyanin Chloride_CE50(8)
Kaempferol-3-Glucuronide_CE20(8)
Kaempferol-3-Glucoside_CE40(8)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(8)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(8)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(8)
kaempferol-7-O-neohesperidoside_CE20(8)
luteolin-7-O-glucoside_CE20(8)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(8)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(8)
Datiscin_CE40(8)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(8)
cyanidin-3,5-di-O-glucoside chloride_CE60(7)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(7)
Poncirin_CE40(7)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(7)
cyanidin-3,5-di-O-glucoside chloride_CE50(7)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(7)
cyanidin-3-glucoside chloride_CE50(7)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(7)
Ideain chloride_CE60(7)
kaempferol-3-O-rutinoside_CE30(7)
Datiscin_CE50(7)
kaempferol-3-O-rutinoside_CE40(7)
Luteolin_CE40(7)
cyanidin 3-glucoside(6)
Cyanidin 3-Glucoside(6)
Kaempferol 3-Glucoside(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(6)
divaricataester C(6)
Cyanidin-3-O-Glucoside(6)
cyanidin 3-glucoside(6)
cyanidin-3-glucoside chloride_CE30(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(6)
Cyanidin 3-Glucoside(6)
Cyanidin 3-Glucoside(6)
cyanidin-3-O-rhamnoside chloride_CE60(6)
cyanidin-3-glucoside(6)
Cyanidin 3-Galactoside(6)
Cyanidin 3-Glucoside(6)
cyanidin-3-glucoside chloride_CE20(5)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(5)
kaempferol-3-O-rutinoside_CE20(5)
kaempferol-7-O-neohesperidoside_CE30(5)
luteolin-4'-O-glucoside_CE50(5)
Isosakuranetin_CE20(5)
cyanidin-3-glucoside chloride_CE60(5)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(5)
Datiscin_CE60(5)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(5)
kaempferol-7-O-neohesperidoside(4)
cyanidin-3-O-rhamnoside chloride_CE40(4)
kaempferol-7-O-neohesperidoside_CE20(4)
kaempferol-7-O-neohesperidoside_CE50(4)
Maritimein_CE40(4)
Kaempferol O-rhamnoside, O-hexosyl-rhamnoside hexoside(4)
luteolin-3',7-di-O-glucoside _CE60(4)
luteolin-7-O-glucoside_CE60(4)
kaempferol-3-O-rutinoside_CE50(4)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(4)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(4)
kaempferol-7-O-neohesperidoside_CE60(4)
Cyanidin 3-Diglucoside(3)
Cyanidin 3-(3''-Malonyl)Glucoside(3)
cyanidin-3-O-rhamnoside chloride_CE50(3)
Cyanidin 3-(6''-Malonyl Glucoside)(3)
luteolin-7-O-glucoside_CE40(3)
Cyanidin 3-Laminaribioside(3)
Cyanidin 3-(3''-Malonyl)Glucoside(3)
Cyanidin 3-O-glucuronide(3)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(3)
Cyanidin 3-(6''-Acetyl) Glucoside(3)
Dehydroevodiamine(3)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(3)
Ideain chloride_CE50(3)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(3)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(3)
cyanidin-3-sophoroside(3)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(3)
Ideain chloride_CE40(3)
Cyanidin 3-(3''-Acetyl)Glucoside(3)
Kaempferol-3-Glucoside_CE30(3)
luteolin-7-O-glucoside_CE50(3)
cyanidin-3-xyloside-glucoside(3)
cyanidin 3-sophoroside(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11026

ATH06p11351

ATH07p10026

ATH08p11764

ATH08p11767

ATH09p10677

ATH10p09331

ATH11p10984

ATH12p10030

ATH12p10278

ATH14p11722

ATH56p13624

ATH56p13627

ATH57p12422

ATH58p14124

ATH58p14537

ATH59p11963

ATH61p15128

ATH63p13128

ATH64p14415

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0142 0.0148 0.0266 0.0146
ATGE_7 0.028 0.0197 0.0308 0.0401 0.0297
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0263 0.0299 0.0214 0.0239 0.0254
ATGE_12 0.0141 0.0287 0.0261 0.0133 0.0205
ATGE_13 0.0202 0.0237 0.0276 0.0586 0.0325
ATGE_14 0.0387 0.0228 0.0142 0.0187 0.0236
ATGE_15 0.0806 0.0408 0.0483 0.0712 0.0602
ATGE_16 0.1548 0.0673 0.0361 0.1561 0.1036
ATGE_19 0.0182 0.017 0.0261 0.0211 0.0206
ATGE_20 0.0234 0.0648 0.0382 0.0425 0.0422
ATGE_21 0.0317 0.0837 0.0887 0.0384 0.0606
ATGE_25 0.0246 0.0441 0.0392 0.0208 0.0322
ATGE_26 0.0807 0.1449 0.1092 0.0727 0.1019
ATGE_27 0.0299 0.0016 0.0363 0.0277 0.0239
ATGE_28 0.0531 0.0341 0.0556 0.0456 0.0471
ATGE_29 0.0024 0.0022 0.0017 0.0016 0.0019
ATGE_32 0.0018 0.0026 0.0015 0.0025 0.0021
ATGE_33 0.0016 0.0018 0.002 0.0021 0.0019
ATGE_39 0.0016 0.002 0.002 0.0017 0.0018
ATGE_41 0.044 0.0559 0.0429 0.0429 0.0464
ATGE_42 0.0018 0.0014 0.0014 0.2971 0.0754
ATGE_45 0.0016 0.0015 0.0619 0.0572 0.0306
ATGE_76 0.0268 0.0085 0.0232 0.002 0.0151
ATGE_77 0.0267 0.0022 0.0182 0.0269 0.0185
ATGE_78 0.0379 0.0824 0.0126 0.0542 0.0468
ATGE_84 0.0154 0.0158 0.0016 0.0015 0.0086
ATGE_91 0.0201 0.029 0.0221 0.0284 0.0249
ATGE_92 0.139 0.1111 0.0017 0.3282 0.145
ATGE_93 0.002 0.0414 0.0021 0.0241 0.0174
ATGE_95 0.0031 0.0019 0.0027 0.018 0.0064
ATGE_96 0.0236 0.0222 0.0188 0.0214 0.0215
ATGE_97 0.0186 0.0267 0.0223 0.0239 0.0229
ATGE_98 0.0015 0.0051 0.0024 0.0176 0.0066
ATGE_99 0.0019 0.0013 0.0019 0.0021 0.0018
ATGE_101 0.0327 0.0154 0.0202 0.0246 0.0233
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch