AtMetExpress Development LC-MS

Perk Nr:adp030267.

Polarity: [POSITIVE]
Retention time: 4.22
m/z: 741
Annotation:
Annotation level: Unknown
compound:
MS2Ts 25 MS2Ts
KNApSAcK C32H41N2O16S1(14):C32H42N2O17S-H2O;
C33H41O19(12):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C35H37N2O16(12):C35H36N2O15+O;
C44H37O11(9):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C37H41O16(6):C37H40O15+O;
C36H37O17(5):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
in-house MS/MS Kaempferol-3-O-alpha-L-rhamnoside_CE10(19)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(19)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(19)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(18)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(18)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(18)
Cyanidin 3-(Glucosyl)Rhamnoside(18)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(18)
Keracyanin Chloride_Ramp5-45 V(18)
Robinin_CE40(18)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(18)
kaempferol-3-O-rutinoside_Ramp5-45 V(17)
Kaempferol-3-Glucoside_CE20(17)
Ideain chloride_CE30(17)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(17)
cyanidin 3-diglucoside(17)
Kaempferol-3-Rhamnoside_Ramp5-45 V(17)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(17)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(17)
Luteolin_CE20(17)
Kaempferol-3-Glucuronide_CE30(17)
kaempferol-7-O-neohesperidoside_CE30(17)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(17)
luteolin-4'-O-glucoside_Ramp5-45 V(17)
cyanidin-3-glucoside chloride_Ramp5-45 V(17)
luteolin-4'-O-glucoside_CE40(17)
cyanidin 3-(6''-acetyl)galactoside(17)
cyanidin 3-sambubinoside(17)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(17)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(17)
Poncirin_CE30(17)
Isosakuranetin_CE10(17)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(17)
Datiscin_CE30(17)
Luteolin_CE10(17)
kaempferol-3-O-glucoside_Ramp5-45 V(17)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(17)
Poncirin_CE20(17)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(17)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(17)
Luteolin_Ramp5-45 V(17)
Kaempferol-3-Glucoside_Ramp5-45 V(17)
Robinin_CE50(17)
Keracyanin Chloride_CE40(17)
kaempferol-7-O-neohesperidoside_CE40(17)
Maritimein_Ramp5-45 V(17)
kaempferol-3-O-glucoside_CE40(17)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(17)
cyanidin 3-(6''-maronoyl)-laminaribiose(17)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(17)
cyanidin 3-galactoside(17)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(17)
kaempferol-7-O-neohesperidoside_CE40(17)
Kaempferol-3-O-alpha-L-arabinoside_CE20(17)
Datiscin_CE20(17)
cyanidin 3-glucoside(17)
cyanidin 3-malonylglucoside(17)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(17)
luteolin-7-O-glucoside_CE30(17)
Sakuranetin_CE10(17)
Ideain chloride_Ramp5-45 V(17)
cyanidin 3-(6''-coumaroyl)glucoside(17)
Datiscin_Ramp5-45 V(17)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(17)
cyanidin 3-sophoroside(17)
luteolin-7-O-glucoside_Ramp5-45 V(17)
Kaempferol_CE10(17)
cyanidin 3-laminaribiose(17)
Kaempferol-3-Glucuronide_Ramp5-45 V(17)
cyanidin 3-arabinoside(17)
kaempferol-7-O-neohesperidoside_CE50(17)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(17)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(17)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(17)
cyanidin-3-glucoside chloride_CE40(17)
Sakuranetin_CE20(17)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(17)
cyanidin 3-dioxaloylglucoside(17)
cyanidin 7-arabinoside(17)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(17)
Maritimein_CE20(17)
cyanidin-3-O-rhamnoside chloride_CE30(17)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(17)
cyanidin 3-sophoroside(17)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(17)
cyanidin 3-xyloside(17)
luteolin-4'-O-glucoside_CE30(17)
cyanidin 3-(6''-acetoyl)glucoside(17)
Kaempferol_CE20(17)
cyanidin-3,5-di-O-glucoside chloride_CE60(16)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(16)
cyanidin-3-O-rhamnoside chloride_CE40(16)
Poncirin_CE40(16)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(16)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(16)
Keracyanin Chloride_CE60(16)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(16)
kaempferol-7-O-neohesperidoside_CE30(16)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(16)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(16)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(16)
Cyanidin-3-O-Glucoside(16)
cyanidin 3-rutinoside(16)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(16)
luteolin-4'-O-glucoside_CE50(16)
cyanidin-3,5-di-O-glucoside chloride_CE50(16)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(16)
Maritimein_CE40(16)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(16)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(16)
cyanidin-3-glucoside chloride_CE30(16)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(16)
Keracyanin Chloride_CE50(16)
Kaempferol-3-Glucuronide_CE20(16)
Kaempferol-3-Glucoside_CE40(16)
Cyanidin-3-O-Rutinoside(16)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(16)
cyanidin-3-glucoside p-coumaric(16)
cyanidin-3-glucoside chloride_CE50(16)
Isosakuranetin_CE20(16)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(16)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(16)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(16)
cyanidin-3-O-rhamnoside chloride_CE60(16)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(16)
cyanidin-3-glucoside chloride_CE60(16)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(16)
Ideain chloride_CE60(16)
luteolin-7-O-glucoside_CE60(16)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(16)
luteolin-3',7-di-O-glucoside _CE50(16)
kaempferol-3-O-glucoside_CE30(16)
cyanidin-3,5-di-O-glucoside chloride_CE40(16)
Datiscin_CE60(16)
kaempferol-3-O-glucoside_CE20(16)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(16)
kaempferol-3-O-rutinoside_CE30(16)
luteolin-7-O-glucoside_CE20(16)
cyanidin 3-(glucosyl)rhamnoside(16)
Datiscin_CE50(16)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(16)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(16)
Datiscin_CE40(16)
kaempferol-3-O-rutinoside_CE40(16)
Luteolin_CE40(16)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(16)
kaempferol-7-O-neohesperidoside_CE50(15)
luteolin-3',7-di-O-glucoside _CE60(15)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(15)
kaempferol-7-O-neohesperidoside_CE60(15)
kaempferol-3-O-rutinoside_CE20(14)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(14)
cyanidin 3-O-galactosyl-rhamnoside(14)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(14)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(14)
Ideain chloride_CE40(14)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(14)
kaempferol-7-O-neohesperidoside_CE20(14)
cyanidin 3-rutinoside(14)
Robinin_CE60(13)
kaempferol-3-O-rutinoside_CE50(13)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(13)
Kaempferol-3-Glucoside_CE30(13)
cyanidin 3-glucoside(12)
Cyanidin 3-Diglucoside(12)
Cyanidin 3-(3''-Malonyl)Glucoside(12)
cyanidin-3-O-rhamnoside chloride_CE50(12)
Cyanidin 3-Glucoside(12)
Cyanidin 3-(6''-Malonyl Glucoside)(12)
Cyanidin 3-Laminaribioside(12)
Kaempferol 3-Glucoside(12)
Cyanidin 3-(3''-Malonyl)Glucoside(12)
Cyanidin 3-O-glucuronide(12)
Cyanidin 3-(6''-Acetyl) Glucoside(12)
Dehydroevodiamine(12)
divaricataester C(12)
Cyanidin-3-O-Glucoside(12)
cyanidin 3-glucoside(12)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(12)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(12)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(12)
cyanidin-3-sophoroside(12)
Cyanidin 3-Glucoside(12)
Cyanidin 3-Glucoside(12)
cyanidin-3-glucoside(12)
Cyanidin 3-Galactoside(12)
Cyanidin 3-(3''-Acetyl)Glucoside(12)
Cyanidin 3-Glucoside(12)
cyanidin-3-xyloside-glucoside(12)
cyanidin 3-sophoroside(12)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(12)
cyanidin-3-glucoside chloride_CE20(11)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(11)
luteolin-7-O-glucoside_CE40(11)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(11)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(11)
kaempferol-7-O-neohesperidoside_CE60(11)
Ideain chloride_CE50(11)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(11)
luteolin-7-O-glucoside_CE50(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(11)
kaempferol-7-O-neohesperidoside(9)
Kaempferol_CE30(9)
kaempferol-7-O-neohesperidoside_CE20(8)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(8)
Keracyanin Chloride_CE30(8)
Maritimein_CE30(8)
luteolin-4'-O-glucoside_CE60(7)
Poncirin_Ramp5-45 V(7)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(7)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(4)
Quercetin 3'/4'-rhamnose(3)
herbacetin-7-O-rha(3)
quercetin-3'/4'-rha(3)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(3)
rhodionin:7-O-? -L-rhamnopyranosylherbacetin(3)
herbacetin-7-O-rha-8-O-glu(3)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(3)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(3)
Quercetin-3-Rhamnoside_CE10(3)
kaempferol 3-O-b-glucopyranoside-7-O-a-rhamnopyranoside(3)
quercetin 3-O-a-rhamnopyranoside(3)
Quercetin 3'/4'-rhamnose(3)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(3)
Kaempferol-3,7-O-di-rhamnopyranoside_CE30(3)
Quercitrin_CE10(3)
Herbacetin 7-O-rhamnose(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11033

ATH06p11036

ATH06p11351

ATH07p10233

ATH08p11473

ATH08p11767

ATH09p10684

ATH10p09513

ATH11p10989

ATH12p10038

ATH13p12929

ATH14p11725

ATH14p12004

ATH56p13132

ATH56p13627

ATH57p12925

ATH58p14130

ATH58p14387

ATH59p11971

ATH61p14922

ATH62p12228

ATH63p13135

ATH63p15471

ATH64p14418

ATH64p14793

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0087 0.0047 0.0019 0.0148 0.0075
ATGE_9 0.0461 0.1264 0.0426 0.002 0.0542
ATGE_10 0.0077 0.0184 0.0126 0.0014 0.01
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0266 0.008
ATGE_14 0.0254 0.0019 0.0015 0.0019 0.0077
ATGE_15 0.0332 0.0211 0.0174 0.034 0.0264
ATGE_16 0.0736 0.028 0.0027 0.0736 0.0445
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0117 0.027 0.0204 0.0181 0.0193
ATGE_21 0.0019 0.0435 0.0439 0.0317 0.0302
ATGE_25 0.0014 0.0018 0.0113 0.0015 0.004
ATGE_26 0.0026 0.0186 0.0194 0.0155 0.014
ATGE_27 0.0015 0.0016 0.0015 0.0071 0.0029
ATGE_28 0.002 0.0018 0.0018 0.0047 0.0026
ATGE_29 0.0402 0.0022 0.0017 0.0016 0.0114
ATGE_32 0.079 0.1301 0.0709 0.061 0.0853
ATGE_33 0.0628 0.0678 0.0639 0.1127 0.0768
ATGE_39 0.0417 0.002 0.047 0.0349 0.0314
ATGE_41 0.0024 0.0155 0.0012 0.0012 0.0051
ATGE_42 0.0018 0.0014 0.0014 0.0019 0.0016
ATGE_45 0.0151 0.0015 0.0185 0.0236 0.0147
ATGE_76 0.0014 0.0017 0.0016 0.002 0.0017
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.002 0.0353 0.0014 0.0628 0.0254
ATGE_84 0.0018 0.0019 0.0016 0.0015 0.0017
ATGE_91 0.0728 0.0571 0.0017 0.0404 0.043
ATGE_92 0.0691 0.0551 0.0588 0.1324 0.0789
ATGE_93 2.8198 2.1773 2.1629 2.1065 2.3166
ATGE_95 2.8792 2.2186 2.2398 1.5293 2.2167
ATGE_96 0.0509 0.0861 0.0701 0.0651 0.0681
ATGE_97 0.0441 0.1239 0.1348 0.0857 0.0971
ATGE_98 1.4615 2.8886 1.6309 1.9348 1.979
ATGE_99 2.5723 3.7363 2.2514 1.9358 2.624
ATGE_101 0.0018 0.0015 0.0202 0.0246 0.012
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch