AtMetExpress Development LC-MS

Perk Nr:adp030269. Kaempferol-Hex-diRha

Polarity: [POSITIVE]
Retention time: 4.36
m/z: 741
Annotation: Kaempferol-Hex-diRha
Annotation level: Characterized
compound:
MS2Ts 35 MS2Ts
KNApSAcK C33H41O19(19):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(19):C32H42N2O17S-H2O;
C35H37N2O16(17):C35H36N2O15+O;
C44H37O11(13):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C37H41O16(8):C37H40O15+O;
C36H37O17(7):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(19)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(19)
cyanidin 3-O-rhamnoside(19)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(19)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(19)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(19)
cyanidin-3-O-rhamnoside chloride_CE20(19)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(19)
Robinin_Ramp5-45 V(19)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(19)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(19)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(19)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(19)
kaempferol 3-O-a-rhamnopyranoside(19)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(19)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(18)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(18)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(18)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(17)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(17)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(17)
Cyanidin 3-(Glucosyl)Rhamnoside(17)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(17)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(17)
Robinin_CE40(17)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(17)
kaempferol-3-O-rutinoside_Ramp5-45 V(16)
Kaempferol-3-Glucoside_CE20(16)
Ideain chloride_CE30(16)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(16)
cyanidin 3-diglucoside(16)
Kaempferol-3-Rhamnoside_Ramp5-45 V(16)
Luteolin_CE20(16)
luteolin-4'-O-glucoside_Ramp5-45 V(16)
cyanidin-3-glucoside chloride_Ramp5-45 V(16)
luteolin-4'-O-glucoside_CE40(16)
cyanidin 3-(6''-acetyl)galactoside(16)
cyanidin 3-sambubinoside(16)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(16)
Poncirin_CE30(16)
Isosakuranetin_CE10(16)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(16)
Luteolin_CE10(16)
kaempferol-3-O-glucoside_Ramp5-45 V(16)
Poncirin_CE20(16)
Luteolin_Ramp5-45 V(16)
Kaempferol-3-Glucoside_Ramp5-45 V(16)
Robinin_CE50(16)
Keracyanin Chloride_CE40(16)
Maritimein_Ramp5-45 V(16)
Keracyanin Chloride_Ramp5-45 V(16)
cyanidin 3-(6''-maronoyl)-laminaribiose(16)
cyanidin 3-galactoside(16)
Kaempferol-3-O-alpha-L-arabinoside_CE20(16)
Datiscin_CE20(16)
cyanidin 3-glucoside(16)
cyanidin 3-malonylglucoside(16)
luteolin-7-O-glucoside_CE30(16)
Sakuranetin_CE10(16)
Ideain chloride_Ramp5-45 V(16)
cyanidin 3-(6''-coumaroyl)glucoside(16)
Datiscin_Ramp5-45 V(16)
cyanidin 3-sophoroside(16)
luteolin-7-O-glucoside_Ramp5-45 V(16)
Kaempferol_CE10(16)
cyanidin 3-laminaribiose(16)
Kaempferol-3-Glucuronide_Ramp5-45 V(16)
cyanidin 3-arabinoside(16)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(16)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(16)
Sakuranetin_CE20(16)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(16)
cyanidin 3-dioxaloylglucoside(16)
cyanidin 7-arabinoside(16)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(16)
Maritimein_CE20(16)
cyanidin 3-sophoroside(16)
cyanidin 3-xyloside(16)
cyanidin 3-(6''-acetoyl)glucoside(16)
Kaempferol_CE20(16)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(15)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(15)
Kaempferol-3-Glucuronide_CE30(15)
kaempferol-7-O-neohesperidoside_CE30(15)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(15)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(15)
Datiscin_CE30(15)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(15)
kaempferol-7-O-neohesperidoside_CE40(15)
kaempferol-3-O-glucoside_CE40(15)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(15)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(15)
kaempferol-7-O-neohesperidoside_CE40(15)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(15)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(15)
kaempferol-7-O-neohesperidoside_CE50(15)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(15)
cyanidin-3-glucoside chloride_CE40(15)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(15)
cyanidin-3-O-rhamnoside chloride_CE30(15)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(15)
cyanidin 3-(glucosyl)rhamnoside(15)
luteolin-4'-O-glucoside_CE30(15)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(14)
Cyanidin-3-O-Glucoside(14)
cyanidin 3-rutinoside(14)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(14)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(14)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(14)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(14)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(14)
Kaempferol-3-Glucoside_CE40(14)
Cyanidin-3-O-Rutinoside(14)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(14)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(14)
cyanidin-3-glucoside p-coumaric(14)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(14)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(14)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(14)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(14)
kaempferol-3-O-glucoside_CE30(14)
Datiscin_CE60(14)
kaempferol-3-O-glucoside_CE20(14)
Datiscin_CE50(14)
Datiscin_CE40(14)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(14)
kaempferol-3-O-rutinoside_CE40(14)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(14)
cyanidin-3,5-di-O-glucoside chloride_CE60(13)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(13)
Poncirin_CE40(13)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(13)
kaempferol-3-O-rutinoside_CE20(13)
Keracyanin Chloride_CE60(13)
kaempferol-7-O-neohesperidoside_CE30(13)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(13)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(13)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(13)
cyanidin-3,5-di-O-glucoside chloride_CE50(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(13)
Maritimein_CE40(13)
Keracyanin Chloride_CE50(13)
Kaempferol-3-Glucuronide_CE20(13)
cyanidin-3-glucoside chloride_CE50(13)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(13)
cyanidin-3-O-rhamnoside chloride_CE60(13)
cyanidin-3-glucoside chloride_CE60(13)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(13)
Ideain chloride_CE60(13)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(13)
luteolin-3',7-di-O-glucoside _CE50(13)
cyanidin-3,5-di-O-glucoside chloride_CE40(13)
kaempferol-7-O-neohesperidoside_CE20(13)
kaempferol-3-O-rutinoside_CE30(13)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(13)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(13)
Luteolin_CE40(13)
cyanidin-3-O-rhamnoside chloride_CE40(12)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(12)
Robinin_CE60(12)
luteolin-4'-O-glucoside_CE50(12)
cyanidin 3-O-galactosyl-rhamnoside(12)
cyanidin-3-glucoside chloride_CE30(12)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(12)
luteolin-3',7-di-O-glucoside _CE60(12)
Isosakuranetin_CE20(12)
luteolin-7-O-glucoside_CE60(12)
kaempferol-3-O-rutinoside_CE50(12)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(12)
Ideain chloride_CE40(12)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(12)
cyanidin 3-rutinoside(12)
luteolin-7-O-glucoside_CE20(12)
kaempferol-7-O-neohesperidoside_CE60(12)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(12)
cyanidin 3-glucoside(11)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(11)
Cyanidin 3-Diglucoside(11)
Cyanidin 3-(3''-Malonyl)Glucoside(11)
cyanidin-3-O-rhamnoside chloride_CE50(11)
Cyanidin 3-Glucoside(11)
kaempferol-7-O-neohesperidoside_CE50(11)
Cyanidin 3-(6''-Malonyl Glucoside)(11)
luteolin-7-O-glucoside_CE40(11)
Cyanidin 3-Laminaribioside(11)
Kaempferol 3-Glucoside(11)
Cyanidin 3-(3''-Malonyl)Glucoside(11)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(11)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(11)
Cyanidin 3-O-glucuronide(11)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(11)
Cyanidin 3-(6''-Acetyl) Glucoside(11)
Dehydroevodiamine(11)
divaricataester C(11)
Cyanidin-3-O-Glucoside(11)
cyanidin 3-glucoside(11)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(11)
Ideain chloride_CE50(11)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(11)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(11)
cyanidin-3-sophoroside(11)
Cyanidin 3-Glucoside(11)
Cyanidin 3-Glucoside(11)
cyanidin-3-glucoside(11)
Cyanidin 3-Galactoside(11)
Cyanidin 3-(3''-Acetyl)Glucoside(11)
Cyanidin 3-Glucoside(11)
Kaempferol-3-Glucoside_CE30(11)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(11)
luteolin-7-O-glucoside_CE50(11)
cyanidin-3-xyloside-glucoside(11)
cyanidin 3-sophoroside(11)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(11)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(9)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(9)
kaempferol-7-O-neohesperidoside(8)
kaempferol-7-O-neohesperidoside_CE20(8)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(8)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(8)
Keracyanin Chloride_CE30(8)
Kaempferol_CE30(8)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(8)
N1-Acetylspermine Trihydrochloride_CE30(7)
delta-Tocotrienol_Ramp5-45 V(7)
Maritimein_CE30(7)
luteolin-4'-O-glucoside_CE60(6)
Poncirin_Ramp5-45 V(6)
Calciferol_Ramp5-45 V(6)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(5)
4-Hydroxybenzoate_Ramp5-45 V(5)
Hinokitiol_Ramp5-45 V(4)
alpha-Tocotrienol_Ramp5-45 V(4)
4-Nitrophenol_Ramp5-45 V(4)
Disodium Glycerophoshate 5.5-Hydrate_Ramp5-45 V(4)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11033

ATH06p11036

ATH07p10038

ATH07p10233

ATH08p11473

ATH08p11476

ATH09p10684

ATH09p10688

ATH10p09513

ATH10p09514

ATH11p10711

ATH11p10989

ATH12p10038

ATH12p10042

ATH13p12929

ATH14p11917

ATH14p12004

ATH56p13132

ATH56p13135

ATH57p12433

ATH57p12925

ATH58p14387

ATH58p14390

ATH59p11971

ATH59p11974

ATH61p14922

ATH61p14926

ATH62p12228

ATH62p12232

ATH63p13135

ATH63p13139

ATH63p15471

ATH63p15965

ATH64p14793

ATH64p14796

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0253 0.0303 0.028 0.0216
ATGE_7 0.0299 0.0244 0.0298 0.0648 0.0373
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0349 0.046 0.0326 0.0262 0.0349
ATGE_12 0.0558 0.0897 0.0833 0.0563 0.0713
ATGE_13 0.054 0.0492 0.0585 0.128 0.0724
ATGE_14 0.056 0.0516 0.0505 0.0523 0.0526
ATGE_15 0.0961 0.0736 0.0606 0.0776 0.077
ATGE_16 0.0972 0.0785 0.0445 0.1114 0.0829
ATGE_19 0.0118 0.0037 0.0145 0.0082 0.0096
ATGE_20 0.0312 0.0702 0.0329 0.0507 0.0462
ATGE_21 0.0799 0.1164 0.12 0.097 0.1033
ATGE_25 0.2164 0.2885 0.314 0.1651 0.246
ATGE_26 0.2688 0.4128 0.1695 0.1684 0.2549
ATGE_27 0.0307 0.0267 0.0427 0.0462 0.0366
ATGE_28 0.0401 0.036 0.0395 0.0495 0.0413
ATGE_29 0.1916 0.2697 0.2133 0.2151 0.2224
ATGE_32 0.1427 0.1687 0.1597 0.1364 0.1519
ATGE_33 0.1578 0.1281 0.1434 0.1729 0.1506
ATGE_39 0.1357 0.1488 0.1175 0.0978 0.1249
ATGE_41 0.1443 0.1126 0.114 0.114 0.1212
ATGE_42 0.1948 0.1023 0.101 0.1495 0.1369
ATGE_45 0.0016 0.0015 0.0805 0.0018 0.0213
ATGE_76 0.0372 0.0162 0.0504 0.0512 0.0388
ATGE_77 0.0577 0.0344 0.0213 0.0451 0.0396
ATGE_78 0.0615 0.0488 0.0208 0.0428 0.0435
ATGE_84 0.0018 0.0019 0.0016 0.0022 0.0019
ATGE_91 0.0385 0.044 0.0292 0.0394 0.0378
ATGE_92 0.1552 0.1102 0.1578 0.1392 0.1406
ATGE_93 0.002 0.0311 0.0338 0.0023 0.0173
ATGE_95 0.0021 0.0019 0.0018 0.0015 0.0018
ATGE_96 0.0236 0.0239 0.0242 0.031 0.0257
ATGE_97 0.0169 0.0331 0.0294 0.0299 0.0273
ATGE_98 0.0015 0.0034 0.0024 0.0015 0.0022
ATGE_99 0.0038 0.0013 0.0019 0.0021 0.0023
ATGE_101 0.0537 0.0317 0.0363 0.0693 0.0477
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch