AtMetExpress Development LC-MS

Perk Nr:adp030270.

Polarity: [POSITIVE]
Retention time: 4.43
m/z: 741
Annotation:
Annotation level: Unknown
compound:
MS2Ts 24 MS2Ts
KNApSAcK C33H41O19(13):Apigenin 7-rutinoside-4'-glucoside, Apigenin 7-neo
C32H41N2O16S1(12):C32H42N2O17S-H2O;
C35H37N2O16(12):C35H36N2O15+O;
C44H37O11(9):Guibourtinidol-(4alpha->2)-3,5,4'-trihydroxystilbe
C36H37O17(6):Apigenin 7-rutinoside-4'-trans-caffeate, Kaempfero
C37H41O16(6):C37H40O15+O;
in-house MS/MS Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(12)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(12)
Cyanidin 3-(Glucosyl)Rhamnoside(12)
cyanidin 3-O-rhamnoside(12)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(12)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(12)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(12)
cyanidin-3-O-rhamnoside chloride_CE20(12)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(12)
Robinin_Ramp5-45 V(12)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(12)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(12)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(12)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE40(12)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(12)
Kaempferol-3-Rhamnoside-4-Rhamnoside,-7-Rhamnoside_Ramp5-45 V(12)
kaempferol 3-O-a-rhamnopyranoside(12)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(12)
Robinin_CE40(11)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE40(11)
cyanidin 3-(glucosyl)rhamnoside(11)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(11)
kaempferol-3-O-rutinoside_Ramp5-45 V(9)
Kaempferol-3-Glucoside_CE20(9)
Ideain chloride_CE30(9)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(9)
cyanidin 3-diglucoside(9)
Kaempferol-3-Rhamnoside_Ramp5-45 V(9)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE30(9)
Luteolin_CE20(9)
luteolin-4'-O-glucoside_Ramp5-45 V(9)
cyanidin-3-glucoside chloride_Ramp5-45 V(9)
luteolin-4'-O-glucoside_CE40(9)
cyanidin 3-(6''-acetyl)galactoside(9)
cyanidin 3-sambubinoside(9)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(9)
Poncirin_CE30(9)
Isosakuranetin_CE10(9)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(9)
Luteolin_CE10(9)
kaempferol-3-O-glucoside_Ramp5-45 V(9)
Poncirin_CE20(9)
Luteolin_Ramp5-45 V(9)
Kaempferol-3-Glucoside_Ramp5-45 V(9)
Robinin_CE50(9)
Keracyanin Chloride_CE40(9)
Maritimein_Ramp5-45 V(9)
Keracyanin Chloride_Ramp5-45 V(9)
cyanidin 3-(6''-maronoyl)-laminaribiose(9)
cyanidin 3-galactoside(9)
Kaempferol-3-O-alpha-L-arabinoside_CE20(9)
Datiscin_CE20(9)
cyanidin 3-glucoside(9)
cyanidin 3-malonylglucoside(9)
luteolin-7-O-glucoside_CE30(9)
Sakuranetin_CE10(9)
Ideain chloride_Ramp5-45 V(9)
cyanidin 3-(6''-coumaroyl)glucoside(9)
Datiscin_Ramp5-45 V(9)
cyanidin 3-sophoroside(9)
luteolin-7-O-glucoside_Ramp5-45 V(9)
Kaempferol_CE10(9)
cyanidin 3-laminaribiose(9)
Kaempferol-3-Glucuronide_Ramp5-45 V(9)
cyanidin 3-arabinoside(9)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(9)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(9)
Sakuranetin_CE20(9)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(9)
cyanidin 3-dioxaloylglucoside(9)
cyanidin 7-arabinoside(9)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(9)
Maritimein_CE20(9)
cyanidin 3-sophoroside(9)
cyanidin 3-xyloside(9)
cyanidin 3-(6''-acetoyl)glucoside(9)
Kaempferol_CE20(9)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(8)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(8)
Kaempferol-3-Glucuronide_CE30(8)
kaempferol-7-O-neohesperidoside_CE30(8)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(8)
Cyanidin-3-O-Glucoside(8)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(8)
Datiscin_CE30(8)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(8)
kaempferol-7-O-neohesperidoside_CE40(8)
kaempferol-3-O-glucoside_CE40(8)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(8)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(8)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(8)
kaempferol-7-O-neohesperidoside_CE40(8)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(8)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(8)
kaempferol-7-O-neohesperidoside_CE50(8)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(8)
cyanidin-3-glucoside chloride_CE40(8)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(8)
cyanidin-3-O-rhamnoside chloride_CE30(8)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(8)
luteolin-4'-O-glucoside_CE30(8)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(7)
N1-Acetylspermine Trihydrochloride_CE30(7)
cyanidin 3-rutinoside(7)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(7)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(7)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(7)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(7)
delta-Tocotrienol_Ramp5-45 V(7)
Kaempferol-3-Glucoside_CE40(7)
Cyanidin-3-O-Rutinoside(7)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(7)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(7)
cyanidin-3-glucoside p-coumaric(7)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(7)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(7)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(7)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(7)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(7)
kaempferol-3-O-glucoside_CE30(7)
Datiscin_CE60(7)
kaempferol-3-O-glucoside_CE20(7)
Datiscin_CE50(7)
Datiscin_CE40(7)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(7)
kaempferol-3-O-rutinoside_CE40(7)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(7)
cyanidin-3,5-di-O-glucoside chloride_CE60(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(6)
Poncirin_CE40(6)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(6)
kaempferol-3-O-rutinoside_CE20(6)
Keracyanin Chloride_CE60(6)
Robinin_CE60(6)
kaempferol-7-O-neohesperidoside_CE30(6)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(6)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(6)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(6)
cyanidin-3,5-di-O-glucoside chloride_CE50(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(6)
Maritimein_CE40(6)
Keracyanin Chloride_CE50(6)
Kaempferol-3-Glucuronide_CE20(6)
luteolin-3',7-di-O-glucoside _CE60(6)
cyanidin-3-glucoside chloride_CE50(6)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(6)
cyanidin-3-O-rhamnoside chloride_CE60(6)
cyanidin-3-glucoside chloride_CE60(6)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(6)
Ideain chloride_CE60(6)
kaempferol-3-O-rutinoside_CE50(6)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(6)
luteolin-3',7-di-O-glucoside _CE50(6)
cyanidin-3,5-di-O-glucoside chloride_CE40(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(6)
kaempferol-7-O-neohesperidoside_CE20(6)
kaempferol-3-O-rutinoside_CE30(6)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(6)
Calciferol_Ramp5-45 V(6)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(6)
kaempferol-7-O-neohesperidoside_CE60(6)
Luteolin_CE40(6)
cyanidin 3-glucoside(5)
cyanidin-3-O-rhamnoside chloride_CE40(5)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(5)
Cyanidin 3-Diglucoside(5)
Cyanidin 3-(3''-Malonyl)Glucoside(5)
cyanidin-3-O-rhamnoside chloride_CE50(5)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(5)
Cyanidin 3-Glucoside(5)
kaempferol-7-O-neohesperidoside_CE50(5)
Cyanidin 3-(6''-Malonyl Glucoside)(5)
luteolin-7-O-glucoside_CE40(5)
Cyanidin 3-Laminaribioside(5)
Kaempferol 3-Glucoside(5)
Cyanidin 3-(3''-Malonyl)Glucoside(5)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(5)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(5)
Cyanidin 3-O-glucuronide(5)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(5)
luteolin-4'-O-glucoside_CE50(5)
Cyanidin 3-(6''-Acetyl) Glucoside(5)
Dehydroevodiamine(5)
cyanidin 3-O-galactosyl-rhamnoside(5)
divaricataester C(5)
Cyanidin-3-O-Glucoside(5)
cyanidin 3-glucoside(5)
cyanidin-3-glucoside chloride_CE30(5)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(5)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(5)
Ideain chloride_CE50(5)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(5)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(5)
cyanidin-3-sophoroside(5)
Isosakuranetin_CE20(5)
Cyanidin 3-Glucoside(5)
Cyanidin 3-Glucoside(5)
cyanidin-3-glucoside(5)
luteolin-7-O-glucoside_CE60(5)
Ideain chloride_CE40(5)
Cyanidin 3-Galactoside(5)
Cyanidin 3-(3''-Acetyl)Glucoside(5)
cyanidin 3-rutinoside(5)
4-Hydroxybenzoate_Ramp5-45 V(5)
luteolin-7-O-glucoside_CE20(5)
Cyanidin 3-Glucoside(5)
Kaempferol-3-Glucoside_CE30(5)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(5)
luteolin-7-O-glucoside_CE50(5)
cyanidin-3-xyloside-glucoside(5)
cyanidin 3-sophoroside(5)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(5)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(5)
cyanidin-3-glucoside chloride_CE20(4)
Kaempferol-3,7-O-di-rhamnopyranoside_CE40(4)
Hinokitiol_Ramp5-45 V(4)
alpha-Tocotrienol_Ramp5-45 V(4)
kaempferol-7-O-neohesperidoside_CE60(4)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(4)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(4)
4-Nitrophenol_Ramp5-45 V(4)
Disodium Glycerophoshate 5.5-Hydrate_Ramp5-45 V(4)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(4)
kaempferol-7-O-neohesperidoside_CE20(3)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(3)
3,5-Dimethoxycinnamic acid (predominantly trans)_Ramp5-45 V(3)
Keracyanin Chloride_CE30(3)
Kaempferol-3,7-O-di-rhamnopyranoside_CE30(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11036

ATH07p10038

ATH08p11473

ATH08p11476

ATH09p10688

ATH10p09514

ATH11p10711

ATH12p10042

ATH14p11917

ATH14p12004

ATH56p13132

ATH56p13135

ATH57p12433

ATH57p12925

ATH58p14387

ATH58p14390

ATH59p11971

ATH59p11974

ATH61p14926

ATH62p12232

ATH63p13139

ATH63p15965

ATH64p14793

ATH64p14796

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0148 0.0013 0.0051
ATGE_7 0.0019 0.0013 0.0019 0.0218 0.0067
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0015 0.0161 0.0207 0.0014 0.0099
ATGE_12 0.0096 0.0017 0.002 0.0014 0.0037
ATGE_13 0.0015 0.0018 0.0022 0.04 0.0113
ATGE_14 0.002 0.0019 0.0157 0.0019 0.0054
ATGE_15 0.0346 0.0014 0.002 0.0212 0.0148
ATGE_16 0.0491 0.028 0.0027 0.0517 0.0329
ATGE_19 0.0018 0.0037 0.0019 0.0064 0.0034
ATGE_20 0.0019 0.0018 0.0177 0.0172 0.0096
ATGE_21 0.0019 0.0402 0.0456 0.0307 0.0296
ATGE_25 0.0417 0.0526 0.0598 0.0015 0.0389
ATGE_26 0.0033 0.0039 0.048 0.0408 0.024
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.011 0.0041
ATGE_29 0.0611 0.0022 0.0733 0.0741 0.0527
ATGE_32 0.08 0.1149 0.0817 0.0861 0.0907
ATGE_33 0.0679 0.0593 0.0629 0.0773 0.0668
ATGE_39 0.0032 0.0968 0.0562 0.041 0.0493
ATGE_41 0.0375 0.0372 0.033 0.033 0.0352
ATGE_42 0.1243 0.0014 0.0014 0.0019 0.0322
ATGE_45 0.0016 0.0314 0.0274 0.0018 0.0156
ATGE_76 0.0014 0.0017 0.0152 0.002 0.0051
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.002 0.0033 0.0014 0.0042 0.0027
ATGE_84 0.0018 0.0019 0.0016 0.0022 0.0019
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0682 0.0017 0.066 0.0793 0.0538
ATGE_93 0.002 0.0238 0.0253 0.0023 0.0134
ATGE_95 0.0021 0.0268 0.0018 0.0015 0.008
ATGE_96 0.0014 0.0017 0.0017 0.0015 0.0016
ATGE_97 0.0016 0.0021 0.002 0.0089 0.0037
ATGE_98 0.0015 0.0034 0.0024 0.0015 0.0022
ATGE_99 0.0352 0.0013 0.0019 0.0021 0.0101
ATGE_101 0.0018 0.0092 0.0106 0.0018 0.0059
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch