AtMetExpress Development LC-MS

Perk Nr:adp031156. Kaempferol-diHex-Rha

Polarity: [POSITIVE]
Retention time: 3.21
m/z: 757
Annotation: Kaempferol-diHex-Rha
Annotation level: Characterized
compound:
MS2Ts 6 MS2Ts
KNApSAcK C33H41O20(5):Luteolin 7-rutinoside-3'-glucoside, Luteolin 7-rut
C40H37O15(4):C40H36O16-O; C39H34O14+CH3O; C34H26O10+C6H10O5; C4
C35H37N2O17(3):C34H34N2O16+CH3O;
C44H37O12(2):Guibourtinidol-(4alpha->2)-3,5,3',4'-tetrahydroxys
C37H41O17(1):C36H38O16+CH3O; ,
in-house MS/MS cyanidin 3-glucoside(4)
kaempferol-7-O-neohesperidoside(4)
cyanidin 3-glucoside(4)
Probable kaempferol triglycosidese of m/z 741 or757(4)
Cyanidin 3-Glucoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-glucoside(4)
Kaempferol 3-Glucoside(4)
cyanidin 3-(3''-malonyl)glucoside(4)
Cyanidin-3-O-Glucoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-rutinoside(4)
divaricataester C(4)
cyanidin 3-galactoside(4)
Cyanidin-3-O-Glucoside(4)
cyanidin 3-glucoside(4)
cyanidin 3,5-diglucoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-glucoside(4)
Kaempferol 3-O-rutinoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-glucoside(4)
Cyanidin 3-Glucoside(4)
Cyanidin 3-Glucoside(4)
cyanidin-3-glucoside(4)
cyanidin 3-glucoside(4)
Probable kaempferol triglycosidese of m/z 741 or757(4)
cyanidin 3-glucoside(4)
Cyanidin 3-Galactoside(4)
cyanidin 3-glucoside(4)
cyanidin 3-glucoside(4)
Cyanidin 3-Glucoside(4)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(4)
cyanidin 3-(caffeoyl)diglucoside-5-glucoside(4)
cyanidin 3-galactoside(4)
cyanidin 3-galactoside(4)
cyanidin 3,5-diglucoside(4)
cyanidin-3-glucoside chloride_CE20(3)
cyanidin-3-rutinoside(3)
kaempferol-3-O-rutinoside_CE20(3)
Cyanidin 3,5-Diglucoside(3)
kaempferol 3-neo hesperidoside(3)
luteolin-4'-O-glucoside_CE20(3)
Cyanidin 3,5-Diglucoside(3)
kaempferol 3-rutinoside(3)
rhamnosyl hexosyl luteolin (3)
luteolin-7-O-glucoside_CE20(3)
Cyanidin-3-O-Rutinoside(3)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(3)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE40(2)
luteolin-4'-O-glucoside_Ramp5-45 V(2)
hexosyl luteolin sulfate (2)
cyanidin-3-glucoside chloride_Ramp5-45 V(2)
Kaempferol O-hexoside, O-hexosyl-rhamnoside(2)
Ideain chloride_CE20(2)
Kaempferol hexose(2)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(2)
Datiscin_CE20(2)
Ideain chloride_Ramp5-45 V(2)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(2)
luteolin-3',7-di-O-glucoside _CE50(2)
cyanidin-3,5-di-O-glucoside chloride_CE30(2)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(2)
Cyanidin 3-(6''-Malonyl Glucoside)(2)
Cyanidin 3-(Caffeoyl)Diglucoside-5-Glucoside(2)
Kaempferol-3-Glucoside_CE10(2)
cyanidin-3,5-di-O-glucoside chloride_CE60(1)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(1)
kaempferol-3-O-rutinoside_Ramp5-45 V(1)
cyanidin-3-O-rhamnoside chloride_CE40(1)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(1)
Kaempferol-3-Glucoside_CE20(1)
Ideain chloride_CE30(1)
Cyanidin 3-Diglucoside(1)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(1)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(1)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(1)
Hinokitiol_Ramp5-45 V(1)
Cyanidin 3-(3''-Malonyl)Glucoside(1)
Solasodine_Ramp5-45 V(1)
cyanidin-3-O-rhamnoside chloride_CE50(1)
cyanidin 3-diglucoside(1)
Poncirin_CE40(1)
Kaempferol-3-Rhamnoside_Ramp5-45 V(1)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(1)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(1)
kaempferol-7-O-neohesperidoside_CE50(1)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(1)
Cyanidin 3-(6''-Malonyl Glucoside)(1)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(1)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(1)
Luteolin_CE20(1)
luteolin-7-O-glucoside_CE40(1)
Kaempferol-3-Glucuronide_CE30(1)
Keracyanin Chloride_CE60(1)
Cyanidin 3-Laminaribioside(1)
kaempferol-7-O-neohesperidoside_CE30(1)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(1)
Cyanidin 3-Diglucoside-5-Glucoside(1)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(1)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(1)
Robinin_CE60(1)
kaempferol-7-O-neohesperidoside_CE30(1)
Cyanidin 3-(3''-Malonyl)Glucoside(1)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(1)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(1)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(1)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(1)
luteolin-4'-O-glucoside_CE40(1)
Cyanidin 3-O-glucuronide(1)
cyanidin 3-(6''-acetyl)galactoside(1)
N1-Acetylspermine Trihydrochloride_CE30(1)
cyanidin 3-sambubinoside(1)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE60(1)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(1)
cyanidin 3-sophoroside-5-glucoside(1)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(1)
cyanidin 3-rutinoside(1)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(1)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(1)
alpha-Tocotrienol_Ramp5-45 V(1)
luteolin-4'-O-glucoside_CE50(1)
rhamnosyl dihexosyl luteolin (1)
cyanidin-3,5-di-O-glucoside chloride_CE50(1)
Cyanidin 3-(6''-Acetyl) Glucoside(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(1)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(1)
Dehydroevodiamine(1)
Poncirin_CE30(1)
Maritimein_CE40(1)
Isosakuranetin_CE10(1)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(1)
cyanidin 3-O-galactosyl-rhamnoside(1)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(1)
Datiscin_CE30(1)
Luteolin_CE10(1)
kaempferol-3-O-glucoside_Ramp5-45 V(1)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(1)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(1)
Poncirin_CE20(1)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(1)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE30(1)
Luteolin_Ramp5-45 V(1)
cyanidin-3-glucoside chloride_CE30(1)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(1)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE60(1)
Kaempferol-3-Glucoside_Ramp5-45 V(1)
kaempferol-7-O-neohesperidoside_CE60(1)
Robinin_CE50(1)
Keracyanin Chloride_CE40(1)
Keracyanin Chloride_CE50(1)
Kaempferol-3-Glucuronide_CE20(1)
cyanidin 3-O-rhamnoside(1)
delta-Tocotrienol_Ramp5-45 V(1)
kaempferol-7-O-neohesperidoside_CE40(1)
cyanidin 3,5-diglucoside(1)
Maritimein_Ramp5-45 V(1)
Kaempferol-3-Glucoside_CE40(1)
Cyanidin-3-O-Rutinoside(1)
Ideain chloride_CE50(1)
cyanidin 3-diglucoside-5-glucoside(1)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(1)
kaempferol-3-O-glucoside_CE40(1)
Keracyanin Chloride_Ramp5-45 V(1)
Cyanidin 3-diglucoide-5-Glucoside(1)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(1)
cyanidin 3-(6''-maronoyl)-laminaribiose(1)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE60(1)
kaempferol-3-O-glucoside_CE10(1)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(1)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(1)
cyanidin 3-galactoside(1)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(1)
luteolin-3',7-di-O-glucoside _CE60(1)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(1)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(1)
cyanidin-3-sophoroside(1)
kaempferol-7-O-neohesperidoside_CE40(1)
cyanidin-3-glucoside p-coumaric(1)
Kaempferol-3-O-alpha-L-arabinoside_CE20(1)
cyanidin-3-glucoside chloride_CE50(1)
cyanidin 3-glucoside(1)
Isosakuranetin_CE20(1)
cyanidin 3-malonylglucoside(1)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(1)
luteolin-7-O-glucoside_CE30(1)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(1)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(1)
cyanidin-3-O-rhamnoside chloride_CE60(1)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(1)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(1)
Sakuranetin_CE10(1)
cyanidin-3-glucoside chloride_CE60(1)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(1)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(1)
Ideain chloride_CE60(1)
cyanidin-3-O-rhamnoside chloride_CE20(1)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(1)
luteolin-7-O-glucoside_CE60(1)
cyanidin 3-(6''-coumaroyl)glucoside(1)
Datiscin_Ramp5-45 V(1)
Cyanidin 3-Sophoroside-5-Glucoside(1)
cyanidin 3-sophoroside(1)
luteolin-7-O-glucoside_Ramp5-45 V(1)
kaempferol-3-O-rutinoside_CE50(1)
Kaempferol_CE10(1)
Kaempferol-3-Glucuronide_Ramp5-45 V(1)
cyanidin 3-laminaribiose(1)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(1)
cyanidin 3-arabinoside(1)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(1)
kaempferol-7-O-neohesperidoside_CE50(1)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(1)
kaempferol-3-O-glucoside_CE30(1)
cyanidin-3,5-di-O-glucoside chloride_CE40(1)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(1)
Datiscin_CE60(1)
Ideain chloride_CE40(1)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(1)
kaempferol-3-O-glucoside_CE20(1)
cyanidin-3-glucoside chloride_CE40(1)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(1)
Sakuranetin_CE20(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(1)
Cyanidin 3-(3''-Acetyl)Glucoside(1)
cyanidin 3-dioxaloylglucoside(1)
Robinin_Ramp5-45 V(1)
cyanidin 7-arabinoside(1)
kaempferol-7-O-neohesperidoside_CE20(1)
4-Nitrophenol_Ramp5-45 V(1)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(1)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(1)
cyanidin 3-rutinoside(1)
Maritimein_CE20(1)
cyanidin-3-O-rhamnoside chloride_CE30(1)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(1)
4-Hydroxybenzoate_Ramp5-45 V(1)
kaempferol-3-O-rutinoside_CE30(1)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(1)
Kaempferol-3-Glucoside_CE30(1)
Datiscin_CE50(1)
luteolin-7-O-glucoside_CE50(1)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(1)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(1)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(1)
Calciferol_Ramp5-45 V(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(1)
Datiscin_CE40(1)
cyanidin 3-sophoroside(1)
kaempferol 3-O-a-rhamnopyranoside(1)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(1)
cyanidin 3-xyloside(1)
cyanidin-3-xyloside-glucoside(1)
luteolin-4'-O-glucoside_CE30(1)
Disodium Glycerophoshate 5.5-Hydrate_Ramp5-45 V(1)
kaempferol-7-O-neohesperidoside_CE60(1)
cyanidin 3-sophoroside(1)
kaempferol-3-O-rutinoside_CE40(1)
cyanidin 3-(6''-acetoyl)glucoside(1)
Kaempferol_CE20(1)
Luteolin_CE40(1)
luteolin-3',7-di-O-glucoside _CE40(1)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(1)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(1)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(1)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11013

ATH08p11451

ATH56p13110

ATH58p14111

ATH62p12207

ATH64p14399

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0019 0.0013 0.0019 0.0014 0.0016
ATGE_9 0.0021 0.002 0.0023 0.0112 0.0044
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0106 0.004
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0091 0.0014 0.002 0.0021 0.0037
ATGE_16 0.0018 0.014 0.0027 0.0157 0.0086
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0072 0.0017 0.0018 0.0031
ATGE_21 0.0019 0.0076 0.0017 0.0019 0.0033
ATGE_25 0.0014 0.0093 0.0013 0.0015 0.0034
ATGE_26 0.0165 0.0186 0.002 0.0016 0.0097
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.004 0.0018 0.0018 0.0015 0.0023
ATGE_29 0.0016 0.0022 0.0017 0.0179 0.0058
ATGE_32 0.0163 0.0179 0.0254 0.0016 0.0153
ATGE_33 0.0415 0.0574 0.0454 0.029 0.0433
ATGE_39 0.0473 0.056 0.0501 0.0436 0.0493
ATGE_41 0.0016 0.0015 0.0012 0.0012 0.0014
ATGE_42 0.1066 0.0659 0.0687 0.0703 0.0779
ATGE_45 0.0016 0.0015 0.0017 0.0018 0.0017
ATGE_76 0.0014 0.0017 0.0016 0.002 0.0017
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.002 0.0033 0.0014 0.0028 0.0024
ATGE_84 0.0018 0.0019 0.0016 0.0015 0.0017
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0332 0.0378 0.0401 0.027 0.0345
ATGE_93 0.0143 0.002 0.0021 0.0101 0.0071
ATGE_95 0.0231 0.0019 0.0226 0.0015 0.0123
ATGE_96 0.0014 0.0017 0.0017 0.0015 0.0016
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0015 0.0034 0.027 0.0153 0.0118
ATGE_99 0.0276 0.0013 0.0219 0.0384 0.0223
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch