AtMetExpress Development LC-MS

Perk Nr:adp031160. "Quercetin-3-O-a-L-rhamnopyranosyl(1,2)-b-D-glucopyranoside-7-O-a-L-rhamnopyranoside_1"

Polarity: [POSITIVE]
Retention time: 3.56
m/z: 757
Annotation: "Quercetin-3-O-a-L-rhamnopyranosyl(1,2)-b-D-glucopyranoside-7-O-a-L-rhamnopyranoside_1"
Annotation level: Identified
compound: Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside
MS2Ts 23 MS2Ts
KNApSAcK C33H41O20(12):Luteolin 7-rutinoside-3'-glucoside, Luteolin 7-rut
C37H41O17(7):C36H38O16+CH3O;
C44H37O12(7):Guibourtinidol-(4alpha->2)-3,5,3',4'-tetrahydroxys
C36H37O18(5):Kaempferol 3-(6''-p-coumarylglucoside)-7-glucoside
in-house MS/MS Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(15)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(14)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(14)
herbacetin-7-O-rha(13)
quercetin-3'/4'-rha(13)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(13)
Quercetin-3-Rhamnoside_CE10(13)
Quercetin-7-O-rhamnoside_Ramp5-45 V(13)
quercetin 3-O-a-rhamnopyranoside(13)
Quercitrin_CE10(13)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(13)
Quercetin 3'/4'-rhamnose(12)
rhodionin:7-O-? -L-rhamnopyranosylherbacetin(12)
herbacetin-7-O-rha-8-O-glu(12)
Quercetin 3'/4'-rhamnose(12)
Herbacetin 7-O-rhamnose(12)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(11)
Herbacetin 7-O-rhamnose-8-O-glucose(9)
Hyperoside_Ramp5-45 V(9)
delphinidin 3-malonylglucoside(9)
delphinidin 3-arabinoside(9)
delphinidin 3-galactoside(9)
delphinidin 3-glucoside(9)
Peltatoside_Ramp5-45 V(9)
rhodionidin:7-O-rhamnosyl-8-O-glucosylherbacetin(9)
delphinidin 3-(6''-coumaroyl)glucoside(9)
delphinidin 3-(6''-acetyl)glucoside(9)
Quercetin-3-Glucuronide_Ramp5-45 V(9)
Quercetin-3-Rhamnoside_Ramp5-45 V(8)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(8)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(8)
Quercetin-3-Arabinoside_Ramp5-45 V(8)
Quercetin-3-O-beta-D-galactoside_CE20(8)
Quercetin_CE10(8)
Quercetin-3-D-xyloside_Ramp5-45 V(8)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(7)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(7)
Quercetin-3-D-xyloside_CE20(7)
Quercetin_CE20(7)
Hesperetin_CE20(7)
Quercetin-3-O-glucose-6''-acetate_CE20(7)
Hesperetin_CE10(7)
Spiraeoside_Ramp5-45 V(7)
PIPES_CE10(7)
Quercetin_Ramp5-45 V(7)
Quercetin-3-Arabinoside_CE20(6)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(6)
Delphinidin-3-O-beta-glucopyranoside_CE50(6)
Quercetin-3-O-beta-D-galactoside_CE30(6)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(6)
Hyperoside_CE20(6)
delphinidin 3-glucoside p-coumaric(6)
Hesperidin_Ramp5-45 V(5)
Spiraeoside_CE30(5)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(5)
PIPES_CE20(5)
Peltatoside_CE30(5)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(5)
Hyperoside_CE40(5)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(5)
Quercetin-3-Glucuronide_CE30(5)
quercetin-3-O-beta-glucopyranoside_CE30(5)
quercetin-3-O-beta-glucopyranoside_CE40(5)
Rutin _CE30(5)
quercetin-3-O-beta-glucopyranoside_CE20(4)
Rutin _CE40(4)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(4)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(4)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(4)
Peltatoside_CE20(4)
(NC-OMe)-Hex ? isomer #1(4)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(4)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(4)
Quercetin-3-O-glucose-6''-acetate_CE50(3)
Quercetin-3-O-glucose-6''-acetate_CE30(3)
Peltatoside_CE40(3)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(3)
Delphinidin-3-O-beta-glucopyranoside_CE60(3)
Rutin _CE50(3)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(3)
Quercetin-3-Glucuronide_CE20(3)
Quercetin-3-O-beta-D-galactoside_CE50(3)
Spiraeoside_CE60(3)
Spiraeoside_CE50(3)
Delphinidin-3-O-beta-glucopyranoside_CE40(3)
PIPES_CE30(3)
Quercetin-3-D-xyloside_CE40(3)
Quercetin-3-D-xyloside_CE30(3)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(3)
Delphinidin-3-O-beta-glucopyranoside_CE30(3)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11020

ATH07p10019

ATH07p10256

ATH08p11456

ATH08p11689

ATH09p10669

ATH10p09323

ATH11p10693

ATH12p10023

ATH13p12916

ATH14p11714

ATH56p13117

ATH57p12414

ATH58p14116

ATH58p14119

ATH59p12198

ATH61p15119

ATH62p12695

ATH63p13120

ATH63p13380

ATH63p15457

ATH64p14406

ATH64p14640

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0444 0.0641 0.0693 0.0889 0.0667
ATGE_7 0.2814 0.3034 0.3383 0.3448 0.3169
ATGE_9 0.0559 0.1551 0.0967 0.0367 0.0861
ATGE_10 0.1055 0.1158 0.0926 0.1056 0.1049
ATGE_12 0.0387 0.0401 0.0311 0.0296 0.0349
ATGE_13 0.0616 0.0747 0.0541 0.2462 0.1091
ATGE_14 0.1274 0.1012 0.0836 0.0741 0.0966
ATGE_15 0.5198 0.2078 0.1397 0.1606 0.257
ATGE_16 0.322 0.2142 0.1849 0.2815 0.2506
ATGE_19 0.1103 0.1041 0.1761 0.1757 0.1415
ATGE_20 0.1435 0.2126 0.1903 0.2454 0.198
ATGE_21 0.1358 0.2328 0.215 0.1479 0.1829
ATGE_25 0.035 0.0413 0.0465 0.0401 0.0407
ATGE_26 0.1145 0.0941 0.146 0.0809 0.1089
ATGE_27 0.1727 0.0534 0.1558 0.2168 0.1497
ATGE_28 0.2337 0.1081 0.2808 0.3398 0.2406
ATGE_29 2.9178 1.6182 3.5631 2.3333 2.6081
ATGE_32 7.6036 7.675 3.7052 3.6476 5.6579
ATGE_33 6.2529 7.2318 6.1857 5.6949 6.3413
ATGE_39 2.6899 2.8848 5.1993 4.3921 3.7915
ATGE_41 1.535 1.6184 1.5707 1.5707 1.5737
ATGE_42 2.0343 2.0021 2.2457 1.8924 2.0436
ATGE_45 4.4093 2.0161 1.4371 3.1227 2.7463
ATGE_76 0.9455 0.1813 0.8525 0.9466 0.7315
ATGE_77 1.0473 0.6481 0.7728 0.9038 0.843
ATGE_78 0.9394 0.0993 0.0387 0.1228 0.3001
ATGE_84 0.3666 0.3316 0.4196 0.44 0.3895
ATGE_91 0.1005 0.0721 0.031 0.0569 0.0651
ATGE_92 3.5819 2.0387 2.1382 2.6995 2.6146
ATGE_93 1.088 1.0062 0.8783 0.8087 0.9453
ATGE_95 1.1165 0.9175 1.0235 0.6288 0.9216
ATGE_96 0.0832 0.0994 0.0935 0.093 0.0923
ATGE_97 0.0755 0.1356 0.1419 0.1445 0.1244
ATGE_98 0.9749 3.7414 1.0057 0.9263 1.6621
ATGE_99 1.8923 2.002 1.976 1.485 1.8388
ATGE_101 0.0564 0.024 0.0555 0.0675 0.0508
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch