AtMetExpress Development LC-MS

Perk Nr:adp031166. Kaempferol-diHex-Rha

Polarity: [POSITIVE]
Retention time: 4.08
m/z: 757
Annotation: Kaempferol-diHex-Rha
Annotation level: Characterized
compound:
MS2Ts 26 MS2Ts
KNApSAcK C33H41O20(11):Luteolin 7-rutinoside-3'-glucoside, Luteolin 7-rut
C44H37O12(9):Guibourtinidol-(4alpha->2)-3,5,3',4'-tetrahydroxys
C37H41O17(8):C36H38O16+CH3O;
C36H37O18(4):Kaempferol 3-(6''-p-coumarylglucoside)-7-glucoside
C33H45N2O16S1(4):C33H44N2O17S-O;
C31H37N2O20(3):C30H34N2O19+CH3O;
in-house MS/MS cyanidin 3-glucoside(9)
cyanidin-3-glucoside chloride_CE20(9)
Cyanidin 3-Diglucoside(9)
Cyanidin 3-(3''-Malonyl)Glucoside(9)
Cyanidin 3-Glucoside(9)
Cyanidin 3-(6''-Malonyl Glucoside)(9)
kaempferol-3-O-rutinoside_CE20(9)
Cyanidin 3-Laminaribioside(9)
Kaempferol 3-Glucoside(9)
Cyanidin 3-(3''-Malonyl)Glucoside(9)
Cyanidin 3-O-glucuronide(9)
Cyanidin 3-(6''-Acetyl) Glucoside(9)
Dehydroevodiamine(9)
Quercetin-3-O-alpha-L-rhamnopyranoside_Ramp5-45 V(9)
divaricataester C(9)
Cyanidin-3-O-Glucoside(9)
cyanidin 3-glucoside(9)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(9)
Robinin_CE40(9)
cyanidin-3-sophoroside(9)
Cyanidin 3-Glucoside(9)
Cyanidin 3-Glucoside(9)
cyanidin-3-glucoside(9)
Cyanidin 3-Galactoside(9)
Cyanidin 3-(3''-Acetyl)Glucoside(9)
Kaempferol-3-O-alpha-L-rhamnoside_CE10(9)
Cyanidin 3-Glucoside(9)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(9)
luteolin-7-O-glucoside_CE50(9)
cyanidin-3-xyloside-glucoside(9)
cyanidin 3-sophoroside(9)
kaempferol-7-O-neohesperidoside(8)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(8)
Robinin_CE60(8)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(8)
cyanidin 3-O-galactosyl-rhamnoside(8)
cyanidin 3-rutinoside(8)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE50(8)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE50(8)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(7)
Spiraeoside_CE30(7)
Cyanidin-3-O-alpha-arabinopyranoside_CE50(7)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(7)
Hyperoside_Ramp5-45 V(7)
delphinidin 3-malonylglucoside(7)
Quercetin-3-Arabinoside_CE20(7)
Quercitrin_Ramp5-45 V(7)
delphinidin 3-arabinoside(7)
delphinidin 3-galactoside(7)
Rutin _CE40(7)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(7)
delphinidin 3-glucoside(7)
Peltatoside_Ramp5-45 V(7)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(7)
Quercetin-3-D-xyloside_CE20(7)
PIPES_CE20(7)
Quercetin-3-Rhamnoside_Ramp5-45 V(7)
Quercetin_CE20(7)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(7)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(7)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(7)
Quercetin-3-Arabinoside_Ramp5-45 V(7)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(7)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(7)
Peltatoside_CE20(7)
Quercetin-3-O-beta-D-galactoside_CE20(7)
Peltatoside_CE30(7)
Delphinidin-3-O-beta-glucopyranoside_CE50(7)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(7)
delphinidin 3-(6''-coumaroyl)glucoside(7)
Quercetin-3-O-beta-D-galactoside_CE30(7)
Quercetin-7-O-rhamnoside_Ramp5-45 V(7)
Quercetin_CE10(7)
Hesperetin_CE20(7)
Quercetin-3-O-glucose-6''-acetate_CE20(7)
Quercetin-3-O-beta-D-galactoside_CE50(7)
Hesperetin_CE10(7)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(7)
quercetin 3-O-a-rhamnopyranoside(7)
Hyperoside_CE40(7)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(7)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(7)
Quercetin-3-D-xyloside_Ramp5-45 V(7)
Quercetin-3-Glucuronide_CE30(7)
Hyperoside_CE20(7)
delphinidin 3-(6''-acetyl)glucoside(7)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(7)
delphinidin 3-glucoside p-coumaric(7)
Spiraeoside_Ramp5-45 V(7)
quercetin-3-O-beta-glucopyranoside_CE30(7)
quercetin-3-O-beta-glucopyranoside_CE40(7)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(7)
PIPES_CE10(7)
Rutin _CE30(7)
Quercetin-3-Glucuronide_Ramp5-45 V(7)
Quercetin_Ramp5-45 V(7)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(7)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(7)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(7)
quercetin-3-O-beta-glucopyranoside_CE20(6)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(6)
Kaempferol-3-Rhamnoside-7-Rhamnoside_CE40(6)
Cyanidin-3-O-alpha-arabinopyranoside_CE60(6)
Quercetin-3-Rhamnoside_CE10(6)
kaempferol-7-O-neohesperidoside_CE60(6)
Rutin _CE50(6)
Quercetin-3-Glucuronide_CE20(6)
(NC-OMe)-Hex ? isomer #1(6)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE60(6)
Spiraeoside_CE50(6)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE50(6)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(6)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE40(6)
Kaempferol_CE30(6)
cyanidin 3-(glucosyl)rhamnoside(6)
Peltatoside_CE40(5)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE60(5)
Maritimein_CE30(5)
Quercetin-3-D-xyloside_CE30(5)
Delphinidin-3-O-beta-glucopyranoside_CE30(5)
Kaempferol-3-O-alpha-L-rhamnoside_CE30(5)
Peltatoside_CE50(4)
Hesperidin_Ramp5-45 V(4)
delphinidin 3-O-Glucoside(4)
Quercetin-3-O-glucose-6''-acetate_CE50(4)
Ellagic Acid(4)
Quercetin-3-O-glucose-6''-acetate_CE30(4)
Delphinidin 3-Galactoside(4)
Quercetin-3-Glucuronide_CE40(4)
dihexosyl quercetin (4)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(4)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE60(4)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(4)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(4)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(4)
Quercetin-3-O-beta-D-galactoside_CE40(4)
Delphinidin 3-Glucoside(4)
Quercetin-3-Arabinoside_CE30(4)
delphinidin 3-glucoside(4)
Delphinidin-3-O-beta-glucopyranoside_CE60(4)
Quercetin-3-Arabinoside_CE40(4)
Spiraeoside_CE60(4)
Quercitrin_CE20(4)
delphinidin 3-O-Glucoside(4)
delphinidin 3-glucoside(4)
Delphinidin-3-O-beta-glucopyranoside_CE40(4)
PIPES_CE30(4)
Quercetin-3-D-xyloside_CE40(4)
delphinidin 3-xyloside-glucoside(4)
Delphinidin 3-Glucoside(4)
quercetin 3-glucoside(4)
delphinidin 3-O-Glucoside(4)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(4)
Spiraeoside_CE40(4)
herbacetin-7-O-rha(3)
quercetin-3'/4'-rha(3)
luteolin-4'-O-glucoside_CE60(3)
Poncirin_Ramp5-45 V(3)
Quercetin-3-Rhamnoside_CE20(3)
Peltatoside_CE60(3)
Quercitrin_CE10(3)
Quercetin-3-O-glucose-6''-acetate_CE40(3)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11029

ATH06p11264

ATH07p10029

ATH08p11467

ATH09p10679

ATH10p09332

ATH11p10925

ATH12p10033

ATH13p12925

ATH13p13325

ATH14p11723

ATH14p11726

ATH56p13126

ATH56p13629

ATH57p12425

ATH57p12923

ATH58p14127

ATH59p11966

ATH59p11967

ATH61p14655

ATH62p12223

ATH63p13130

ATH63p13131

ATH63p15467

ATH64p14416

ATH64p14419

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0592 0.087 0.106 0.0924 0.0861
ATGE_7 0.0851 0.0857 0.0825 0.1819 0.1088
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0488 0.036 0.0459 0.0352 0.0415
ATGE_12 0.035 0.0409 0.0512 0.0378 0.0412
ATGE_13 0.0353 0.0382 0.0232 0.0675 0.041
ATGE_14 0.0244 0.0317 0.0244 0.0365 0.0293
ATGE_15 0.0594 0.0401 0.0318 0.0382 0.0424
ATGE_16 0.05 0.0355 0.0278 0.0403 0.0384
ATGE_19 0.0018 0.0037 0.0087 0.0073 0.0054
ATGE_20 0.0244 0.0423 0.0231 0.0353 0.0313
ATGE_21 0.0327 0.0544 0.0546 0.0461 0.0469
ATGE_25 0.0694 0.0798 0.0858 0.0648 0.0749
ATGE_26 0.0715 0.1071 0.0663 0.0776 0.0806
ATGE_27 0.0165 0.0105 0.0015 0.0246 0.0133
ATGE_28 0.013 0.0083 0.0197 0.022 0.0157
ATGE_29 0.066 0.0865 0.1006 0.1002 0.0883
ATGE_32 0.189 0.2136 0.189 0.2033 0.1987
ATGE_33 0.1714 0.1856 0.1878 0.1793 0.181
ATGE_39 0.1638 0.1702 0.1441 0.1205 0.1496
ATGE_41 0.1476 0.146 0.137 0.137 0.1419
ATGE_42 0.0918 0.0603 0.0601 0.0664 0.0696
ATGE_45 0.0947 0.0837 0.0681 0.0745 0.0803
ATGE_76 0.026 0.0076 0.028 0.0366 0.0246
ATGE_77 0.0344 0.0221 0.003 0.0259 0.0214
ATGE_78 0.0317 0.0824 0.023 0.0585 0.0489
ATGE_84 0.1874 0.1683 0.2154 0.2109 0.1955
ATGE_91 0.0385 0.0501 0.0434 0.0523 0.046
ATGE_92 0.1049 0.1145 0.1355 0.1257 0.1202
ATGE_93 0.2487 0.2209 0.164 0.1905 0.206
ATGE_95 0.2048 0.1869 0.1746 0.1307 0.1743
ATGE_96 0.2037 0.2211 0.214 0.1629 0.2004
ATGE_97 0.0509 0.0747 0.0791 0.0677 0.0681
ATGE_98 0.1394 0.4315 0.1546 0.1556 0.2203
ATGE_99 0.2142 0.2906 0.1946 0.1463 0.2114
ATGE_101 0.0418 0.0278 0.0181 0.0437 0.0329
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch