AtMetExpress Development LC-MS

Perk Nr:adp032039. Kaempferol-triHex

Polarity: [POSITIVE]
Retention time: 3.05
m/z: 773
Annotation: Kaempferol-triHex
Annotation level: Characterized
compound:
MS2Ts 15 MS2Ts
KNApSAcK C40H37O16(7):Madhusalmone; C40H36O16;
C33H41O21(7):Luteolin 7-gentiobioside-4'-glucoside, Kaempferol
C44H37O13(5):C44H36O12+O;
C37H41O18(2):C31H30O13+C6H10O5;
in-house MS/MS cyanidin 3-glucoside(5)
cyanidin-3-glucoside chloride_CE20(5)
kaempferol-7-O-neohesperidoside(5)
cyanidin 3-glucoside(5)
Probable kaempferol triglycosidese of m/z 741 or757(5)
Cyanidin 3-Glucoside(5)
cyanidin 3-glucoside(5)
kaempferol-3-O-rutinoside_CE20(5)
cyanidin 3-glucoside(5)
Kaempferol 3-Glucoside(5)
cyanidin 3-(3''-malonyl)glucoside(5)
Cyanidin-3-O-Glucoside(5)
cyanidin 3-glucoside(5)
cyanidin 3-rutinoside(5)
divaricataester C(5)
cyanidin 3-galactoside(5)
Cyanidin-3-O-Glucoside(5)
cyanidin 3-glucoside(5)
cyanidin 3,5-diglucoside(5)
cyanidin 3-glucoside(5)
cyanidin 3-glucoside(5)
cyanidin 3-glucoside(5)
Kaempferol 3-O-rutinoside(5)
cyanidin 3-glucoside(5)
cyanidin 3-glucoside(5)
Cyanidin 3-Glucoside(5)
luteolin-4'-O-glucoside_CE20(5)
Cyanidin 3-Glucoside(5)
cyanidin-3-glucoside(5)
cyanidin 3-glucoside(5)
Probable kaempferol triglycosidese of m/z 741 or757(5)
cyanidin 3-glucoside(5)
Cyanidin 3-Galactoside(5)
cyanidin 3-glucoside(5)
cyanidin 3-glucoside(5)
luteolin-7-O-glucoside_CE20(5)
Cyanidin 3-Glucoside(5)
luteolin-3',7-di-O-glucoside_Ramp5-45 V(5)
cyanidin 3-(caffeoyl)diglucoside-5-glucoside(5)
cyanidin 3-galactoside(5)
cyanidin 3-galactoside(5)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE20(5)
cyanidin 3,5-diglucoside(5)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE40(4)
Ellagic acid hexose(4)
delphinidin 3-O-Glucoside(4)
Hinokitiol_Ramp5-45 V(4)
cyanidin-3-rutinoside(4)
Delphinidin 3-Galactoside(4)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(4)
luteolin-4'-O-glucoside_Ramp5-45 V(4)
hexosyl luteolin sulfate (4)
cyanidin-3-glucoside chloride_Ramp5-45 V(4)
N1-Acetylspermine Trihydrochloride_CE30(4)
delphinidin 3-glucoside-5-rhamnoside(4)
Cyanidin 3,5-Diglucoside(4)
Kaempferol O-hexoside, O-hexosyl-rhamnoside(4)
Ideain chloride_CE20(4)
Delphinidin 3-Glucoside(4)
Kaempferol hexose(4)
delphinidin 3-glucoside(4)
quercetin 3-rutinoside(4)
delta-Tocotrienol_Ramp5-45 V(4)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE20(4)
quercetin 3-neo hesperidoside(4)
kaempferol-3-O-glucoside_CE10(4)
kaempferol 3-neo hesperidoside(4)
delphinidin 3-O-Rutinoside(4)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(4)
Datiscin_CE20(4)
Ideain chloride_Ramp5-45 V(4)
cyanidin-3,5-di-O-glucoside chloride_Ramp5-45 V(4)
delphinidin 3-O-Glucoside(4)
rhamnosyl hexosyl quercetin (4)
Delphinidin 3-Rutinoside(4)
luteolin-3',7-di-O-glucoside _CE50(4)
delphinidin 3-glucoside(4)
Cyanidin 3,5-Diglucoside(4)
Delphinidin 3-Glucoside(4)
kaempferol 3-rutinoside(4)
cyanidin-3,5-di-O-glucoside chloride_CE30(4)
quercetin 3-glucoside(4)
delphinidin 3-O-Rutinoside(4)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_30V(4)
delphinidin 3-O-Glucoside(4)
rhamnosyl hexosyl luteolin (4)
4-Hydroxybenzoate_Ramp5-45 V(4)
Cyanidin 3-(6''-Malonyl Glucoside)(4)
Cyanidin-3-O-Rutinoside(4)
Cyanidin 3-(Caffeoyl)Diglucoside-5-Glucoside(4)
Calciferol_Ramp5-45 V(4)
Kaempferol-3-Glucoside_CE10(4)
luteolin-3',7-di-O-glucoside _CE40(4)
delphinidin 3-glucoside(3)
kaempferol-3-O-rutinoside_Ramp5-45 V(3)
Kaempferol-3-Glucoside-3-Rhamnoside_Ramp5-45 V(3)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE30(3)
Delphinidin 3,5-Diglucoside(3)
Delphinidin-3-O-beta-glucopyranoside_CE20(3)
cyanidin 3-sophoroside-5-glucoside(3)
similar to peak 7(3)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE20(3)
alpha-Tocotrienol_Ramp5-45 V(3)
cyanidin 3-O-galactosyl-rhamnoside(3)
delphinidin 3,5-diglucoside(3)
kaempferol-3-O-glucoside_Ramp5-45 V(3)
(NC-OMe)-Hex ? isomer #2(3)
Poncirin_CE20(3)
cyanidin 3,5-diglucoside(3)
cyanidin 3-diglucoside-5-glucoside(3)
delphinidin 3-glucoside(3)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE50(3)
delphinidin 3-rutinoside(3)
(NC-OMe)-Hex ? isomer #1(3)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_Ramp5-45 V(3)
Datiscin_Ramp5-45 V(3)
luteolin-7-O-glucoside_Ramp5-45 V(3)
Quercetin hexose(3)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE40(3)
cyanidin-3,5-di-O-glucoside chloride_CE40(3)
Kaempferol-3-Galactoside-6-Rhamnoside-3-Rhamnoside_Ramp5-45 V(3)
Rutin _CE20(3)
Q-Hex (T4). (3)
delphinidin 3-galactoside(3)
cyanidin 3-rutinoside(3)
delphinidin 3-glucoside-5-acetylrhamnoside(3)
delphinidin 3-glucoside(3)
rutin(3)
delphinidin 3-glucoside(3)
cyanidin-3,5-di-O-glucoside chloride_CE60(2)
Kaempferol-7-O-alpha-L-rhamnoside_CE40(2)
delphinidin 3-rutinoside-5-glucoside(2)
cyanidin-3-O-rhamnoside chloride_CE40(2)
Kaempferol-3-Glucoside_CE20(2)
delphinidin 3-rutinoside(2)
Ideain chloride_CE30(2)
Cyanidin 3-Diglucoside(2)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(2)
Hyperoside_Ramp5-45 V(2)
Kaempferol-7-O-alpha-L-rhamnoside_Ramp5-45 V(2)
Cyanidin 3-(3''-Malonyl)Glucoside(2)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(2)
cyanidin 3-diglucoside(2)
Poncirin_CE40(2)
Kaempferol-3-Rhamnoside_Ramp5-45 V(2)
Kaempferol-7-O-alpha-L-rhamnoside_CE30(2)
Kaempferol-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(2)
kaempferol-7-O-neohesperidoside_CE50(2)
Cyanidin 3-(6''-Malonyl Glucoside)(2)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(2)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE50(2)
Luteolin_CE20(2)
Kaempferol-3-Glucuronide_CE30(2)
Keracyanin Chloride_CE60(2)
Cyanidin 3-Laminaribioside(2)
kaempferol-7-O-neohesperidoside_CE30(2)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE40(2)
Cyanidin 3-Diglucoside-5-Glucoside(2)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE60(2)
Cyanidin-3-O-[6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside]-5-O-beta-glucopyranoside_Ramp5-45 V(2)
kaempferol-7-O-neohesperidoside_CE30(2)
Cyanidin 3-(3''-Malonyl)Glucoside(2)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE30(2)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(2)
Cyanidin-3-O-alpha-arabinopyranoside_CE40(2)
Peltatoside_Ramp5-45 V(2)
luteolin-4'-O-glucoside_CE40(2)
Cyanidin 3-O-glucuronide(2)
cyanidin 3-(6''-acetyl)galactoside(2)
cyanidin 3-sambubinoside(2)
Kaempferol-3-O-alpha-L-arabinoside_Ramp5-45 V(2)
Cyanidin-3-O-(6''-O-(E-p-coum)-2''-O-(beta-xylopyranosyl)-beta-glucopyranoside)-5-O-beta-glucopyranoside trifluoroacetate salt_CE60(2)
cyanidin 3-rutinoside(2)
Quercetin-3-O-beta-D-galactoside_CE10(2)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE50(2)
luteolin-4'-O-glucoside_CE50(2)
rhamnosyl dihexosyl luteolin (2)
cyanidin-3,5-di-O-glucoside chloride_CE50(2)
Cyanidin 3-(6''-Acetyl) Glucoside(2)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(2)
cyanidin-3-O-rhamnoside chloride_Ramp5-45 V(2)
Dehydroevodiamine(2)
Poncirin_CE30(2)
Spiraeoside_CE20(2)
Maritimein_CE40(2)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE30(2)
Isosakuranetin_CE10(2)
Cyanidin-3-O-alpha-arabinopyranoside_Ramp5-45 V(2)
Kaempferol-3-Glucoside-3''-Rhamnoside_CE40(2)
trans-2-Hexenal_Ramp5-45 V(2)
Datiscin_CE30(2)
Luteolin_CE10(2)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(2)
Kaempferol-3-O-beta-D-glucoside-7-O-alpha-L-rhamnoside_CE40(2)
quercetin-3-O-beta-glucopyranoside_CE10(2)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE60(2)
Luteolin_Ramp5-45 V(2)
cyanidin-3-glucoside chloride_CE30(2)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE30(2)
Kaempferol-3-Glucoside_Ramp5-45 V(2)
Robinin_CE50(2)
Keracyanin Chloride_CE40(2)
Keracyanin Chloride_CE50(2)
Kaempferol-3-Glucuronide_CE20(2)
delphinidin 3-rutinoside(2)
cyanidin 3-O-rhamnoside(2)
kaempferol-7-O-neohesperidoside_CE40(2)
Maritimein_Ramp5-45 V(2)
Kaempferol-3-Glucoside_CE40(2)
Cyanidin-3-O-Rutinoside(2)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(2)
Quercetin-3-O-beta-D-galactoside_CE20(2)
kaempferol-7-O-neohesperidoside_Ramp5-45 V(2)
Cyanidin 3-diglucoide-5-Glucoside(2)
kaempferol-3-O-glucoside_CE40(2)
Keracyanin Chloride_Ramp5-45 V(2)
Kaempferol-7-O-alpha-L-rhamnoside_CE50(2)
cyanidin 3-(6''-maronoyl)-laminaribiose(2)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_Ramp5-45 V(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE50(2)
Cyanidin 3-(6''-Malonyl-Laminaribioside)(2)
cyanidin 3-galactoside(2)
Cyanidin 3-O-(6-O-p-coumaroyl)glucoside(2)
luteolin-3',7-di-O-glucoside _CE60(2)
cyanidin-3-sophoroside(2)
kaempferol-7-O-neohesperidoside_CE40(2)
cyanidin-3-glucoside p-coumaric(2)
Kaempferol-3-O-alpha-L-arabinoside_CE20(2)
delphinidin 3-(6''-coumaroyl)-5-diglucoside(2)
cyanidin-3-glucoside chloride_CE50(2)
cyanidin 3-glucoside(2)
Isosakuranetin_CE20(2)
cyanidin 3-malonylglucoside(2)
Kaempferol-3-Glucoside-2-Rhamnoside,-7-Rhamnoside?_Ramp5-45 V(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE60(2)
luteolin-7-O-glucoside_CE30(2)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE50(2)
Kaempferol-3-Galactoside-6''-Rhamnoside-3'''-Rhamnoside_CE50(2)
cyanidin-3-O-rhamnoside chloride_CE60(2)
Kaempferol-3,7-O-di-rhamnopyranoside_Ramp5-45 V(2)
Cyanidin-3-O-alpha-arabinopyranoside_CE30(2)
Sakuranetin_CE10(2)
cyanidin-3-glucoside chloride_CE60(2)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(2)
Kaempferol-3-O-alpha-L-rhamnoside_CE20(2)
Ideain chloride_CE60(2)
cyanidin-3-O-rhamnoside chloride_CE20(2)
2',6'-Dihydroxy-4-Methoxychalcone-4'-O-Neohesperidoside_CE40(2)
luteolin-7-O-glucoside_CE60(2)
cyanidin 3-(6''-coumaroyl)glucoside(2)
delphinidin 3-rutinoside-5-galactoside(2)
Cyanidin 3-Sophoroside-5-Glucoside(2)
cyanidin 3-sophoroside(2)
kaempferol-3-O-rutinoside_CE50(2)
Kaempferol_CE10(2)
cyanidin 3-laminaribiose(2)
Kaempferol-3-Glucuronide_Ramp5-45 V(2)
Kaempferol-3,7-O-bis-alpha-L-rhamnoside_CE40(2)
cyanidin 3-arabinoside(2)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(2)
kaempferol-7-O-neohesperidoside_CE50(2)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE30(2)
kaempferol-3-O-glucoside_CE30(2)
Datiscin_CE60(2)
Ideain chloride_CE40(2)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_Ramp5-45 V(2)
kaempferol-3-O-glucoside_CE20(2)
delphinidin 3-rutinoside(2)
cyanidin-3-glucoside chloride_CE40(2)
Kaempferol-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(2)
Sakuranetin_CE20(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(2)
Cyanidin 3-(3''-Acetyl)Glucoside(2)
cyanidin 3-dioxaloylglucoside(2)
Robinin_Ramp5-45 V(2)
cyanidin 7-arabinoside(2)
kaempferol-7-O-neohesperidoside_CE20(2)
4-Nitrophenol_Ramp5-45 V(2)
Hyperoside_CE20(2)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_Ramp5-45 V(2)
Kaempferol-3-O-alpha-L-rhamnoside_Ramp5-45 V(2)
Maritimein_CE20(2)
cyanidin-3-O-rhamnoside chloride_CE30(2)
delphinidin 3-glucoside p-coumaric(2)
Spiraeoside_Ramp5-45 V(2)
Kaempferol-3-O-beta-D-galactoside-7-O-alpha-L-rhamnoside_CE30(2)
kaempferol-3-O-rutinoside_CE30(2)
Kaempferol-3-Glucoside-2''-Rhamnoside-7-Rhamnoside_CE50(2)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(2)
Kaempferol-3-Glucoside_CE30(2)
Datiscin_CE50(2)
Quercetin dihexose(2)
Kaempferol-7-O-alpha-L-rhamnoside_CE60(2)
Kaempferol-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(2)
Kaempferol-3-Rhamnoside-7-Rhamnoside_Ramp5-45 V(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(2)
Datiscin_CE40(2)
cyanidin 3-sophoroside(2)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(2)
kaempferol 3-O-a-rhamnopyranoside(2)
Cyanidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)-5-O-beta-glucopyranoside_CE50(2)
Disodium Glycerophoshate 5.5-Hydrate_Ramp5-45 V(2)
cyanidin 3-xyloside(2)
cyanidin-3-xyloside-glucoside(2)
luteolin-4'-O-glucoside_CE30(2)
cyanidin 3-sophoroside(2)
kaempferol-3-O-rutinoside_CE40(2)
cyanidin 3-(6''-acetoyl)glucoside(2)
Kaempferol_CE20(2)
Luteolin_CE40(2)
Kaempferol-7-O-alpha-L-rhamnoside_CE20(2)
Cyanidin-3-O-(2''-O-beta-glucopyranosyl-beta-glucopyranoside)_CE40(2)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11449

ATH06p11452

ATH08p11860

ATH10p09621

ATH11p11061

ATH12p10342

ATH13p13711

ATH14p12091

ATH56p13832

ATH56p13833

ATH58p14690

ATH58p15098

ATH62p13164

ATH63p16429

ATH64p14923

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0102 0.0015 0.0095 0.006
ATGE_7 0.0019 0.0013 0.0019 0.0155 0.0051
ATGE_9 0.0021 0.002 0.0023 0.002 0.0021
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0205 0.0138 0.002 0.0021 0.0096
ATGE_16 0.0122 0.0215 0.0222 0.0017 0.0144
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0068 0.0063 0.0133 0.0126 0.0097
ATGE_21 0.0077 0.0021 0.0017 0.0019 0.0033
ATGE_25 0.0014 0.0018 0.0013 0.0015 0.0015
ATGE_26 0.0013 0.0011 0.002 0.0016 0.0015
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0016 0.0022 0.0017 0.0016 0.0017
ATGE_32 0.1672 0.1588 0.172 0.143 0.1603
ATGE_33 0.1417 0.1979 0.132 0.1439 0.1539
ATGE_39 0.069 0.0784 0.0582 0.0427 0.0621
ATGE_41 0.0146 0.0155 0.0012 0.0012 0.0081
ATGE_42 0.025 0.0112 0.0257 0.0195 0.0204
ATGE_45 0.0167 0.0015 0.0017 0.0018 0.0054
ATGE_76 0.0014 0.0017 0.0016 0.002 0.0017
ATGE_77 0.0017 0.0022 0.003 0.0019 0.0022
ATGE_78 0.002 0.0033 0.0074 0.0042 0.0042
ATGE_84 0.0282 0.0297 0.0282 0.0212 0.0268
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.1697 0.1481 0.1123 0.2641 0.1736
ATGE_93 0.002 0.002 0.0021 0.0015 0.0019
ATGE_95 0.0021 0.0019 0.0018 0.0015 0.0018
ATGE_96 0.0014 0.0017 0.0017 0.0015 0.0016
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0015 0.0034 0.0016 0.0015 0.002
ATGE_99 0.0019 0.0013 0.0019 0.0021 0.0018
ATGE_101 0.0018 0.0108 0.0096 0.0127 0.0087
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch