AtMetExpress Development LC-MS

Perk Nr:adp032040. Quercetin-diHex-Rha

Polarity: [POSITIVE]
Retention time: 3.25
m/z: 773
Annotation: Quercetin-diHex-Rha
Annotation level: Characterized
compound:
MS2Ts 23 MS2Ts
KNApSAcK C40H37O16(11):Madhusalmone; C40H36O16;
C33H41O21(9):Luteolin 7-gentiobioside-4'-glucoside, Kaempferol
C44H37O13(8):C44H36O12+O;
C37H41O18(6):C31H30O13+C6H10O5;
in-house MS/MS Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE40(13)
Hyperoside_Ramp5-45 V(13)
Quercetin-3-(6-malonyl)-Glucoside_Ramp5-45 V(13)
delphinidin 3-malonylglucoside(13)
delphinidin 3-arabinoside(13)
delphinidin 3-galactoside(13)
Quercetin-3,4'-O-di-beta-glucopyranoside_Ramp5-45 V(13)
delphinidin 3-glucoside(13)
Peltatoside_Ramp5-45 V(13)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_Ramp5-45 V(13)
Quercetin-3-D-xyloside_CE20(13)
Quercetin_CE20(13)
Delphinidin-3-O-beta-glucopyranoside_Ramp5-45 V(13)
Quercetin-3-O-glucose-6''-acetate_Ramp5-45 V(13)
Quercetin-3-Arabinoside_Ramp5-45 V(13)
Quercetin-3-O-b-glucopyranosyl-7-O-a-rhamnopyranoside_Ramp5-45 V(13)
Quercetin-3-O-beta-D-galactoside_CE20(13)
delphinidin 3-(6''-coumaroyl)glucoside(13)
Quercetin-7-O-rhamnoside_Ramp5-45 V(13)
Quercetin_CE10(13)
Hesperetin_CE20(13)
(NC-OMe)-Hex ? isomer #1(13)
Quercetin-3-O-glucose-6''-acetate_CE20(13)
Hesperetin_CE10(13)
quercetin 3-O-a-rhamnopyranoside(13)
quercetin-3-O-beta-glucopyranoside_Ramp5-45 V(13)
Quercetin-3-D-xyloside_Ramp5-45 V(13)
Hyperoside_CE20(13)
delphinidin 3-(6''-acetyl)glucoside(13)
Spiraeoside_Ramp5-45 V(13)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE40(13)
PIPES_CE10(13)
Quercetin-3-Glucuronide_Ramp5-45 V(13)
Quercetin_Ramp5-45 V(13)
Quercetin-3-O-beta-D-galactoside_Ramp5-45 V(13)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_Ramp5-45 V(13)
Quercetin-3-Arabinoside_CE20(12)
Quercitrin_Ramp5-45 V(12)
dihexosyl quercetin (12)
Quercetin-3-Rhamnoside_Ramp5-45 V(12)
Peltatoside_CE20(12)
Delphinidin-3-O-beta-glucopyranoside_CE50(12)
Quercetin-3-O-beta-D-galactoside_CE30(12)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE40(12)
Hyperoside_CE40(12)
Spiraeoside_CE30(11)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE50(11)
delphinidin 3-O-Glucoside(11)
quercetin-3-O-beta-glucopyranoside_CE20(11)
Delphinidin 3-Galactoside(11)
PIPES_CE20(11)
Delphinidin 3-Glucoside(11)
delphinidin 3-glucoside(11)
delphinidin 3-O-Glucoside(11)
delphinidin 3-glucoside(11)
Quercetin-3-Glucuronide_CE30(11)
Delphinidin 3-Glucoside(11)
quercetin 3-glucoside(11)
delphinidin 3-O-Glucoside(11)
quercetin-3-O-beta-glucopyranoside_CE40(11)
quercetin-3-O-beta-glucopyranoside_CE30(9)
Hesperidin_Ramp5-45 V(8)
Rutin _CE40(8)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1->2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_Ramp5-45 V(8)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE50(8)
Quercetin-3-D-xyloside_CE30(8)
Quercetin-3-O-beta-glucopyranosyl-7-O-alpha-rhamnopyranoside_CE30(8)
Ellagic acid hexose(7)
herbacetin-7-O-rha(7)
quercetin-3'/4'-rha(7)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_Ramp5-45 V(7)
delphinidin 3-O-(6-O-p-coumaroyl)glucoside(7)
Rutin _CE50(7)
Q-Hex (T4). (7)
Quercitrin_CE10(7)
delphinidin 3-glucoside p-coumaric(7)
Delphinidin-3-O-beta-glucopyranoside_CE30(7)
Delphinidin 3,5-Diglucoside(6)
Peltatoside_CE40(6)
Delphinidin-3-O-(6''-O-alpha-rhamnopyranosyl-beta-glucopyranoside)_CE40(6)
Quercetin-3-Rhamnoside_CE10(6)
Delphinidin-3-O-beta-glucopyranoside_CE60(6)
Spiraeoside_CE60(6)
Delphinidin-3-O-beta-glucopyranoside_CE40(6)
Quercetin-3,7-O-alpha-L-dirhamnopyranoside_CE40(6)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE20(6)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE30(6)
delphinidin 3-glucoside(5)
Quercetin-3-O-glucose-6''-acetate_CE50(5)
Quercetin 3'/4'-rhamnose(5)
Ellagic Acid(5)
Quercetin-3-O-glucose-6''-acetate_CE30(5)
Quercetin-3-Glucuronide_CE40(5)
Delphinidin-3-O-beta-glucopyranoside_CE20(5)
delphinidin 3-glucoside-5-rhamnoside(5)
similar to peak 7(5)
Quercetin-3-O-alpha-L-rhamnopyranosyl(1-2)-beta-D-glucopyranoside-7-O-alpha-L-rhamnopyranoside_CE60(5)
Quercetin-3,4'-O-di-beta-glucopyranoside_CE60(5)
Delphinidin-3-O-(2''-O-beta-xylopyranosyl-beta-glucopyranoside)_CE60(5)
rhodionin:7-O-? -L-rhamnopyranosylherbacetin(5)
herbacetin-7-O-rha-8-O-glu(5)
Quercetin-3-O-alpha-L-rhamnopyranoside_CE10(5)
Quercetin-3-O-beta-D-galactoside_CE40(5)
delphinidin 3,5-diglucoside(5)
(NC-OMe)-Hex ? isomer #2(5)
Quercetin-3-Arabinoside_CE30(5)
quercetin 3-rutinoside(5)
quercetin 3-neo hesperidoside(5)
delphinidin 3-glucoside(5)
delphinidin 3-O-Rutinoside(5)
Quercetin-3-Arabinoside_CE40(5)
delphinidin 3-rutinoside(5)
Quercetin 3'/4'-rhamnose(5)
Quercetin hexose(5)
rhamnosyl hexosyl quercetin (5)
Delphinidin 3-Rutinoside(5)
PIPES_CE30(5)
Rutin _CE20(5)
Quercetin-3-D-xyloside_CE40(5)
delphinidin 3-xyloside-glucoside(5)
delphinidin 3-galactoside(5)
delphinidin 3-O-Rutinoside(5)
delphinidin 3-glucoside-5-acetylrhamnoside(5)
Quercetin-3-O-glucose-6''-acetate_CE40(5)
delphinidin 3-glucoside(5)
Herbacetin 7-O-rhamnose(5)
Spiraeoside_CE40(5)
delphinidin 3-glucoside(5)
Peltatoside_CE50(4)
N1-Acetylspermine Trihydrochloride_CE30(4)
delta-Tocotrienol_Ramp5-45 V(4)
DL-3,4-Dihydroxymandelic acid _Ramp5-45 V(4)
Quercitrin_CE20(4)
Hinokitiol_Ramp5-45 V(3)
alpha-Tocotrienol_Ramp5-45 V(3)
quercetin-3-O-beta-glucopyranoside_CE10(3)
4-Hydroxybenzoate_Ramp5-45 V(3)
Quercetin dihexose(3)
Calciferol_Ramp5-45 V(3)
Represetative peak This peak

eFP visualizaion


Raw chromatograms


MS2Ts

ATH06p11452

ATH06p11457

ATH08p11867

ATH10p09621

ATH11p11061

ATH11p11065

ATH12p10342

ATH13p13497

ATH14p12095

ATH14p12098

ATH14p12297

ATH56p13836

ATH56p13839

ATH58p14695

ATH58p14698

ATH59p12879

ATH61p15327

ATH61p15330

ATH62p13164

ATH63p16202

ATH63p16432

ATH64p14929

ATH64p14932

Peak intensity data

Sample 1 2 3 4 Average
ATGE_1 0.0026 0.0015 0.0015 0.0013 0.0018
ATGE_7 0.0019 0.0013 0.0019 0.0014 0.0016
ATGE_9 0.0175 0.0195 0.0172 0.002 0.0141
ATGE_10 0.0015 0.0015 0.0014 0.0014 0.0015
ATGE_12 0.0014 0.0017 0.002 0.0014 0.0016
ATGE_13 0.0015 0.0018 0.0022 0.0017 0.0018
ATGE_14 0.002 0.0019 0.0015 0.0019 0.0018
ATGE_15 0.0014 0.0014 0.002 0.0021 0.0017
ATGE_16 0.0018 0.0018 0.0027 0.0017 0.002
ATGE_19 0.0018 0.0037 0.0019 0.0018 0.0023
ATGE_20 0.0019 0.0018 0.0017 0.0045 0.0025
ATGE_21 0.0019 0.0021 0.0017 0.0019 0.0019
ATGE_25 0.0014 0.0018 0.0053 0.0015 0.0025
ATGE_26 0.0013 0.0011 0.002 0.0016 0.0015
ATGE_27 0.0015 0.0016 0.0015 0.002 0.0017
ATGE_28 0.002 0.0018 0.0018 0.0015 0.0018
ATGE_29 0.0016 0.0022 0.0017 0.0016 0.0017
ATGE_32 0.0018 0.0017 0.0015 0.0016 0.0017
ATGE_33 0.005 0.0018 0.002 0.0021 0.0027
ATGE_39 0.0016 0.002 0.002 0.0017 0.0018
ATGE_41 0.0016 0.0015 0.0012 0.0012 0.0014
ATGE_42 0.0018 0.0014 0.0021 0.0019 0.0018
ATGE_45 0.0016 0.0015 0.0017 0.0018 0.0017
ATGE_76 0.1043 0.0017 0.0745 0.1025 0.0707
ATGE_77 0.236 0.0621 0.1143 0.1615 0.1435
ATGE_78 0.3251 0.0033 0.0014 0.0042 0.0835
ATGE_84 0.0018 0.0019 0.0129 0.0136 0.0075
ATGE_91 0.0016 0.002 0.0017 0.0018 0.0018
ATGE_92 0.0017 0.0017 0.0017 0.0025 0.0019
ATGE_93 0.0225 0.002 0.0021 0.0178 0.0111
ATGE_95 0.021 0.0019 0.0307 0.0148 0.0171
ATGE_96 0.0014 0.0017 0.0017 0.0015 0.0016
ATGE_97 0.0016 0.0021 0.002 0.0019 0.0019
ATGE_98 0.0015 0.0034 0.0368 0.0306 0.0181
ATGE_99 0.0019 0.0013 0.0429 0.0021 0.012
ATGE_101 0.0018 0.0015 0.0021 0.0018 0.0018
RIKEN Plant Science Center
Metabolome analysis research team, LC-MS Branch